IP Library Granted Patent US 9,708,713
Granted Patent B2
US 9,708,713 · App. 14/282,824 · Granted Jul 18, 2017

Aerosol deposition coating for semiconductor chamber components

Inventors: Jennifer Y. Sun (Mountain View, CA); Biraja Kanungo (San Jose, CA); Tom Cho (Los Altos, CA); Ying Zhang (Santa Clara, CA)
Assignee: Applied Materials, Inc.
C23C24/04H01J37/3244H01J37/32807Y10T428/24413
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Quick Facts
Patent No.
US 9,708,713
App. No.
14/282,824
Granted
Jul 18, 2017
Kind
B2
Abstract

A method for coating a component for use in a semiconductor chamber for plasma etching includes providing the component and loading the component in a deposition chamber. A pressure in the deposition chamber is reduced to below atmospheric pressure. A coating is deposited on the component by spraying an aerosol comprising a suspension of a first type of metal oxide nanoparticle and a second type of metal oxide nanoparticle onto the component at approximately room temperature.

Claims (53)

1. A method comprising:

loading a component into a deposition chamber, wherein the component is a component of a processing chamber;

reducing a pressure of the deposition chamber below atmospheric pressure; and

depositing a coating on the component by spraying an aerosol of ceramic nanoparticles comprising a mixture of a first rare earth metal oxide, a second rare earth metal oxide and a third metal oxide onto the component at approximately room temperature, wherein the coating has a particle crystal structure and wherein:

the first rare earth metal oxide is Y 2 O 3 and the mixture comprises the Y 2 O 3 in a range of 40 mol % to less than 100 mol %;

the second rare earth metal oxide is ZrO 2 and the mixture comprises the ZrO 2 in a range of greater than 0 mol % to less than 60 mol %; and

the third metal oxide is Al 2 O 3 and the mixture comprises the Al 2 O 3 at a range of greater than 0 mol % to 40 mol %.

2. The method of claim 1 further comprising polishing the component such that a surface roughness of the component is less than about 0.2 microinch.

3. The method of claim 1 , wherein the aerosol has a velocity of greater than about 300 meters per second.

4. The method of claim 1 , wherein the aerosol further comprises a carrier gas of Nitrogen or Argon.

5. The method of claim 1 , further comprising heating the component after deposition of the coating to greater than about 1450 degrees C. for more than about 30 minutes to form a barrier layer between the component and the coating.

6. The method of claim 1 , further comprising depositing an additional coating on the component via a pressurized flow of an additional powder directed to the component in the deposition chamber at room temperature.

7. The method of claim 1 , wherein the component comprises Aluminum.

8. The method of claim 1 , wherein:

the mixture comprises the Y 2 O 3 in a range of 50-75 mol %;

the mixture comprises the ZrO 2 in a range of 10-30 mol %; and

the mixture comprises the Al 2 O 3 in a range of 10-30 mol %.

9. The method of claim 1 , wherein:

the mixture comprises the Y 2 O 3 in a range of 40 mol % to less than 100 mol %;

the mixture comprises the ZrO 2 in a range of greater than 0 mol % to less than 60 mol %; and

the mixture comprises the Al 2 O 3 in a range of greater than 0 mol % to less than 10 mol %.

10. The method of claim 1 , wherein:

the mixture comprises the Y 2 O 3 in a range of 40-60 mol %;

the mixture comprises the ZrO 2 in a range of greater than 30 mol % to 50 mol %; and

the mixture comprises the Al 2 O 3 in a range of 10-20 mol %.

11. The method of claim 1 , wherein:

the mixture comprises the Y 2 O 3 in a range of 40 mol % to less than 50 mol %;

the mixture comprises the ZrO 2 in a range of 20-40 mol %; and

the mixture comprises the Al 2 O 3 in a range of 20-40 mol %.

12. The method of claim 1 , wherein:

the mixture comprises the Y 2 O 3 in a range of greater than 70 mol % to 90 mol %;

the mixture comprises the ZrO 2 in a range of greater than 0 mol % to 20 mol %; and

the mixture comprises the Al 2 O 3 in a range of 10-20 mol %.

13. The method of claim 1 , wherein:

the mixture comprises the Y 2 O 3 in a range of 60-80 mol %;

the mixture comprises the ZrO 2 in a range of greater than 0 mol % to 10 mol %; and

the mixture comprises the Al 2 O 3 in a range of 20-40 mol %.

14. The method of claim 1 , wherein:

the mixture comprises the Y 2 O 3 in a range of 40-60 mol %;

the mixture comprises the ZrO 2 in a range of greater than 0 mol % to 20 mol %; and

the mixture comprises the Al 2 O 3 in a range of greater than 30 mol % to 40 mol %.

15. A method comprising:

loading a component into a deposition chamber, wherein the component is a component of a processing chamber;

reducing a pressure of the deposition chamber below atmospheric pressure; and

depositing a coating on the component by spraying an aerosol of ceramic nanoparticles consisting of a mixture of a first rare earth metal oxide and a second metal oxide onto the component at approximately room temperature, wherein the coating has a particle crystal structure and wherein:

the first rare earth metal oxide is Er 2 O 3 ; and

the second metal oxide is Al 2 O 3 .

16. A method comprising:

loading a component into a deposition chamber, wherein the component is a component of a processing chamber;

reducing a pressure of the deposition chamber below atmospheric pressure; and

depositing a coating on the component by spraying an aerosol of ceramic nanoparticles consisting of a mixture of a first rare earth metal oxide and a second metal oxide onto the component at approximately room temperature, wherein the coating has a particle crystal structure and wherein:

the first rare earth metal oxide is Gd 2 O 3 ; and

the second metal oxide is Al 2 O 3 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 20, 2014
From: SUN, JENNIFER Y.; KANUNGO, BIRAJA; CHO, TOM; ZHANG, YING
To: APPLIED MATERIALS, INC.
Reel/Frame 032934/0916 →
Continuity (2)
Provisional Application 61827290 · May 24, 2013
Related Publication 20140349073A1 · Nov 27, 2014