Propylene composition with improved impact resistance at low temperature
Polypropylene composition comprising comonomer units derived from ethylene in an amount of from 9.0 to 52.0 mol-% and comonomer units derived from a higher a-olefin in an amount of from 0.4 to 3.0 mol-%, wherein said polypropylene composition has an amount of xylene cold solubles of at least 30 wt.-%, wherein further the xylene cold soluble fraction has an ethylene content of from 20.0 to 80.0 mol-% and a higher a-olefin content from 0.1 to 1.5 mol-%.
1. A polypropylene composition comprising comonomer units derived from ethylene in an amount of from 9.0 to 52.0 mol-% and comonomer units derived from at least one C 5-12 α-olefin in an amount of from 0.4 to 3.0 mol-%, wherein the polypropylene composition
(a) has an amount of xylene cold solubles (XCS) of at least 30 wt.-%,
(b) fulfills in-equation (I)
IV(XCS)−IV(tot)≦0.30 (I)
wherein IV(XCS) is the intrinsic viscosity (IV) of the xylene cold soluble (XCS) fraction of the polypropylene composition, and IV(tot) is the intrinsic viscosity (IV) of the polypropylene composition, and
(c) is a heterophasic propylene copolymer (HECO) comprising a propylene copolymer (C) and an elastomeric copolymer (E), wherein the propylene copolymer (C) is a propylene copolymer of units derived from propylene and at least one C 5-12 α-olefin and the elastomeric copolymer (E) is a terpolymer (T) of units derived from propylene ethylene and C 5-12 α-olefin.
2. The polypropylene composition according to claim 1 , wherein the xylene cold soluble (XCS) fraction has an amount (a) of ethylene-derived comonomer units of from 20.0 to 80.0 mol-%; and/or (b) of C 5-12 α-olefin-derived comonomer units of from 0.1 to 1.5 mol-%.
3. A polypropylene composition comprising comonomer units derived from ethylene in an amount of from 9.0 to 52.0 mol-% and comonomer units derived from at least one C 5-12 α-olefin in an amount of from 0.4 to 3.0 mol-%, wherein the polypropylene composition has an amount of xylene cold solubles (XCS) of at least 30 wt.-%,
wherein further the xylene cold solubles (XCS) of the polypropylene composition has an amount of (a) of ethylene-derived comonomer units of from 20.0 to 80.0 mol-%; and/or (b) of C 5-12 α-olefin-derived comonomer units of from 0.1 to 1.5 mol-%.
4. The polypropylene composition according to claim 3 , wherein the polypropylene composition fulfills in-equation (I)
IV(XCS)−IV(tot)≦0.30 (I)
wherein
IV(XCS) is the intrinsic viscosity (IV) of the xylene cold soluble (XCS) fraction of the polypropylene composition and IV(tot) is the intrinsic viscosity (IV) of the polypropylene composition.
5. The polypropylene composition according to claim 1 , wherein
(a) the amount of 20 wt-% of ethylene-derived comonomer units in the xylene cold soluble (XCS) fraction of the polypropylene composition is excluded; and/or
(b) the polypropylene composition fulfills in-equation (II)
57.0
<
XCS
CX
(
XCS
)
<
300
(
II
)
wherein
CX(XCS) is the amount in mol-% of C 5-12 α-olefin-derived comonomer units in the xylene cold soluble (XCS) fraction of the polypropylene composition,
XCS is the amount in wt.-% of xylene cold soluble (XCS) fraction of the polypropylene composition.
6. The polypropylene composition according to claim 1 , wherein
(a) the C 5-12 α-olefin is 1-hexene or 1-octene; and/or
(b) the total amount of comonomer units in the polypropylene composition is from 9.4 to 55.5 mol-%.
7. The polypropylene composition according to claim 1 , wherein
(a) the intrinsic viscosity (IV) of the xylene cold soluble (XCS) fraction of the polypropylene composition is in the range of 1.5 to 4.0 dl/g; and/or
(b) the intrinsic viscosity (IV) of the polypropylene composition is in the range of 1.0 to 3.0 dl/g.
