Pressure-sensitive adhesive composition
Provided are a pressure-sensitive adhesive composition, a protective film, an optical device, and a display device. The pressure-sensitive adhesive composition may exhibit suitable low speed and high speed peel-off strengths after forming a crosslinking structure, and have an excellent balance between them. Accordingly, the pressure-sensitive adhesive composition may exhibit an excellent protective effect when applied to a protective film, may be easily peeled in a high speed peel-off and thus advantageous for the high speed process, and may exhibit an excellent antistatic characteristic.
1. An optical device having a surface,
wherein a protective film is adhered to the surface,
wherein the protective film comprises a base film for protecting the surface and a pressure-sensitive adhesive layer on one surface of the base film,
wherein the pressure-sensitive adhesive layer comprises a crosslinked pressure-sensitive adhesive composition,
wherein the pressure-sensitive adhesive composition comprises: a polymer comprising a polymerization unit of a hydroxyalkyl (meth)acrylate in which an alkyl group has 1 carbon atom or 2 carbon atoms and a polymerization unit of a monomer represented by Formula 1; and an aliphatic isocyanate crosslinking agent,
wherein the polymer does not include a polymerization unit induced from a carboxyl group-containing monomer,
wherein crosslinking points of the polymer reacted with the crosslinking agent are only hydroxyl groups included in the polymerization unit of the hydroxyalkyl (meth)acrylate in which the alkyl group has 1 carbon atom or 2 carbon atoms or the polymerization unit of the monomer represented by Formula 1, wherein a weight ratio of the hydroxyalkyl (meth)acrylate in which the alkyl group has 1 carbon atom or 2 carbon atoms with respect to the monomer of Formula 1 in the polymer is more than 1 and not more than 5, and
wherein the surface of the optical device has a surface energy of 30 mN/m or less, and the pressure-sensitive adhesive layer of the protective film is directly adhered on the surface having the surface energy of 30 mN/m or less:
where the “Q” is hydrogen or an alkyl group, the “T” is an alkylene group, the “m” is a number ranging from 1 to 16, and a multiplication (m×c) of the “m” and the number (c) of carbon atoms in the alkylene group of the “T” is 4 or more.
2. The optical device according to claim 1 , wherein the multiplication (m×c) of the “m” and the number (c) of carbon atoms in the alkylene group of the “T” ranges from 4 to 20.
3. The optical device according to claim 1 , wherein, in Formula 1, the “Q” is an alkyl group having 1 to 8 carbon atoms.
4. The optical device according to claim 1 , wherein the polymer comprises a polymerization unit of 1 to 10 parts by weight of the hydroxyalkyl (meth)acrylate in which the alkyl group has 1 carbon atom or 2 carbon atoms and 1 to 10 parts by weight of the monomer of Formula 1.
5. The optical device according to claim 1 , wherein the polymer further comprises a polymerization unit of an alkyl (meth)acrylate.
6. The optical device according to claim 1 , wherein the aliphatic isocyanate crosslinking agent comprises at least one selected from the group consisting of an aliphatic cyclic isocyanate compound and an aliphatic non-cyclic isocyanate compound.
7. The optical device according to claim 6 , wherein the aliphatic cyclic isocyanate compound is an isocyanate compound that is isophorone diisocyanate, methylene dicyclohexyl diisocyanate, or cyclohexane diisocyanate; a dimer or trimer of the isocyanate compound; or a reaction product of the isocyanate compound and a polyol.
8. The optical device according to claim 6 , wherein the aliphatic non-cyclic isocyanate compound is an alkylene diisocyanate compound having 1 to 20 carbon atoms; a dimer or trimer of the isocyanate compound; or a reaction product of a polyol with the isocyanate compound.
9. The optical device according to claim 1 , wherein the crosslinking agent is comprised in the pressure-sensitive adhesive composition in an amount from 0.01 to 10 parts by weight relative to 100 parts by weight of the polymer.
10. The optical device according to claim 1 , wherein the pressure-sensitive adhesive composition further comprises an ionic compound.
11. The optical device according to claim 1 , wherein the pressure-sensitive adhesive composition has a peel-off strength in a range from 1 to 40 gf/25 mm, and wherein the peel-off strength is measured at a peel-off angle of 180 degrees and a peel-off speed of 0.3 m/min with respect to an adherend having surface energy of 30 mN/m or less in a state where a crosslinking structure is realized in the pressure-sensitive adhesive composition.
12. The optical device according to claim 1 , wherein the pressure-sensitive adhesive composition has a peel-off strength in a range from 10 to 150 gf/25 mm, and wherein the peel-off strength is measured at a peel-off angle of 180 degrees and a peel-off speed of 30 m/min with respect to an adherend having surface energy of 30 mN/m or less in a state where a crosslinking structure is realized in the pressure-sensitive adhesive composition.
13. The optical device according to claim 1 , wherein the pressure-sensitive adhesive composition has a peel-off electrostatic discharge in a range of 0.5 kV or less, and wherein the peel-off electrostatic discharge is measured at a peel-off angle of 180 degrees and a peel-off speed of 40 m/min with respect to an adherend having surface energy of 30 mN/m or less in a state where a crosslinking structure is realized in the pressure-sensitive adhesive composition.
14. The optical device according to claim 1 , wherein the surface having the surface energy of 30 mN/m or less is a high hardness layer having a pencil hardness of 1H or more, a glariness preventing layer, or an anti-reflection layer.
15. A display device, comprising the optical device of claim 1 .