Paper and paper articles and method for making same
This invention relates to a paper material containing cellulosic fibers and from about 0.1 to about 6.0 wt % by weight dry basis expandable microspheres and a density of at least about 6.0 lb/3000 ft 2 /mil and articles formed there from such as file folders.
1 - 36 . (canceled)
37 . A paper material for use in the manufacture of paper articles, comprising a web of cellulosic fibers and from about 0.1 to about 6 wt % based upon a total weight of the web on a dry basis of expanded microspheres, the paper web having a density equal to or greater than 7.5 lb/3000 ft 2 /mil; a caliper after calendaring of from about 3 mils to about 25 mils.
38 . The paper material according to claim 37 , wherein the paper web has a density of from about 6.0 lb/3000 ft 2 /mil to about 13.0 lb 3000 ft 2 /mil.
39 . The paper material according to claim 37 , wherein the paper web has a caliper after calendaring of from about 3.0 to about 14.0 mils.
40 . The paper material according to claim 37 , comprising from about 0.25 to about 5.0 wt. % based upon a total weight of the web on a dry basis of expanded micro spheres.
41 . The paper material according to claim 37 , comprising from 0.5 to about 3.0 wt. % based upon a total weight of the web on a dry basis of expanded microspheres.
42 . The paper material according to claim 37 , wherein the expanded microspheres in the paper web comprises synthetic polymeric microspheres.
43 . The paper material according to claim 37 , wherein the paper web has a basis weight of from about 20 lb/3000 ft 2 to about 300 lb/3000 ft 2 .
44 . The paper material according to claim 37 , wherein the paper web has a basis weight of from about 20 lb/3000 ft 2 to about 200 lb/3000 ft 2 .
45 . The paper material according to claim 37 , wherein the paper web has a basis weight of from about 28 lb/3000 ft 2 to about 180 lb/3000 ft 2 .
46 . The paper material according to claim 37 , wherein the expanded microspheres in the paper web comprise microspheres made from at least one polymeric material selected from the group consisting of methyl methacrylate, ortho-chlorostyrene, polyortho-chlorostyrene, polyvinylbenzyl chloride, acrylonitrile, vinylidene chloride, para-tert-butyl styrene, vinyl acetate, butyl acrylate, styrene, methacrylic acid, and vinylbenzyl chloride.
47 . The paper material according to claim 37 , wherein the fibers in the paper web comprise from about 30 to about 100% by weight dry basis softwood fibers, from about 70 to about 0% by weight dry basis hardwood fibers and 0 to about 50% by weight dry basis post consumer waste.
48 . The paper material according to claim 37 , wherein the microspheres have an expanded diameter of up to about 60 microns.
49 . The paper material according to claim 37 , wherein the web has been calendered in a calendaring apparatus having one or more nips where the pressure at any nip is not more than about 350 lbs/lineal inch.
50 . The paper material according to claim 49 , wherein said pressure is equal to or less than about 280 lbs/lineal inch.
51 . The paper material according to claim 49 , wherein said pressure is equal to or less than about 250 lbs/lineal inch.
52 . The paper material according to claim 49 , wherein said pressure is equal to or less than about 100 lbs/lineal inch.
53 . The paper material according to claim 49 , wherein said pressure is equal to or less than about 50 lbs/lineal inch.
54 . The paper material according to claim 37 , wherein the paper material comprises at least one reverse die cut edge.
55 . The paper material according to claim 37 , wherein the paper material comprises at least one reverse die cut edge which exhibits an improved resistance to inflicting cuts upon human skin than does a paper material that is the same except that it does not contain expanded microspheres and does not have a density at least 7.5 lb/3000 ft2/mil.
56 . The paper material according to claim 55 , wherein the paper material exhibits a Cutting Index of less than about 40 when analyzed according to the Cutting Index 30 test.
57 . The paper material according to claim 37 , wherein the paper material exhibits a Cutting Index of less than about 40 when analyzed according to the Cutting Index 30 test.
58 . The paper material of claim 37 , wherein the paper material exhibits a GM Fold equal to or great than about 200.
59 . The paper material according to claim 58 , wherein the GM Fold is equal to or greater than about 350.
60 . The paper material according to claim 58 , wherein the GM Fold is equal to or greater than about 450.
61 . The paper material according to claim 37 , wherein said paper material exhibits a higher GM Fold than does a paper material that is the same except that it does not contain from about 0.1 to about 6 wt % based upon a total weight of the web on a dry basis expanded microspheres and does not have a density at least 7.5 lb/3000 ft 2 /mil.
62 . The paper material according to claim 37 , wherein said paper material exhibits a GM Fold substantially the same as that exhibited by a second paper material which is substantially the same as said paper material except it does not contain from about 0.1 to about 6 wt % based upon a total weight of the web on a dry basis expanded microspheres and has a basis weight that is 5% greater than the basis weight of said paper material.
63 . A method for making the paper material according to claim 37 , comprising
providing a papermaking furnish containing cellulosic fibers and from about 0.1 to about 6 wt % by weight dry basis expanded or expandable microspheres;
forming a fibrous web from the papermaking furnish;
drying the web; and
calendering the web to a caliper of from about 3 to about 25 mils and a density equal to or greater than 7.5 lb/3000 ft 2 /mil.
64 . An article of manufacture having a body formed from the paper material according to claim 37 .
65 . The article according to claim 64 , wherein said body comprises a substantially planar first portion and a substantially planar second portion, said first portion and second portion connect along a fold line and are capable of flexing along said line.
66 . The paper material according to claim 37 , wherein the paper web has a basis weight that is equal to or greater than about 90 lb/3000 ft 2 .
67 . The paper material according to claim 37 , wherein the paper web has a basis weight of from about 90 lb/3000 ft 2 to about 300 lb/3000 ft 2 .
68 . The paper material according to claim 37 , wherein the paper web has a basis weight of from about 100 lb/3000 ft 2 to about 300 lb/3000 ft 2 .
69 . The paper material according to claim 37 , wherein said paper web has a caliper after calendaring of from about 7 to about 18 mils.
70 . The paper material according to claim 37 , wherein said paper web has a caliper after calendaring of from about 8 to about 14 mils.
71 . The paper material according to claim 37 , wherein said paper web has a caliper after calendaring of from about 9 to about 12 mils.
72 . The paper material according to claim 37 , wherein said paper web has a caliper after calendaring of from about 10 to about 11.5 mils.