Zoned catalyst system for reducing N
A catalyst system for reducing N 2 O emissions in the exhaust system of a vehicle is provided and comprises a support in communication with the exhaust gas stream, with the support including an exhaust gas inlet and an exhaust gas outlet. The support has at least one exhaust gas passage therethrough. The support, which may be in the form of a monolithic, multi-cell honeycomb construction, comprises a first catalytic zone and a second catalytic zone positioned downstream from the first zone. The first catalytic zone includes rhodium or a rhodium-enriched catalyst, while the second catalytic zone includes palladium or a palladium-enriched catalyst.
1. A catalyst system for reducing N 2 O emissions in an exhaust system of a vehicle comprising:
a support in communication with an exhaust gas stream, said support including an exhaust gas inlet and an exhaust gas outlet and having at least one exhaust gas passage therethrough, said support comprising a first catalytic zone and a second catalytic zone positioned downstream from said first catalytic zone, said first catalytic zone including a PGM catalyst comprising from 50 to 100 wt % rhodium, with the remainder comprising palladium and/or platinum in any weight ratio, and said second catalytic zone including a PGM catalyst comprising from 50 to 100 wt % palladium, with the remainder comprising rhodium and/or platinum in any weight ratio, in which said second catalytic zone includes a nickel-copper catalyst.
2. The catalyst system as claimed in claim 1 in which said support comprises cerium oxide, zirconium oxide, aluminum oxide, and mixtures thereof.
3. The catalyst system as claimed in claim 1 in which said PGM catalyst in said first catalytic zone has a catalyst loading of from about 0.5 to about 300 gm/ft 3 .
4. The catalyst system as claimed in claim 1 in which said PGM catalyst in said second catalytic zone has a catalyst loading of from about 0.5 to about 300 gm/ft 3 .
5. The catalyst system as claimed in claim 1 in which said nickel-copper catalyst has a catalyst loading of from about 0.5 to about 2000 gm/ft 3 .
6. The catalyst system as claimed in claim 1 in which said nickel-copper catalyst has a nickel to copper ratio of >1.
7. The catalyst system as claimed in claim 1 further including a third catalytic zone downstream from said second catalytic zone including a catalyst comprising nickel and copper.
8. The catalyst system as claimed in claim 7 in which said first catalytic zone in said exhaust gas passage comprises an inlet channel having first and second ends, said first end of said inlet channel communicating with said exhaust gas inlet, said second catalytic zone comprises an outlet channel having first and second ends, said second end of said outlet channel communicating with said exhaust gas outlet, and said third catalytic zone comprises an intermediate channel having first and second ends, said first end of said intermediate channel communicating with said second end of said inlet channel and said second end of said intermediate channel communicating with said first end of said outlet channel, wherein said intermediate channel is oriented such that a flow of exhaust gas through said at least one exhaust gas passage is reversed from a direction of flow in said inlet and outlet channels.
9. A catalyst system for reducing N 2 O emissions in an exhaust system of a vehicle comprising:
a support in communication with an exhaust gas stream, said support including an exhaust gas inlet and an exhaust gas outlet and having at least one exhaust gas passage therethrough, said support comprising:
a first catalytic zone and a second catalytic zone positioned downstream from said first catalytic zone, said first catalytic zone including a PGM catalyst comprising from about 50 to about 100 wt % rhodium, with the remainder comprising palladium and/or platinum in any weight ratio, and said second catalytic zone including a PGM catalyst comprising from about 50 to about 100 wt % palladium, with the remainder comprising rhodium and/or platinum in any weight ratio, and
further including a third catalytic zone downstream from said second catalytic zone including a catalyst comprising nickel and copper,
wherein said first catalytic zone in said exhaust gas passage comprises an inlet channel having first and second ends, said first end of said inlet channel communicating with said exhaust gas inlet, said second catalytic zone comprises an outlet channel having first and second ends, said second end of said outlet channel communicating with said exhaust gas outlet, and said third catalytic zone comprises an intermediate channel having first and second ends, said first end of said intermediate channel communicating with said second end of said inlet channel and said second end of said intermediate channel communicating with said first end of said outlet channel, and wherein said intermediate channel is oriented such that a flow of exhaust gas through said at least one exhaust gas passage is reversed from a direction of flow in said inlet and outlet channels.