8. The polypropylene composition according to claim 1 , wherein the polypropylene composition has a glass transition temperature below −25° C.
9. The polypropylene composition according to claim 1 , wherein the propylene copolymer (C) comprises a propylene homopolymer fraction (HF1) and a propylene copolymer fraction (CF1′), wherein further the propylene copolymer fraction (CF1′) consists of units derived from derived from propylene and at least one C 5-12 α-olefin.
10. The polypropylene composition according to claim 1 , wherein
(a) the terpolymer (T) has a comonomer content in the range of 20.05 to 82.0 mol-%; and/or
(b) the weight ratio between the propylene homopolymer fraction (HF1) and the propylene copolymer fraction (CF1′) [(HF1)/(CF1′)] is 75/25 to 30/70; and/or
(c) the weight ratio between the propylene copolymer (C) and the elastomeric copolymer (E) [(C)/(E)] is 75/25 to 40/60.
11. A molded article comprising the polypropylene composition according to claim 1 .
12. A process for preparing the polypropylene composition according to claim 1 , comprising
(i) preparing the propylene homopolymer fraction (HF1) in a first polymerization reactor PR1,
(ii) transferring the propylene homopolymer fraction (HF1) obtained in the polymerization reactor (R1) to a polymerization reactor (R2) and preparing the propylene copolymer fraction (CF1′) by polymerizing propylene and at least one C 5-12 α-olefin in the presence of propylene homopolymer fraction (HF1), thereby obtaining the propylene copolymer (C); and
(iii) transferring the propylene copolymer (C) of step (ii) into a polymerization reactor (R3) and preparing the elastomeric copolymer (E) by polymerizing propylene, ethylene and at least one C 5-12 α-olefin in the presence of the propylene copolymer (C), thereby obtaining the polypropylene composition.
13. The polypropylene composition according to claim 6 , wherein
(a) the C 5-12 α-olefin is 1-hexene; and/or
(b) the total amount of comonomer units are derived from ethylene and at least one C 5-12 α-olefin in the polypropylene composition is from 9.4 to 55.5 mol-%.
14. The polypropylene composition according to claim 3 , wherein
(a) the amount of 20 wt-% of ethylene-derived comonomer units in the xylene cold soluble (XCS) fraction of the polypropylene composition is excluded; and/or
(b) the polypropylene composition fulfills in-equation (II)
57.0
<
XCS
CX
(
XCS
)
<
300
(
II
)
wherein
CX(XCS) is the amount in mol-% of C 5-12 α-olefin-derived comonomer units in the xylene cold soluble (XCS) fraction of the polypropylene composition,
XCS is the amount in wt.-% of xylene cold soluble (XCS) fraction of the polypropylene composition.
15. The polypropylene composition according to claim 3 , wherein
(a) the C 5-12 α-olefin is 1-hexene or 1-octene; and/or
(b) the total amount of comonomer units in the polypropylene composition is from 9.4 to 55.5 mol-%.
16. The polypropylene composition according to claim 3 , wherein
(a) the intrinsic viscosity (IV) of the xylene cold soluble (XCS) fraction of the polypropylene composition is in the range of 1.5 to 4.0 dl/g; and/or
(b) the intrinsic viscosity (IV) of the polypropylene composition is in the range of 1.0 to 3.0 dl/g.
17. The polypropylene composition according to claim 3 , wherein the polypropylene composition has a glass transition temperature below −25° C.
18. The polypropylene composition according to claim 3 , wherein the polypropylene composition is a heterophasic propylene copolymer (HECO) comprising a propylene copolymer (C) and an elastomeric copolymer (E), wherein the propylene copolymer (C) is a propylene copolymer of units derived from propylene and at least one C 5-12 α-olefin and the elastomeric copolymer (E) is a terpolymer (T) of units derived from propylene, ethylene and C 5-12 α-olefin.
19. The polypropylene composition according to claim 18 , wherein the propylene copolymer (C) comprises a propylene homopolymer fraction (HF1) and a propylene copolymer fraction (CF1′), wherein further the propylene copolymer fraction (CF1′) consists of units derived from derived from propylene and at least one C 5-12 α-olefin.