Use of magnetic iron oxide red in catalyzing and oxidizing methanthiol and methods for preparing and appling same
The present invention relates to a novel use of magnetic iron oxide red Fe 21.333 O 32 as a catalyst in oxidizing methanthiol to prepare dimethyl disulfide. The magnetic iron oxide red Fe 21.333 O 32 according to the present invention has extremely high catalytic selectivity in catalyzing and oxidizing methanthiol to prepare dimethyl disulfide. The magnetic iron oxide red Fe 21.333 O 32 is prepared with a carbonate and a ferrite as raw materials, has advantages of low cost and simple preparation process, and is suitable for industrial production.
1. A method for preparing dimethyl disulfide, wherein the method comprises oxidizing methanthiol in presence of a catalyst comprising magnetic iron oxide red (Fe 21.333 O 32 ).
2. The method of claim 1 , wherein the catalyst consists of magnetic iron oxide red (Fe 21.333 O 32 ) in an amount of 80-95 wt %, and a binder.
3. The method of claim 1 , wherein the catalyst is prepared by a method comprising:
preparing a solution of a soluble carbonate and a soluble ferrous salt by providing the solution in a controlled molar ratio of the carbonate to the ferrous salt of 1:0.8-1.5, stirring the solution to allow the carbonate to react with the ferrous salt in the solution to form a first mixture, and filtrating the first mixture to obtain a filter cake;
calcining the filter cake at a temperature of 250-400° C. for two to five hours, then washing with water and drying the filter cake to yield the magnetic iron oxide red (Fe 21.333 O 32 ); and
mixing the magnetic iron oxide red (Fe 21.333 O 32 ) and a binder to form a second mixture, followed by roll molding at room temperature and drying the second mixture to produce the catalyst.
4. The method of claim 3 , wherein the soluble carbonate is sodium carbonate or potassium carbonate, and the soluble ferrous salt is ferrous sulfate.
5. The method of claim 4 , wherein the ferrous sulfate has a concentration of 1.5-3.0 mol/L in the solution.
6. The method of claim 4 , wherein the ferrous sulfate has a concentration of 2.2 mol/L in the solution.
7. The method of claim 3 , wherein calcining the filter cake is at a temperature of 300° C.
8. The method of claim 3 , wherein the binder is polyvinyl alcohol or red clay.
9. The method of claim 3 , wherein drying the second mixture is at a temperature of no more than 100° C.
10. The method of claim 1 , wherein the method comprises,
introducing a gas mixture of a methanthiol gas and an oxygen containing gas into a fixed bed reactor, reacting the gas mixture in the presence of catalyst under controlled conditions of a reaction temperature of 10-150° C., a space velocity of the gas mixture of 500-2000 h −1 , and a reaction pressure of atmospheric pressure, wherein a molar ratio of the oxygen in the oxygen containing gas and the methanthiol gas is equal to or greater than 1:3.
11. The method of claim 10 , wherein the catalyst is prepared by a method comprising:
preparing a solution of a soluble carbonate and a soluble ferrous salt by providing the solution in a controlled molar ratio of the carbonate to the ferrous salt of 1:0.8-1.5, stirring the solution to allow the carbonate to react with the ferrous salt in the solution to form a first mixture, and filtrating the first mixture to obtain a filter cake;
calcining the filter cake at 250-400° C. for two to five hours, then washing with water and drying the filter cake to yield the magnetic iron oxide red (Fe 21.333 O 32 ); and
mixing the magnetic iron oxide red Fe 21.333 O 32 and a binder to form a second mixture, followed by roll molding at room temperature, and drying the second mixture to produce the catalyst.
12. The method of claim 11 , wherein the catalyst consists of magnetic iron oxide red Fe 21.333 O 32 in an amount of 80-95 wt %, and a binder.