IP Library Granted Patent US 7,575,625
Granted Patent B2
US 7,575,625 · App. 11/226,196 · Granted Aug 18, 2009

Method for separating solids from gas scrubbers

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Quick Facts
Patent No.
US 7,575,625
App. No.
11/226,196
Granted
Aug 18, 2009
Kind
B2
Abstract

A solid is separated from a gas scrubber by collecting a solids burden not collected at a solids-collection device of a flue gas desulfurization system by adding at least one flocculant, flocculation aid or mixtures thereof, while using a separating device; wherein te flue-gas desulfurization system contains at least one absorption device disposed downstream from said solids-collection device.

Claims (19)

1. A method for separating a solid from a gas scrubber, comprising:

collecting a solids burden not collected at a solids-collection device of a flue gas desulfurization system by adding at least one flocculant, flocculation aid or mixtures thereof, while using a separating device;

wherein said flocculant, flocculation aid or mixtures thereof are a cationic acrylic acid or methacrylic acid ester or copolymer of such ester with acrylamide;

wherein the addition of the flocculant, flocculation aid or mixtures thereof into the separating device results in agglomeration of the particles, the agglomerated particles having a particle and/or floc diameter of at least >15 μm;

wherein said flue-gas desulfurization system comprises

at least one absorption device, which is disposed downstream from said solids-collection device,

wherein absorption device is a prescrubber of said flue-gas desulfurization system;

wherein a proportioning device for proportioning the flocculant and/or flocculation aid is disposed upstream from the separating device; and

said separating device is integrated in a prescrubber circuit; and

wherein the solids burden in the absorption device is less than 2 g of solids per liter of scrubbing fluid.

2. The method according to claim 1 wherein an electrofilter is used as the solids-collection device.

3. The method according to claim 1 wherein a sulfur dioxide absorption system is used as the absorption device.

4. The method according to claim 1 wherein a hydrocyclone is used as the separating device.

5. The method according to claim 1 wherein solid/liquid separation is performed by addition of at least one flocculant, flocculation aid or mixtures thereof into the separating device.

6. The method according to claim 5 wherein a hydrocyclone is used as the separating device.

7. The method according to claim 1 wherein the flocculant, flocculation aid or mixtures thereof comprise a water-in-water polymer dispersion.

8. The method according to claim 1 comprising branching off a partial stream from the absorption device to the separating device, and,

after solid/liquid separation has taken place in the separating device, separating said branched off partial stream as overflow and underflow,

returning a fine fraction to the absorption system while feeding the coarse fraction in the underflow to a wastewater device.

Assignments (6)
RELEASE OF PATENT SECURITY AGREEMENT Recorded Mar 18, 2013
From: THE BANK OF NOVA SCOTIA
To: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; AQUALON COMPANY; ISP INVESTMENTS INC.; HERCULES INCORPORATED
Reel/Frame 030025/0320 →
SECURITY AGREEMENT Recorded Sep 16, 2011
From: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; HERCULES INCORPORATED; AQUALON COMPANY; ISP INVESTMENT INC.
To: THE BANK OF NOVA SCOTIA, AS ADMINISTRATIVE AGENT
Reel/Frame 026918/0052 →
RELEASE OF SECURITY INTEREST Recorded Apr 13, 2010
From: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
To: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; AQUALON COMPANY; HERCULES INCORPORATED
Reel/Frame 024218/0928 →
SECURITY AGREEMENT Recorded Dec 3, 2008
From: ASHLAND LICENSING AND INTELLECTUAL PROPERTY...; AQUALON COMPANY; HERCULES INCORPORATED
To: BANK OF AMERICA, N.A. AS ADMINISTRATIVE AGENT
Reel/Frame 021924/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 5, 2006
From: STOCKHAUSEN GMBH
To: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC
Reel/Frame 017870/0643 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 23, 2005
From: SEIDA, FRANK; GRAF, PETER
To: STOCKHAUSEN GMBH
Reel/Frame 017265/0227 →