IP Library Granted Patent US 9,895,649
Granted Patent B2
US 9,895,649 · App. 14/681,241 · Granted Feb 20, 2018

High solids magnesium hydroxide sea water slurries

Inventors: Joe Christopher Brown (Molino, FL); Jerry Elliott Rademan (Atlanta, GA); Peyton L. Pool, Sr. (Royal Palm Beach, FL); Mark Alexander Shand (Arden, NC); James O. Williams (Port St. Joe, FL)
Assignee: Premier Magnesia, LLC
B01D53/1493B01D53/48B01D53/80B01D2253/112B01D2257/30
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Quick Facts
Patent No.
US 9,895,649
App. No.
14/681,241
Granted
Feb 20, 2018
Kind
B2
Abstract

A high solids magnesium hydroxide slurry may be provided. The slurry may include a magnesium hydroxide compound and a carbohydrate-based viscosity control agent. The slurry may further include sea water as at least a portion of the liquid component. The high solids magnesium hydroxide slurry may be utilized in connection with exhaust scrubber systems for removing SOx and NOx compounds from exhaust gas emissions.

Claims (35)

1. A composition comprising:

a slurry including:

a magnesium hydroxide compound;

sea water; and

a carbohydrate-based viscosity control agent;

wherein the slurry includes between about 25 wt. % to about 70 wt. % magnesium hydroxide solids.

2. The composition of claim 1 , wherein the magnesium hydroxide compound includes powdered magnesium hydroxide.

3. The composition of claim 1 , wherein the magnesium hydroxide compound includes hydrated magnesium oxide.

4. The composition of claim 1 , wherein the carbohydrate-based viscosity control agent includes one or more of a monosaccharide, a disaccharide, and a polysaccharide.

5. The composition of claim 4 , wherein the carbohydrate-based viscosity control agent includes one or more of sucrose, glucose, dextrose, fructose, galactose, maltose, lactose, cellulose, amalose, and starch.

6. The composition of claim 1 , wherein the carbohydrate-based viscosity control agent includes a polyhydric alcohol.

7. The composition of claim 6 , wherein the carbohydrate-based viscosity control agent includes one or more of mannitol, sorbitol, glycol, glycerol, erythritol, threitol, arabitol, xylitol, ribitol, galactitol, fucitol, inositol, volemitol, isomatol, maltitol, and lactitol.

8. The composition of claim 1 , wherein the carbohydrate-based viscosity control agent includes a polyhydric alcohol-based surfactant.

9. The composition of claim 8 , wherein the carbohydrate-based viscosity control agent includes one or more of polysorbate 20-(polyoxyethylene (20) sorbitan monolaurate), polysorbate 40-(polyoxyethylene(20) sorbitan monopalmitate), polysorbate 60-(polyoxyethylene (20) sorbitan monostearate), polysorbate 80-(polyoxyethylene (20) sorbitan monooleate), sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, and sorbitan monooleate.

10. The composition of claim 1 , wherein the slurry includes between about 40 wt. % to about 60 wt. % magnesium hydroxide solids.

11. The composition of claim 1 , wherein the slurry includes between about 0.1 wt. % to about 15 wt. % of the carbohydrate-based viscosity control agent.

12. The composition of claim 1 , wherein the slurry has a viscosity of between about 20 centipoise and about 600 centipoise after about 15 days.

13. A method comprising:

providing a magnesium compound;

providing sea water;

providing a carbohydrate-based viscosity control agent; and

mixing the magnesium compound the sea water and the carbohydrate-based viscosity control agent to form a high solids slurry; wherein the slurry includes between about 25 wt. % to about 70 wt. % magnesium hydroxide solids.

14. The method of claim 13 , wherein providing the magnesium compound and the carbohydrate-based viscosity control agent includes pre-blending the magnesium compound and the carbohydrate-based viscosity control agent.

15. The method of claim 13 , wherein the magnesium compound includes a magnesium hydroxide powder.

16. The method of claim 13 , wherein the magnesium compound includes a magnesium oxide powder.

17. The method of claim 16 , wherein mixing the magnesium compound, the sea water and the carbohydrate-based viscosity control agent includes hydrating the magnesium oxide powder to form magnesium hydroxide.

18. The method of claim 13 , wherein the high solids slurry includes between about 40 wt. % to about 60 wt. % magnesium hydroxide solids.

19. The method of claim 13 , wherein the high solids slurry includes between about 0.1 wt. % to about 15 wt. % of the carbohydrate-based viscosity control agent.

20. The method of claim 13 , wherein the high solids slurry exhibits a viscosity of between about 20 centipoise and about 600 centipoise after about 15 days.

21. The method of claim 13 , wherein the carbohydrate-based viscosity control agent includes one or more of a monosaccharide, a disaccharide, and a polysaccharide.

22. The method of claim 21 , wherein the carbohydrate-based viscosity control agent includes one or more of sucrose, glucose, dextrose, fructose, galactose, maltose, lactose, cellulose, amalose, and starch.

23. The method of claim 13 , wherein the carbohydrate-based viscosity control agent includes a polyhydric alcohol.

24. The method of claim 23 , wherein the carbohydrate-based viscosity control agent includes one or more of mannitol, sorbitol, glycol, glycerol, erythritol, threitol, arabitol, xylitol, ribitol, galactitol, fucitol, inositol, volemitol, isomatol, maltitol, and lactitol.

25. The method of claim 13 , wherein the carbohydrate-based viscosity control agent includes a polyhydric alcohol-based surfactant.

26. The method of claim 25 , wherein the carbohydrate-based viscosity control agent includes one or more of polysorbate 20-(polyoxyethylene(20) sorbitan monolaurate), polysorbate 40-(polyoxyethylene(20) sorbitan monopalmitate), polysorbate 60- (polyoxyethylene(20) sorbitan monostearate), polysorbate 80-(polyoxyethylene (20) sorbitan monooleate), sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, and sorbitan monooleate.

Assignments (3)
RELEASE OF SECURITY INTEREST Recorded Jul 25, 2025
From: WELLS FARGO BANK, NATIONAL ASSOCIATION
To: PREMIER MAGNESIA, LLC
Reel/Frame 071837/0889 →
SECURITY AGREEMENT Recorded May 2, 2018
From: PREMIER MAGNESIA, LLC
To: WELLS FARGO BANK, NATIONAL ASSOCIATION
Reel/Frame 046065/0802 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 8, 2015
From: BROWN, JOE CHRISTOPHER; RADEMAN, JERRY ELLIOTT; POOL, PEYTON L., SR.; SHAND, MARK ALEXANDER; WILLIAMS, JAMES O.
To: PREMIER MAGNESIA, LLC
Reel/Frame 035357/0680 →
Continuity (2)
Provisional Application 61976577 · Apr 8, 2014
Related Publication 20150283499A1 · Oct 8, 2015