IP Library Granted Patent US 9,580,573
Granted Patent B2
US 9,580,573 · App. 14/867,628 · Granted Feb 28, 2017

Mixtures containing trimellitic acid ester and polyether polyol ester as plasticizers, use of the mixtures for producing polymer compounds and PVC materials containing said mixtures

Inventors: Guido D. Frey (Riedstadt, DE); Horst Lange (Bochum, DE); Heinz Strutz (Moers, DE); Jacco de Haas (Krefeld, DE)
Assignee: OXEA GMBH
C08K5/12C08K5/0016C08K5/103C08L71/02
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 9,580,573
App. No.
14/867,628
Granted
Feb 28, 2017
Kind
B2
Abstract

A mixture useful as plasticizer comprises trimellitic esters and polyether polyol esters, characterized in that the mixture comprises from 1 to 99% by weight of trimellitic esters and 99 to 1% by weight of polyether polyol esters, wherein the polyether polyol esters can be derived from linear or branched, aliphatic monocarboxylic acids having 3 to 20 carbon atoms in the molecule.

Claims (11)

1. A mixture comprising trimellitic esters and polyether polyol ester, characterized in that the mixture comprises from more than 84.5% up to 99% by weight of trimellitic esters and 1% up to less than 15.5% by weight of a polyether polyol ester, wherein the polyether polyol ester is triethylene glycol di-2-ethylhexanoate and further characterized in that trimellitic esters are selected from tri(2-ethylhexyl) trimellitate, tri(n-octyl, n-decyl) trimellitate, tri(heptyl, nonyl) trimellitate, tri(n-octyl) trimellitate, tri(isononyl) trimellitate, tri(isodecyl) trimellitate or mixtures thereof.

2. A mixture according to claim 1 , characterized in that the mixture consists of tri(2-ethylhexyl) trimellitate and triethylene glycol di-2-ethylhexanoate.

3. A mixture according to claim 1 , characterized in that the mixture has a viscosity of <300 mm 2 /s at 20° C. and <80 mm 2 /s at 40° C.

4. PVC materials comprising the mixture according to claim 1 , characterized in that the PVC materials have a glass transition temperature of <20° C.

5. PVC materials comprising the mixture according to claim 1 , characterized in that the PVC materials have a fogging number of at least 60.

6. A method of using the mixture according to claim 1 comprising incorporating the mixture into polymer compositions comprising a polymer and the mixture, said compositions having a Shore A hardness of <90.

7. A method of using the mixture according to claim 1 comprising incorporating the mixture into a product selected from the group consisting of: polymer compounds; masterbatches; semifinished products and finished products.

8. The method according to claim 7 , wherein the product comprises PVC.

9. The method according to claim 8 , wherein the mixture consists of tri(2-ethylhexyl) trimellitate and triethylene glycol di-2-ethylhexanoate.

10. A product comprising PVC and provided with a mixture comprising from more than 84.5% up to 99% by weight of trimellitic esters and 1% up to less than 15.5% by weight of a polyether polyol ester, wherein the polyether polyol ester is triethylene glycol di-2-ethylhexanoate, wherein the trimellitic esters are selected from tri(2-ethylhexyl) trimellitate, tri(n-octyl, n-decyl) trimellitate, tri(heptyl, nonyl) trimellitate, tri(n-octyl) trimellitate, tri(isononyl) trimellitate, tri(isodecyl) trimellitate or mixtures thereof.

11. The product according to claim 10 , characterized in that the mixture consists of tri(2-ethylhexyl) trimellitate and triethylene glycol di-2-ethylhexanoate.

Assignments (2)
CHANGE OF NAME Recorded Aug 25, 2021
From: OXEA GMBH
To: OQ CHEMICALS GMBH
Reel/Frame 057312/0979 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 29, 2015
From: FREY, GUIDO D., DR.; LANGE, HORST DR.; STRUTZ, HEINZ DR.; DE HAAS, JACCO
To: OXEA GMBH
Reel/Frame 036735/0259 →
Priority Claims (2)
DE 10 2012 012 942 · Jun 29, 2012 · national
WO PCT/EP2013/001655 · Jun 5, 2013 · international
Continuity (2)
Continuation 14391431
Related Publication 20160017120A1 · Jan 21, 2016