Porous layer, separator formed by laminating porous layer, and non-aqueous electrolyte secondary battery including porous layer or separator
In a porous layer of the present invention, in a case where the porous layer is divided into 32 sections, a degree of variability in voidage that is measured in the 32 sections is 16.0% or lower. Each of the 32 sections is a rectangular parallelepiped whose longitudinal length is 2.3 μm, transverse length is 2.3 μm, and thickness is identical with that of the porous layer. The porous layer of the present invention and a separator formed by laminating the porous layer are suitable as a member for a non-aqueous electrolyte secondary battery that has an excellent cycle characteristic.
1. A porous layer for a non-aqueous electrolyte secondary battery separator, wherein:
when said porous layer is divided into 32 rectangular parallelepiped sections whose longitudinal length is 2.3 μm, transverse length is 2.3 μm, and thickness is identical with that of said porous layer, a degree of variability in voidage that is measured in the 32 sections is 16.0% or lower,
wherein the degree is obtained by dividing a standard deviation of the voidages by an average of voidages obtained in the 32 sections;
said porous layer contains (i) a resin which is one or more resins selected from the group consisting of polyolefins, fluorine-containing resins, fluorine-containing rubbers, aromatic polyamides, wholly aromatic polyamides, rubbers, resins whose melting point or glass transition temperature is 180° C. or higher, and water-soluble polymers and (ii) a filler;
a content of the filler is 60 mass % or higher and 99 mass % or lower relative to said porous layer containing the resin and the filler; and
the filler is a filler in which, in terms of average particle diameter obtained based on a volume, (i) D10 is 0.005 μm to 0.4 μm, D50 is 0.01 μm to 1.0 μm, and D90 is 0.5 μm to 5.0 μm and (ii) a difference between D10 and D90 is 2 μm or less.
2. A porous layer for a non-aqueous electrolyte secondary battery separator, wherein:
when said porous layer is divided into 32 rectangular parallelepiped sections whose longitudinal length is 2.3 μm, transverse length is 2.3 μm, and thickness is identical with that of said porous layer, a degree of variability in voidage that is measured in the 32 sections is 16.0% or lower wherein the degree is obtained by dividing a standard deviation of the voidages by an average of voidages obtained in the 32 sections;
said porous layer contains a resin which is one or more resins selected from the group consisting of polyolefins and fluorine-containing resins; and
said porous layer does not contain a filler.
3. The porous layer as set forth in claim 1 , wherein the degree of variability in voidage that is measured in the 32 sections is 7.0% or lower.
4. The porous layer as set forth in claim 2 wherein:
the degree of variability in viodage that is measured in the 32 section is 70% or lower.
5. The porous layer as set forth in claim 2 , wherein:
said porous layer is a resin layer containing a fibrillar resin or a granular resin.
6. A non-aqueous electrolyte secondary battery laminated separator which is formed by laminating a porous layer for a non-aqueous electrolyte secondary battery separator recited in claim 1 on one surface or each of both surfaces of a porous film which contains polyolefin as a main component.
7. A non-aqueous electrolyte secondary battery laminated separator which is formed by laminating a porous layer for a non-aqueous electrolyte secondary battery separator recited in claim 2 on one surface or each of both surfaces of a porous film which contains polyolefin as a main component.
8. A member for a non-aqueous electrolyte secondary battery, said member comprising:
a positive electrode;
a non-aqueous electrolyte secondary battery laminated separator recited in claim 6 ; and
a negative electrode, the positive electrode, the non-aqueous electrolyte secondary battery laminated separator, and the negative electrode being arranged in this order.
9. A member for a non-aqueous electrolyte secondary battery, said member comprising:
a positive electrode;
a non-aqueous electrolyte secondary battery laminated separator recited in claim 7 ; and
a negative electrode,
the positive electrode, the non-aqueous electrolyte secondary battery laminated separator, and the negative electrode being arranged in this order.
10. A non-aqueous electrolyte secondary battery comprising:
a porous layer for a non-aqueous electrolyte secondary battery separator recited in claim 1 .
11. A non-aqueous electrolyte secondary battery comprising:
a porous layer for a non-aqueous electrolyte secondary battery separator recited in claim 2 .
12. A non-aqueous electrolyte secondary battery comprising:
a non-aqueous electrolyte secondary battery laminated separator recited in claim 6 .
13. A non-aqueous electrolyte secondary battery comprising:
a non-aqueous electrolyte secondary battery laminated separator recited in claim 7 .