Cathode active material for lithium battery, lithium battery, and method for producing cathode active material for lithium battery
The main object of the present invention is to provide a cathode active material for a lithium battery capable of inhibiting resistance from increasing with time. The present invention attains the object by providing a cathode active material for a lithium battery comprising: a cathode active material containing an Mn element and being an oxide; and a coating portion formed on a surface of the cathode active material, characterized in that the coating portion contains a Li element, a P element, an O element and the Mn element derived from the cathode active material, and a ratio of the Mn element to the P element, (Mn/P) is 1 or more at an interface between the cathode active material and the coating portion.
1. A cathode active material complex for a lithium battery comprising:
a cathode active material comprising an Mn element and being an oxide; and
a coating portion formed on a surface of the cathode active material,
wherein the coating portion comprises a Li element, a P element, an O element and the Mn element derived from the cathode active material, and
a ratio of the Mn element to the P element, (Mn/P) is 1 or more at an interface between the cathode active material and the coating portion.
2. The cathode active material complex for a lithium battery according to claim 1 , wherein when a location in which a number of atoms of the P element (%) becomes maximum in a thickness direction of the coating portion is regarded as B, the Mn/P in the location B is 0.79 or more.
3. A lithium battery comprising a cathode active material layer, an anode active material layer, and a solid electrolyte layer formed between the cathode active material layer and the anode active material layer,
wherein the cathode active material layer comprises the cathode active material complex for a lithium battery according to claim 1 , and
at least one of the cathode active material layer and the solid electrolyte layer comprises a sulfide solid electrolyte material.
4. A lithium battery comprising a cathode active material layer, an anode active material layer, and a solid electrolyte layer formed between the cathode active material layer and the anode active material layer,
wherein the cathode active material layer comprises the cathode active material complex for a lithium battery according to claim 2 , and
at least one of the cathode active material layer and the solid electrolyte layer comprises a sulfide solid electrolyte material.
5. A method for producing a cathode active material complex for a lithium battery, the cathode active material complex for a lithium battery comprising a cathode active material comprising an Mn element and being an oxide, and a coating portion,
the method comprising a step of forming the coating portion on a surface of the cathode active material by using a sputtering method,
wherein the coating portion comprises a Li element, a P element, an O element and the Mn element derived from the cathode active material, and
a ratio of the Mn element to the P element, (Mn/P) is 1 or more at an interface between the cathode active material and the coating portion.
6. The method for producing a cathode active material complex for a lithium battery according to claim 5 , wherein when a location in which a number of atoms of the P element (%) becomes maximum in a thickness direction of the coating portion is regarded as B, the Mn/P in the location B is 0.79 or more.
7. The method for producing a cathode active material complex for a lithium battery according to claim 1 , wherein the ratio of the Mn element to the P element, (Mn/P) is 2 or more and 10 or less.
8. The method for producing a cathode active material complex for a lithium battery according to claim 1 , wherein the ratio of the Mn element to the P element, (Mn/P) is 3 or more and 10 or less.
9. The method for producing a cathode active material complex for a lithium battery according to claim 1 , wherein the cathode active material is a spinel type active material.