Sliding element for lubricated sliding system
The invention relates to a chain guide, respectively a chain tensioner for use in a lubricated sliding system, comprising a surface layer or bearing or comprising a sliding element comprising a surface layer, the surface layer being mainly made of a polymeric material containing a matrix polymer and optionally other components dispersed in said matrix polymer, wherein the matrix polymer consists of a semi-crystalline polyamide (SCPA) having a tensile modulus at 140° C. of at least 800 MPa (measured by the method according to ISO 527-1A). The invention also relates to a power train drive system comprising an engine, a transmission differential and a drive shaft system, a drive chain and a plastic component comprising a sliding element in contact with the lubricated drive chain, wherein the chain guide, the chain tensioner, respectively the sliding element has a coefficient of friction (Co F), measured in lubrication oil at 140° C. at a nominal contact pressure of 1 MPa and a speed of 1 m/s, of at most 0.07.
1. A chain guide or chain tensioner for use in a lubricated sliding system, wherein the chain guide or chain tensioner comprises:
a sliding element which includes (i) a plastic body supporting the sliding element, and (ii) a surface layer on the plastic body having a thickness in a range of 50 μm-5 mm, wherein
the plastic body and the surface layer are formed of different injection molded polymeric materials, and wherein
the injection molded polymeric material forming the surface layer comprises:
(A) a matrix polymer which consists of a semi-crystalline polyamide (SCPA) having a tensile modulus at 140° C. of at least 800 MPa (measured by the method according to ISO 527-1A) and, optionally,
(B) other components dispersed in and/or blended with said matrix polymer, wherein
the SCPA comprises:
(A.1) a semi-crystalline aliphatic polyamide, and
(A.2) 0.01-10 wt. % relative to the total weight of the polymeric material of a semi-crystalline semi-aromatic polyamide having a Tg of at least 110° C. and a melting enthalpy of at least 70 J/g.
2. The chain guide or chain tensioner according to claim 1 , wherein the SCPA has a tensile modulus at 140° C. which is in a range of 850-1050 MPa.
3. The chain guide or chain tensioner according to claim 1 , wherein the semi-crystalline aliphatic polyamide (A.1) has a glass transition temperature (Tg) of at least 80° C. and a melting enthalpy (ΔH) of at least 70 J/g.
4. The chain guide or chain tensioner according to claim 1 , wherein the SCPA has a melting temperature (Tm) and the sliding element has been annealed at a temperature between 100 and 20° C. below Tm for at least 1 hour.
5. The chain guide or chain tensioner according to claim 1 , wherein the injection molded polymeric material comprises at least one other component selected from the group consisting of:
(B.a) 0.01-20 wt. % of polymers other than the semi-crystalline polyamide;
(B.b) 0.01-20 wt. % of solid lubricant particles comprising a material chosen from the group consisting of molybdenum disulfide, graphite, boron nitride and silane nitride, and any mixtures thereof;
(B.c) 0.01-5 wt. % of an inorganic nucleating agent comprising micro-talc and/or carbon black; and
(B.d) 0.01-10 wt. % of inorganic fillers other than (B.b) and (B.c) and/or fibrous reinforcing agents; wherein
the wt. % are all relative to the total weight of the polymeric material.
6. The chain guide or chain tensioner according to claim 1 , wherein the plastic body of the sliding element consists of a fibre reinforced thermoplastic material and wherein the surface layer of the sliding element consists of the injection molded polymeric material which is non-reinforced.
7. The chain guide or chain tensioner according to claim 1 , wherein the sliding element has a coefficient of friction (CoF) in a range of 0.005-0.07 as measured in lubrication oil Shell Helix Super Mineral Motor Oil 15W-40 at a contact temperature of 140° C., a nominal contact pressure of 1 MPa and a sliding speed of 1 m/s.
8. A lubricated sliding system comprising a power train drive system which includes an engine, a transmission differential, a drive shaft system and the chain guide or chain tensioner according to claim 1 .
9. A power train drive system comprising:
an engine,
a transmission differential,
a drive shaft system,
a drive chain, and
a sliding element comprising (i) a plastic body supporting the sliding element, and (ii) a surface layer on the plastic body having a thickness in a range of 50 μm-5 mm in sliding contact with a lubricated drive chain, wherein
the sliding element has a coefficient of friction (CoF) of at most 0.07 as measured in lubrication oil Shell Helix Super Mineral Motor Oil 15W-40 at a contact temperature of 140° C., a nominal contact pressure of 1 MPa and a sliding speed of 1 m/s, and wherein
the surface layer of the sliding element being comprised of an injection molded matrix polymer which consists of a semi-crystalline polyamide (SCPA) having a tensile modulus at 140° C. of at least 800 MPa (measured by the method according to ISO 527-1A), wherein the SCPA comprises:
(A.1) a semi-crystalline aliphatic polyamide, and
(A.2) 0.01-10 wt. %, relative to the total weight of the matrix polymer, of a semi-crystalline semi-aromatic polyamide having a Tg of at least 110° C. and a melting enthalpy of at least 70 J/g, and wherein
the plastic body is formed of an injection molded polymeric material which is different from the injection molded matrix polymer of the surface layer.
10. The power train drive system according to claim 9 , further comprising a chain guide or chain tensioner which includes the sliding element.