Adhesive film for polarizing plate, adhesive composition for the same, polarizing plate including the same, and optical display device including the same
An adhesive film for polarizing plates includes a (meth)acrylic copolymer obtained by polymerizing about 15 wt % to about 30 wt % of a (meth)acrylic monomer having a hetero-alicyclic ring. The adhesive film has a storage modulus (G′) of about 30 kPa or greater as determined from Frequency sweep testing at 85° C. by oscillation at an angular speed of 10 −3 rad/s to 10 2 rad/s. An adhesive composition for the same, a polarizing plate including the same, and an optical display device including the same are also disclosed.
1. An adhesive film for polarizing plates, the adhesive film comprising: a (meth)acrylic copolymer comprising 15 wt % to 30 wt % of a polymerized (meth)acrylic monomer having a hetero-alicyclic ring, based on the total weight of the (meth)acrylic copolymer, the adhesive film having a storage modulus (G′) of about 30 kPa to about 10 MPa as determined from frequency sweep testing at 85° C. using oscillation at an angular speed of 10 −3 rad/s to 10 2 rad/s,
wherein the (meth)acrylic copolymer comprises a copolymerization product of a monomer mixture comprising 15 wt % to 30 wt % of the (meth)acrylic monomer having a hetero-alicyclic ring, about 60 wt % to about 84 wt % of a (meth)acrylic monomer having an alkyl group, about 0.5 wt % to about 5 wt % of a (meth)acrylic monomer having a hydroxyl group, and about 0.1 wt % to about 3 wt % of a (meth)acrylic monomer having a carboxylic acid group,
wherein the (meth)acrylic monomer having a hetero-alicyclic ring comprises a morpholine group, and
wherein the adhesive film has a peel strength of about 550 gf/25 mm to about 1000 gf/25 mm.
2. The adhesive film for polarizing plates according to claim 1 , wherein the (meth)acrylic copolymer has a weight average molecular weight of about 1,500,000 g/mol or less.
3. The adhesive film for polarizing plates according to claim 1 , wherein the adhesive film has a thickness of about 1 μm to about 15 μm.
4. The adhesive film for polarizing plates according to claim 1 , wherein the adhesive film comprises a cured product of an adhesive composition comprising the (meth)acrylic copolymer and a crosslinking agent.
5. The adhesive film for polarizing plates according to claim 4 , wherein the crosslinking agent comprises a mixture of an isocyanate crosslinking agent and an epoxy crosslinking agent.
6. The adhesive film for polarizing plates according to claim 4 , wherein the composition further comprises a silane coupling agent having an epoxy group.
7. An adhesive composition for polarizing plates, comprising: a (meth)acrylic copolymer of a monomer mixture comprising 15 wt % or more, based on the total weight of the (meth)acrylic copolymer, of a polymerized (meth)acrylic monomer having a hetero-alicyclic ring, and a crosslinking agent,
wherein an adhesive film formed from the adhesive composition has a storage modulus (G′) of about 30 kPa to about 10 MPa as determined from frequency sweep testing at 85° C. using oscillation at an angular speed of 10 −3 rad/s to 10 2 rad/s, and
wherein the (meth)acrylic copolymer comprises a copolymerization product of a monomer mixture comprising 15 wt % to 30 wt % of the (meth)acrylic monomer having a hetero-alicyclic ring, about 60 wt % to about 84 wt % of a (meth)acrylic monomer having an alkyl group, about 0.5 wt % to about 5 wt % of a (meth)acrylic monomer having a hydroxyl group, and about 0.1 wt % to about 3 wt % of a (meth)acrylic monomer having a carboxylic acid group,
wherein the (meth)acrylic monomer having a hetero-alicyclic ring comprises a morpholine group, and
wherein the adhesive film has a peel strength of about 550 gf/25 mm to about 1000 gf/25 mm.
8. The adhesive composition according to claim 7 , wherein the crosslinking agent comprises a mixture of an isocyanate crosslinking agent and an epoxy crosslinking agent.
9. The adhesive film for polarizing plates according to claim 7 , wherein the composition further comprises a silane coupling agent having an epoxy group.
10. A polarizing plate comprising a retardation film, a first adhesive layer, a second protective film, a polarizer, and a first protective film in sequential order, wherein the first adhesive layer comprises the adhesive film for polarizing plates according to claim 1 .
11. The polarizing plate according to claim 10 , wherein the retardation film has a saturated water absorptivity of 1% or less.
12. The polarizing plate according to claim 10 , wherein the polarizing plate further comprises a second adhesive layer on a side of the retardation film.
13. An optical display device comprising the polarizing plate according to claim 10 .