IP Library Granted Patent US 9,896,358
Granted Patent B2
US 9,896,358 · App. 15/186,608 · Granted Feb 20, 2018

Method of treating cellulose containing waste water sludge for the manufacture of linerboard and cellulosic ethanol production

Inventors: Fabricio Saab Pereira (Araraquara-SP, BR); Adriano Marques Gomes (Araraquara-SP, BR)
Assignee: SOLENIS TECHNOLOGIES, L.P.
C02F1/68C02F11/12C07C29/00D21C11/00C02F2103/28
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Quick Facts
Patent No.
US 9,896,358
App. No.
15/186,608
Granted
Feb 20, 2018
Kind
B2
Abstract

The current process relates to the treatment of a primary sludge that is produced from waste water treatment facilities such as a pulp mill or a pulp and paper mills. It further relates to a process of using the primary sludge in the production of cellulosic ethanol. It further relates to the use of the treated primary sludge in the manufacture of recycled linerboard.

Claims (19)

1. A process for preparing a primary sludge, to be used in the manufacture of cellulosic ethanol, from industrial water effluent, including the step of treating the effluent with a chemical composition comprising benzalkonium chloride; sodium hypochlorite; and oxytetracycline.

2. The process according to claim 1 , wherein the solids of the primary sludge comprises at least 20% by weight of cellulosic fiber, can comprise at least 30% by weight fiber and may comprise at least 40% by weight cellulosic fiber.

3. The process according to claim 1 , wherein the chemical composition is added to the effluent stream in an amount of from about 100 ppm to about 1,000 ppm.

4. The process according to claim 1 , wherein the primary sludge is at least 40% by weight total solids.

5. The process according to claim 1 , wherein the amount of benzalkonium chloride relative to the total actives is from 40-75%, the amount of sodium hypochlorite is from 8-20% and the amount of oxytetracycline is from 0.1-1%.

6. The process according to claim 1 , wherein the chemical composition is added to the effluent stream prior to a filter press.

7. The process according to claim 1 , wherein the chemical composition is added to the industrial effluent stream at the filter press.

8. The process according to claim 1 , wherein the bacterial count in the primary sludge is less than 100,000.

9. The process according to claim 1 , wherein bio-organism activity in the aeration pond is unaffected by the chemical composition.

10. The process according to claim 1 , wherein the industrial effluent stream is from a pulp mill or a pulp and paper mill.

11. A process for preparing cellulosic ethanol comprising preparing a primary sludge from industrial effluent stream, as defined in claim 1 , and using the resulting primary sludge in the production of ethanol.

12. The process according to claim 11 , wherein the solids of the primary sludge comprises at least 20% by weight cellulosic fiber.

13. A process for preparing a primary sludge, to be used in the manufacture of recycled linerboard, from industrial waste effluent, including the step of treating the effluent with a chemical composition comprising benzalkonium chloride; sodium hypochlorite; and oxytetracycline.

14. The process according to claim 13 , wherein the solids of the primary sludge comprises at least 20% by weight cellulosic fiber.

15. The process according to claim 13 , wherein the chemical composition is added to the waste effluent stream in an amount of from about 100 ppm to about 1000 ppm.

16. The process according to claim 13 , wherein the amount of benzalkonium chloride relative to the total actives is from 40-75%, the amount of sodium hypochlorite is from 8-20% and the amount of oxytetracycline is from 0.1-1%.

17. The process according to claim 13 , wherein the chemical composition is added to the industrial effluent stream prior to the filter press.

18. The process according to claim 13 , wherein the chemical composition is added to the industrial effluent stream at the filter press.

19. The process according to claim 13 , wherein bio-organism activity in the aeration pond is unaffected by the chemical composition.

Assignments (15)
RELEASE OF SECURITY INTEREST Recorded Nov 14, 2025
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
To: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 073564/0864 →
SECURITY INTEREST Recorded Nov 14, 2025
From: CHEM-AQUA, INC.; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; NCH CORPORATION; NCH LIFE SCIENCES LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 073570/0838 →
RELEASE OF 2023 NOTES PATENT SECURITY INTERESTS Recorded Oct 10, 2025
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
To: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 073074/0198 →
SECURITY AGREEMENT (NOTES) Recorded Oct 10, 2025
From: DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 073061/0885 →
SECURITY AGREEMENT (2024 NOTES) Recorded Jun 24, 2024
From: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 067824/0278 →
2023 NOTES PATENT SECURITY AGREEMENT Recorded Jul 7, 2023
From: BIRKO CORPORATION; SOLENIS TECHNOLOGIES, L.P.; INNOVATIVE WATER CARE, LLC; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE GLOBAL CORPORATION
To: BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
Reel/Frame 064225/0170 →
SECURITY AGREEMENT (NOTES) Recorded Sep 14, 2022
From: SOLENIS TECHNOLOGIES, L.P.; INNOVATIVE WATER CARE, LLC
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A. AS COLLATERAL AGENT
Reel/Frame 061432/0821 →
NOTES SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
Reel/Frame 058103/0066 →
RELEASE OF SECURITY INTEREST Recorded Nov 10, 2021
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 058856/0724 →
ABL PATENT SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: BANK OF AMERICA, N.A.
Reel/Frame 058102/0122 →
TERM LOAN PATENT SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: GOLDMAN SACHS BANK USA
Reel/Frame 058102/0407 →
RELEASE OF SECURITY INTEREST Recorded Nov 10, 2021
From: CITIBANK, N.A.
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 058848/0636 →
SECOND LIEN NOTICE AND CONFIRMATION OF GRANT OF SECURITY INTEREST IN PATENTS Recorded Jul 20, 2018
From: SOLENIS TECHNOLOGIES, L.P.
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 046629/0213 →
FIRST LIEN NOTICE AND CONFIRMATION OF GRANT OF SECURITY INTEREST IN PATENTS Recorded Jul 20, 2018
From: SOLENIS TECHNOLOGIES, L.P.
To: CITIBANK, N.A., COLLATERAL AGENT
Reel/Frame 046595/0241 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 20, 2016
From: PEREIRA, FABRICIO SAAB; GOMES, ADRIANO MARQUES
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 038953/0265 →
Continuity (1)
Related Publication 20170362106A1 · Dec 21, 2017