Pressure sensitive adhesive composition
Provided are a pressure-sensitive adhesive composition, a protection film, an optical laminate, a polarizing plate, and a display device. Provided is the pressure-sensitive adhesive composition which is excellent in various physical properties, such as endurance reliability, has excellent antistatic characteristics that change little over time. The pressure-sensitive adhesive composition can be used for a protection film, or can be used for an optical film, such as a polarizing plate, for example.
1. A pressure-sensitive adhesive composition comprising:
a block copolymer including a first block having a glass transition temperature of 50° C. or higher, and a second block having a glass transition temperature of −10° C. or lower, the second block including a copolymer which is derived from (meth)acrylic acid ester monomer, a copolymeric monomer having a cross-linkable functional group, and a compound containing a nitrogen atom; and
an antistatic agent,
wherein the first block consists of a homopolymer which is derived from (meth)acrylic acid ester monomer,
the block copolymer is a diblock copolymer having the first block and the second block, and
the diblock copolymer is the only block copolymer in the pressure-sensitive adhesive composition.
2. The pressure-sensitive adhesive composition of claim 1 , wherein the compound containing a nitrogen atom is an amide group-containing compound, an amino group-containing compound, an imide group-containing compound, or a cyano group-containing compound.
3. The pressure-sensitive adhesive composition of claim 2 , wherein the amide group-containing compound is (meth)acrylamide, N,N-dialkyl (meth)acrylamide, N-alkylrol (meth)acrylamide, diacetone (meth)acrylamide, N-vinylacetamide, N,N-alkylene bisacrylamide, N-hydroxyalkyl (meth)acrylamide, N-hydroxy alkylaminoalkyl (meth)acrylamide, N-(2-aminoethyl)acrylamide hydrochloride, N-(3-aminopropyl)methacrylamide hydrochloride, N-(t-butoxycarbonyl-aminopropyl)methacrylamide, N,N-dialkylaminoalkyl (meth)acrylamide, N-vinylpyrrolidone, N-vinylcaprolactam, or (meth)acryloylmorpholine; the amino group-containing compound is aminoalkyl (meth)acrylate, N-alkylaminoalkyl (meth)acrylate, or N,N-dialkylaminoalkyl (meth)acrylate; the imide group-containing compound is N-alkyl maleimide or itaconimide; and the cyano group-containing compound is (meth)acrylonitrile.
4. The pressure-sensitive adhesive composition of claim 1 , wherein the compound containing a nitrogen atom is aminoalkyl (meth)acrylate, alkylaminoalkyl (meth)acrylate, dialkylaminoalkyl (meth)acrylate, or hydroxyalkyl (meth)acrylamide.
5. The pressure-sensitive adhesive composition of claim 1 , wherein the block copolymer includes 5 parts by weight to 50 parts by weight of the first block and 50 parts by weight to 95 parts by weight of the second block.
6. The pressure-sensitive adhesive composition of claim 1 , wherein the (meth)acrylic acid ester monomer is alkyl methacrylate.
7. The pressure-sensitive adhesive composition of claim 1 , wherein the (meth)acrylic acid ester monomer is methyl methacrylate.
8. The pressure-sensitive adhesive composition of claim 1 , wherein the second block includes a copolymer which is derived from 60 parts by weight to 99.8 parts by weight of the (meth)acrylic acid ester monomer, 0.1 parts by weight to 10 parts by weight of the copolymeric monomer having a cross-linkable functional group, and 0.1 parts by weight to 30 parts by weight of the compound containing a nitrogen atom.
9. The pressure-sensitive adhesive composition of claim 1 , wherein the (meth)acrylic acid ester monomer is alkyl acrylate, and the second block includes a copolymer which is derived from 60 parts by weight to 99.8 parts by weight of the alkyl acrylate, 0.1 parts by weight to 10 parts by weight of the copolymeric monomer having a cross-linkable functional group, and 0.1 parts by weight to 30 parts by weight of the compound containing a nitrogen atom.
10. The pressure-sensitive adhesive composition of claim 1 , further comprising a multifunctional cross-linking agent having two or more functional groups capable of reacting with the cross-linkable functional group.
11. The pressure-sensitive adhesive composition of claim 10 , wherein the cross-linking agent is included in an amount of 0.01 parts by weight to 10 parts by weight with respect to 100 parts by weight of the block copolymer.
12. The pressure-sensitive adhesive composition of claim 1 , wherein the antistatic agent is an organic salt or a metal salt.
13. The pressure-sensitive adhesive composition of claim 1 , wherein the antistatic agent is included in an amount of 0.1 parts by weight to 20 parts by weight with respect to 100 parts by weight of the block copolymer.
14. A protection film comprising:
a protection base layer; and
the pressure-sensitive adhesive composition of claim 1 , which is present at one side or both sides of the protection base layer.
15. A pressure-sensitive adhesive optical laminate comprising:
an optical film; and
a pressure-sensitive adhesive layer containing the pressure-sensitive adhesive composition of claim 1 , which is present at one side or both sides of the optical film.
16. A pressure-sensitive adhesive polarizing plate comprising:
a polarizer; and
a pressure-sensitive adhesive layer containing the pressure-sensitive adhesive composition of claim 1 , which is present at one side or both sides of the polarizer.
17. A display device comprising:
the pressure-sensitive adhesive optical laminate of claim 15 .
18. A display device comprising:
the pressure-sensitive adhesive polarizing plate of claim 16 .