System for the purification of exhaust gas from an internal combustion engine
An exhaust gas cleaning system, comprising an active regenerable particulate filter and an SCR catalyst comprising a hydrothermally microporous stable zeolite having the AEI type framework and being promoted with copper, where the zeolite is SSZ-39.
1. An exhaust gas cleaning system, comprising an active regenerable particulate filter and an SCR catalyst comprising a hydrothermally microporous stable zeolite with the AEI type framework and being promoted with copper, wherein the microporous stable zeolite of the AEI type framework is SSZ-39, wherein the SCR catalyst retains 80% of the initial reduction of nitrogen oxides at 250° C. after the catalyst has been exposed to a temperature of 750° C. and a water vapor content of 100% in the exhaust gas for 13 hours.
2. The exhaust gas cleaning system of claim 1 , wherein the SCR catalyst is integrated into the particulate filter.
3. The exhaust gas cleaning system of claim 1 , wherein the atomic copper to aluminium ratio in the zeolite is between about 0.01 and about 1.
4. The exhaust gas cleaning system of claim 1 , wherein the atomic ratio of silicon to aluminium in the SCR catalyst is between 5 and 50 for the zeolite.
5. The exhaust gas cleaning system of claim 1 , wherein the SCR catalyst is deposited on a monolithic support structure.
6. An exhaust gas cleaning system, comprising an active regenerable particulate filter and an SCR catalyst comprising a hydrothermally microporous stable zeolite with the AEI type framework and being promoted with copper, wherein the microporous stable zeolite of the AEI type framework is SSZ-39, wherein the SCR catalyst retains at least 80% to 90% of the initial microporosity after aging at 600° C., and at least 30% to 40% of the initial microporosity after aging at 750° C.
7. The exhaust gas cleaning system of claim 6 , wherein the SCR catalyst is integrated into the particulate filter.
8. The exhaust gas cleaning system of claim 6 , wherein the atomic copper to aluminium ratio in the zeolite is between about 0.01 and about 1.
9. The exhaust gas cleaning system of claim 6 , wherein the atomic ratio of silicon to aluminium in the SCR catalyst is between 5 and 50 for the zeolite.
10. The exhaust gas cleaning system of claim 6 , wherein the SCR catalyst is deposited on a monolithic support structure.