Polymer dispersed liquid crystal elastomers (PDLCE)
The present invention relates to a method of producing liquid crystal elastomer (LCE) based components. The method comprises the steps of (i) providing or creating micro-sized or nano-sized LCE particles, (ii) dispersing the particles in an uncured liquid polymer, (iii) aligning the nematic directors of the particles and, (iv) shaping and curing the matrix/particles mixture. The composite material formed by this method is a polymer dispersed liquid crystal elastomer (PDLCE) with custom-tailored properties which can be shaped into arbitrary forms.
1. A method of producing a thermomechanically responsive liquid crystal elastomer based component of arbitrary shape, comprising the following steps:
a. providing micro-sized or nano-sized thermomechanically anisotropic liquid crystal elastomer particles,
b. dispersing said liquid crystal elastomer particles in a pre-polymerization mixture of a polymer,
c. aligning the nematic directors of said liquid crystal elastomer particles in said mixture, and
d. shaping and curing said mixture while keeping aligned said nematic directors of said liquid crystal elastomer particles.
2. The method according to claim 1 , wherein said liquid crystal elastomer particles have a single domain or consist of a plurality of partially ordered domains.
3. The method according to claim 1 , wherein said step of providing micro-sized or nano-sized anisotropic liquid crystal elastomer particles includes the step of splitting macroscopic main-chain or side-chain liquid crystal elastomers by a mechanical process, in particular by milling or grinding.
4. The method according to claim 1 , wherein the size of said liquid crystal elastomer particles is in the range of between 100 nm and 100 μm.
5. The method according to claim 1 , wherein different types of said liquid crystal elastomer particles are provided and dispersed in said pre-polymerization mixture.
6. The method according to claim 1 , wherein said liquid crystal elastomer particles are aligned by means of at least one of a magnetic field, an electric field, and a mechanical stress field.
7. The method according to claim 6 , wherein the degree of alignment of said liquid crystal elastomer particles is controlled by varying the strength of the aligning field.
8. The method according to claim 6 , wherein the alignment direction of said liquid crystal elastomer particles is controlled by spatial modulation of the aligning field.
9. The method according to claim 1 , wherein said mixture is heat or UV cured.
10. The method according to claim 9 , wherein a spatial modulation of particle ordering or alignment of said liquid crystal elastomer particles in said mixture is achieved by performing sequential alignment steps of said liquid crystal elastomer particles and locally selective UV curing of different parts of the pre-polymerization mixture after each alignment step.
11. The method according to claim 1 , wherein said components are functionalized by incorporating conductive, ferroelectric, ferromagnetic or photoactive materials into pre-polymerization mixture.