Nonaqueous electrolyte secondary battery laminated separator
Provided is a nonaqueous electrolyte secondary battery laminated separator including a laminated porous film including a porous film and a porous layer. The piercing strength (S) of the laminated porous film satisfies Formula (1): 2 gf≦Sp−S≦25 gf, and the piercing strength (Sp) of the porous film after removal of the porous layer from the laminated porous film satisfies Formula (2): 300 gf≦S≦400 gf. The nonaqueous electrolyte secondary battery laminated separator is excellent in output characteristic, shutdown characteristic, and piercing strength.
1. A nonaqueous electrolyte secondary battery laminated separator comprising a laminated porous film, comprising:
(a) a porous film containing a polyolefin component in an amount of not less than 80% by volume with respect to a total volume of the porous film (a); and
(b) a porous layer containing a resin,
the porous film (a) having a thickness of not less than 5 μm and not more than 20 μm,
the laminated porous film having a thickness of not less than 6 μm and not more than 25 μm,
the laminated porous film having a Gurley value of not more than 250 sec/100 mL,
a piercing strength of the laminated porous film and a piercing strength of the porous film (a) after removal of the porous layer from the laminated porous film satisfy Formulae (1) and (2) below,
2 gf≦ Sp−S≦ 25 gf Formula (1):
300 gf≦ S≦ 400 gf, Formula (2):
where
S is the piercing strength of the laminated porous film, and
Sp is the piercing strength of the porous film (a) after the removal of the porous layer from the laminated porous film.
2. The nonaqueous electrolyte secondary battery laminated separator according to claim 1 ,
wherein:
the porous layer further contains a filler; and
the filler is contained at a proportion of not less than 50 mass % and not more than 99 mass % with respect to a total amount of a combination of the filler and the resin.
3. The nonaqueous electrolyte secondary battery laminated separator according to claim 1 ,
wherein
the thickness of the porous film (a) is not less than 6 μm and not more than 14 μm.
4. A nonaqueous electrolyte secondary battery member, comprising:
a cathode;
a nonaqueous electrolyte secondary battery laminated separator according to claim 1 ; and
an anode,
the cathode, the nonaqueous electrolyte secondary battery laminated separator, and the anode being arranged in this order.
5. A nonaqueous electrolyte secondary battery, comprising
a nonaqueous electrolyte secondary battery laminated separator according to claim 1 .