Hydrocarbon recovery with multi-function agent
For hydrocarbon recovery from a reservoir of bituminous sands, steam and a multi-function agent are injected into the reservoir for mobilizing bitumen in the reservoir to form a fluid comprising hydrocarbons, water and the multi-function agent. The fluid is produced from the reservoir. The multi-function agent may comprise an organic molecule that reduces viscosity of oil and the interfacial tension between oil and water or a gas or rock in the reservoir, and has a partition coefficient favoring solubility in oil over water and a partial pressure in the reservoir allowing the organic molecule to be transported with steam as a vapor. The multi-function agent may comprise a solvent for reducing viscosity of oil and a surfactant for reducing interfacial tension, where both the solvent and surfactant are transportable with steam as vapor.
1. A method of oil recovery from a reservoir of bituminous sands, the method comprising:
injecting steam and vapour of a multi-function agent into a steam chamber in the reservoir for mobilizing bitumen in the reservoir to form a fluid comprising oil, water and the multi-function agent; and
producing the fluid from the reservoir,
wherein the multi-function agent comprises an organic molecule that reduces viscosity of oil and interfacial tension between oil and at least one of water, gas or rock in the reservoir, the organic molecule having a partition coefficient favouring solubility in oil over water, and a partial pressure in the steam chamber allowing the organic molecule to be transported as vapour with steam; and
wherein the organic molecule comprises a carboxylic acid group, acid anhydride group, ester group, diol group, dial group, dione group, epoxide group, ketone group, aldehyde group, ether group, or amine group, or a combination thereof and the organic molecule is non-aromatic.
2. The method of claim 1 , wherein the organic molecule has an octanol-water partition coefficient of at least 1.5.
3. The method of claim 1 , wherein the steam is injected at a temperature from about 152° C. to about 328° C. and a pressure from about 0.5 MPa to about 12.5 MPa.
4. The method of claim 1 , wherein the steam is injected through an injection well, and the fluid is produced through a production well.
5. The method of claim 4 , wherein the injection well and the production well have terminal sections that are substantially horizontal.
6. The method of claim 4 , wherein the injection well and the production well form a well pair for a steam-assisted gravity drainage (SAGD) process.
7. The method of claim 6 , wherein a temperature in the steam chamber is from about 152° C. to about 286° C. and a pressure in the steam chamber is from about 0.5 MPa to about 7 MPa.
8. The method of claim 1 , wherein a single well is used to alternately inject steam into the reservoir and produce the fluid from the reservoir.
9. The method of claim 8 , wherein the single well has a substantially horizontal section in fluid communication with the reservoir.
10. The method of claim 8 , wherein the single well has a substantially vertical section in fluid communication with the reservoir.
11. The method of claim 8 , wherein the single well is used in a cyclic steam recovery process.
12. The method of claim 8 , wherein a temperature in the reservoir is about 234° C. to about 328° C. and a pressure in the reservoir is from about 3 MPa to about 12.5 MPa.
13. The method of claim 1 , wherein the organic molecule has a non-polar portion comprising carbon and hydrogen, and a polar portion comprising hydrogen and electronegative atoms.
14. The method of claim 13 , wherein the electronegative atoms comprise oxygen or nitrogen.
15. The method of claim 13 , wherein the non-polar portion comprises a branched chain.
16. The method of claim 13 , wherein the polar portion of the organic molecule comprises a hydroxyl group, a carboxylic acid group, an acid anhydride group, an ester group, a diol group, a dial group, a dione group, an epoxide group, a ketone group, an aldehyde group, an ether group, an amine group, or a combination thereof.
17. The method of claim 13 , wherein an injection stream comprising the organic molecule is injected into the reservoir, and a partial pressure of the organic molecule in the injection stream is from about 0.25% to about 20% of a total vapour pressure in the injection stream before the injection stream enters the reservoir.
18. The method of claim 17 , wherein the injection stream comprises the organic molecule and steam.
19. A method of oil recovery from a reservoir of bituminous sands, the method comprising:
injecting steam and vapour of a multi-function agent into a steam chamber in the reservoir for mobilizing bitumen in the reservoir to form a fluid comprising oil, water, and the multi-function agent; and
producing the fluid from the reservoir,
wherein the multi-function agent comprises a solvent for reducing viscosity of oil and a surfactant for reducing interfacial tension between oil and at least one of water, gas or rock in the reservoir, the surfactant and solvent each having a partial pressure in the reservoir allowing the surfactant and solvent to be transported as vapour with steam, and
wherein the multi-function agent comprises a carboxylic acid group, acid anhydride group, ester group, diol group, dial group, dione group, epoxide group, ketone group, aldehyde group, ether group, or amine group, or a combination thereof and is non-aromatic.