Solid carbon dioxide absorbent including amine or a compound thereof for use in the capturing process of dry carbon dioxide, and method for manufacturing same
The present invention relates to a method for manufacturing a carbon dioxide absorbent and to the absorbent manufactured by the method. The method comprises: (A) a step of preparing a slurry composition including a carrier composition containing a support, an inorganic binder, and a solvent; (B) a step of preparing solid particles by spray drying the thus-prepared slurry composition; (C) a step of manufacturing a carrier by dry calcining the thus-prepared solid particles; and (D) a step of receiving an amine compound into the pores of the thus-manufactured carrier. According to the absorbent of the present invention, an absorbing reaction and a regenerating reaction at a low temperature range (less than or equal to 100° C. may be conducted, and therefore, the cost for capturing CO 2 in a dry capturing process may be expected to decrease.
1. A method for manufacturing a carbon dioxide absorbent, the method comprising the steps of:
(A) preparing a slurry composition including a carrier composition containing a support and an inorganic binder, and a solvent;
(B) preparing solid particles by spray drying the prepared slurry composition;
(C) manufacturing a carrier by dry calcining the solid particles; and
(D) receiving an amine compound into pores of the manufactured carrier.
2. The method of claim 1 , wherein the support comprises at least one of a basic support, a neutral support, and an amphoteric support.
3. The method of claim 2 , wherein the basic support includes calcium oxide, zinc oxide, and magnesium oxide, the neutral support includes carbon molecular sieve or carbon nano tubes, a magnesium and aluminum containing oxide, a magnesium and silicon containing oxide, a calcium and aluminum containing oxide, and the amphoteric support includes alumina, titanium dioxide, zirconium oxide, cesium oxide.
4. The method of claim 1 , wherein a content of the support is in a range of 20 to 85 parts by weight, based on the total weight of the carrier composition.
5. The method of claim 1 , wherein the inorganic binder includes a cement-like inorganic binder, a clay-like inorganic binder, and a ceramic-like inorganic binder.
6. The method of claim 5 , wherein the cement-like inorganic binder is calcium silicate or calcium aluminate, the clay-like inorganic binder is bentonite or kaolinite, and the ceramic-like inorganic binder is alumina sol, silica sol or boehmite.
7. The method of claim 1 , wherein a content of the inorganic binder is in a range of 5 to 50 parts by weight, based on the total weight of the carrier composition.
8. The method of claim 1 , wherein the carrier composition is contained in an amount of 15 to 60 parts by weight, based on the total weight of the slurry composition.
9. The method of claim 1 , wherein the slurry composition further includes one or more organic additives including a dispersant, a defoamer and an organic binder.
10. The method of claim 9 , wherein the dispersant is an anionic dispersant, a cationic dispersant, an amphoteric dispersant or a non-ionic dispersant, the defoamer is a metal soap- or polyester-based material, and the organic binder is one or more selected from the group consisting of a polyvinylalcohol-based material, a polyglycol-based material and methylcellulose.
11. The method of claim 1 , wherein after performing step (A), further comprising:
stirring and comminuting the slurry composition; and
removing foreign substances from the stirred and comminuted slurry composition.
12. The method of claim 1 , wherein the drying in step (C) is performed under an air atmosphere at 110 to 150° C.
13. The method of claim 1 , wherein the calcining in step (C) is performed under an air, nitrogen, helium or reducing gas atmosphere at 350 to 1000° C.
14. The method of claim 1 , wherein step (D) comprises dissolving the amine compound in a solvent; and mixing the carrier prepared in step (C) with the solvent and stirring the resultant product.
15. The method of claim 14 , wherein the amine compound comprises at least one primary amine compound, at least one piperazine-based cyclic secondary amine compound, at least one cyclic tertiary amine compound, and at least one amine compound polymer.
16. The method of claim 14 , wherein a content of the amine compound is in a range of 5 to 70 parts by weight, based on the weight of the carrier.
17. The method of claim 14 , wherein the solvent is distilled water, an organic solvent or a mixture thereof.
18. The method of claim 14 , wherein the stirring is performed at 30 to 80° C.
19. The method of claim 15 , wherein the at least one primary amine compound is selected from the group consisting of monoethanolamine (MEA), tetraethylenepentamine (TEPA), and tetraethylenetetraamine (TETA).
20. The method of claim 15 , wherein the at least one piperazine-based cyclic secondary amine compound is selected from the group consisting of piperazine and 2-piperidine ethanol.
21. The method of claim 15 , wherein the at least one cyclic tertiary amine compound is 1-(2-hydroxyethyl) piperazine.
22. The method of claim 15 , wherein the at least one amine compound polymer is polyethyleneimine (PEI).