IP Library Granted Patent US 9,850,367
Granted Patent B2
US 9,850,367 · App. 15/112,450 · Granted Dec 26, 2017

Polyacetal resin composition and resin molded article

Inventors: Makiko Oshima (Kanagawa, JP); Kunihiko Fujimoto (Kanagawa, JP); Masayuki Nagai (Kanagawa, JP); Hidetoshi Nawata (Tokyo, JP); Koki Sato (Niigata, JP); Ryusuke Tamaki (Tokyo, JP)
Assignee: MITSUBISHI ENGINEERING-PLASTICS CORPORATION
C08K5/30C08K5/25
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Quick Facts
Patent No.
US 9,850,367
App. No.
15/112,450
Granted
Dec 26, 2017
Kind
B2
Abstract

Provided is a polyacetal resin composition in which at least one dihydrazone compound (B) selected from the group of two kinds of dihydrazone compounds is blended in 0.02 to 5 parts by mass with respect to 100 parts by mass of a polyacetal resin (A).

Claims (26)

1. A polyacetal resin composition in which at least one dihydrazone compound (B) selected from the group selected from a dihydrazone compound (B1) represented by the following General Formula (1) and a dihydrazone compound (B2) represented by the following General Formula (2) is blended in 0.02 to 5 parts by mass with respect to 100 parts by mass of a polyacetal resin (A)

in the above formula, R 1 represents an aliphatic hydrocarbon group having 4 to 19 carbon atoms, an alicyclic hydrocarbon group having 6 to 10 carbon atoms, or an aromatic hydrocarbon group having 6 to 10 carbon atoms; R 2 to R 5 each represent an alkyl group having 1 or 2 carbon atoms

in the above formula, R 8 represents an aliphatic hydrocarbon group having 4 to 20 carbon atoms, an alicyclic hydrocarbon group having 6 to 10 carbon atoms, or an aromatic hydrocarbon group having 6 to 10 carbon atoms; and R 6 and R 7 each independently represent an alicyclic hydrocarbon group having 3 to 12 carbon atoms.

2. The polyacetal resin composition according to claim 1 , wherein, in the above General Formula (1), R 1 is an aliphatic hydrocarbon group having 6 to 12 carbon atoms.

3. The polyacetal resin composition according to claim 1 , wherein the dihydrazone compound (B) consists of the dihydrazone compound (B1) represented by the above General Formula (1).

4. The polyacetal resin composition according to claim 1 , wherein the dihydrazone compound (B) consists of the dihydrazone compound (B2) represented by the above General Formula (2).

5. The polyacetal resin composition according to claim 1 , wherein, in the above General Formula (1),

R 2 to R 5 are each a methyl group.

6. The polyacetal resin composition according to claim 1 , wherein the dihydrazone compound (B) is blended in 0.05 to 3 parts by mass with respect to 100 parts by mass of the polyacetal resin (A).

7. The polyacetal resin composition according to claim 1 , wherein a hydrazide compound (C) is further blended at a ratio of 0.01 to 1 part by mass with respect to 100 parts by mass of the polyacetal resin (A).

8. The polyacetal resin composition according to claim 7 , wherein the hydrazide compound (C) is composed of at least one kind of the group consisting of a monohydrazide compound and a dihydrazide compound.

9. The polyacetal resin composition according to claim 8 , wherein the hydrazide compound (C) is composed of a dihydrazide compound.

10. A resin molded article being obtained by molding the polyacetal resin composition according to claim 1 .

11. A polyacetal resin composition in which at least one dihydrazone compound (B) selected from the group selected from a dihydrazone compound (B1) represented by the following General Formula (1) and a dihydrazone compound (B2) represented by the following General Formula (2) is blended in 0.02 to 5 parts by mass with respect to 100 parts by mass of a polyacetal resin (A)

in the above formula, R 1 represents an alkylene group having 11 to 19 carbon atoms, or an alicyclic hydrocarbon group having 7 to 10 carbon atoms; R 2 to R 5 each independently represent a hydrogen atom or an alkyl group having 1 or 2 carbon atoms; at least one of R 2 and R 3 represents an alkyl group having 1 or 2 carbon atoms; and at least one of R 4 and R 5 represents an alkyl group having 1 or 2 carbon atoms

in the above formula, R 8 represents an aliphatic hydrocarbon group having 4 to 20 carbon atoms, an alicyclic hydrocarbon group having 6 to 10 carbon atoms, or an aromatic hydrocarbon group having 6 to 10 carbon atoms; and R 6 and R 7 each independently represent an alicyclic hydrocarbon group having 3 to 12 carbon atoms.

12. The polyacetal resin composition according to claim 11 , wherein, in the above General Formula (1), R 1 is an alkylene group having 11 to 12 carbon atoms.

13. The polyacetal resin composition according to claim 11 , wherein the dihydrazone compound (B) consists of the dihydrazone compound (B1) represented by the above General Formula (1).

14. The polyacetal resin composition according to claim 11 , wherein the dihydrazone compound (B) consists of the dihydrazone compound (B2) represented by the above General Formula (2).

15. The polyacetal resin composition according to claim 11 , wherein, in the above General Formula (1), when R 2 and R 4 are an ethyl group, R 3 and R 5 are a hydrogen atom, or

when R 2 and R 4 are a methyl group, R 3 and R 5 are a hydrogen atom or a methyl group.

16. The polyacetal resin composition according to claim 11 , wherein the dihydrazone compound (B) is blended in 0.05 to 3 parts by mass with respect to 100 parts by mass of the polyacetal resin (A).

17. The polyacetal resin composition according to claim 11 , wherein a hydrazide compound (C) is further blended at a ratio of 0.01 to 1 part by mass with respect to 100 parts by mass of the polyacetal resin (A).

18. The polyacetal resin composition according to claim 17 , wherein the hydrazide compound (C) is composed of at least one kind of the group consisting of a monohydrazide compound and a dihydrazide compound.

19. The polyacetal resin composition according to claim 18 , wherein the hydrazide compound (C) is composed of a dihydrazide compound.

20. A resin molded article being obtained by molding the polyacetal resin composition according to claim 11 .

Assignments (2)
NUNC PRO TUNC ASSIGNMENT Recorded Jan 29, 2024
From: MITSUBISHI ENGINEERING-PLASTICS CORPORATION
To: GLOBAL POLYACETAL CO., LTD.
Reel/Frame 066278/0901 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 19, 2016
From: OSHIMA, MAKIKO; FUJIMOTO, KUNIHIKO; NAGAI, MASAYUKI; NAWATA, HIDETOSHI; SATO, KOKI; TAMAKI, RYUSUKE
To: MITSUBISHI ENGINEERING-PLASTICS CORPORATION
Reel/Frame 039185/0952 →
Priority Claims (1)
JP 2014-012893 · Jan 28, 2014 · national
Continuity (1)
Related Publication 20160333170A1 · Nov 17, 2016