Golf ball layer compositions formed from oxirane functional endcapped polymers

1. A golf ball comprising a core and a cover, wherein at least a portion of the golf ball is formed from a composition comprising:

an intermediate formed from a polyurea prepolymer and an oxirane functional resin, wherein the oxirane functional resin comprises reaction products of phenols or carboxylic acids and epichlorohydrin, reaction products of an aliphatic polyols and epichlorohydrin, oxidized polvolefins, or combinations thereof and wherein the intermediate comprises at least one terminal group comprising an oxirane functionality having the structure:

a curing agent.

2. The golf ball of claim 1 , wherein the curing agent comprises reactive functional groups selected from the group consisting of hydroxy groups, amino groups, thiol groups, epoxy groups, anhydride groups, and combinations thereof.

3. The golf ball of claim 2 , wherein the curing agent further comprises non-reactive functional groups selected from the group consisting of chlorine, bromine, and substituted sulfur moieties.

4. The golf ball of claim 1 , wherein the oxirane functional resin comprises glycidol, a cycloaliphatic epoxy resin, or a mixture thereof

5. The golf ball of claim 1 , wherein the oxirane functional resin comprises glycidyl glycidate; 2,3-epoxybutyl-3,4-epoxypentanoate; 3,4-epoxy-3,4-epoxyhexyl; 3,4-epoxypentanoate; diglycidyl adipate; diglycidyl isophthalate; di(2,3-epoxybutyl) adipate; di(2,3-epoxybutyl) oxalate; di(2,3-epoxyhexyl) succinate; di(3,4-epoxybutyl) maleate; di(2,3-epoxyoctyl) pimelate; di(2,3-epoxybutyl) phthalate; di(2,3 -epoxyoctyl) tetrahydrophthalate; di(4,5-epoxydodecyl) maleate; di(2,3-epoxybutyl) teraphthalate; di(2,3-epoxypentyl) thiodipropionate; di(5,6-epoxytetradecyl) diphenyldicarboxylate; di(3 ,4-epoxyheptyl) sulfonyldibutyrate; di(5,6-epoxypentadecyl) maleate; di(2,3-epoxybutyl) azelate; di(3,4-epoxybutyl) citrate; di(5,6-epoxyoctyl) cyclohexane- 1,3-dicarboxylate; di(4,5-epoxyoctadecyl) malonate; tri(2,3-epoxybutyl)-1 ,2,4-butanetricarboxylate; or mixtures thereof.

6. The golf ball of claim 1 , wherein the curing agent comprises saturated or unsaturated primary, secondary, and tertiary amines and adducts thereof, polyamides, carbamates, phenols, thiols, anhydrides, low molecular weight acids, and mixtures thereof

7. The golf ball of claim 1 , wherein the intermediate has the following structure:

wherein R and R 1 independently comprise straight or branched hydrocarbon moieties, acyclic groups, cyclic groups, heterocyclic groups, aromatic groups, phenyl groups, hydrocarbylene group, or a mixture thereof.

8. The golf ball of claim 1 , wherein the portion is the cover of the golf ball.

9. The golf ball of claim 6 , wherein the curing agent is selected from the group consisting of ethylene diamine; hexamethylene diamine; 1-methyl-2,6-cyclohexyl diamine; 2,2,4- and 2,4,4-trimethyl- 1,6-hexanediamine; 4,4′-bis-(sec-butylamino)-dicyclohexylmethane and derivatives thereof 1,4-bis-(sec-butylamino)-cyclohexane; 1,2-bis-(sec-butylamino)-cyclohexane; 4,4′-dicyclohexylmethane diamine; 1,4-cyclohexane-bis-(methylamine); 1,3-cyclohexane-bis-(methylamine), isomers, and mixtures thereof diethylene glycol bis-(aminopropyl) ether; 2-methylpentamethylene-diamine; diaminocyclohexane, isomers, and mixtures thereof; diethylene triamine; triethylene tetramine; tetraethylene pentamine; propylene diamine; 1,3-diaminopropane; dimethylamino propylamine; diethylamino propylamine; imido-bis-(propylamine); monoethanolamine, diethanolamine; triethanolamine; monoisopropanolamine, diisopropanolamine; isophoronediamine; 4,4′-methylenebis-(2-chloroaniline); 3,5-dimethylthio-2,4-toluenediamine; 3,5-dimethylthio-2,6-toluenediamine; 3,5diethylthio-2,4-toluenediamine; 3,5-diethylthio-2,6-toluenediamine; m-phenylene diamine; 4,4′-bis-(sec-butylamino)-diphenylmethane and derivatives thereof; diaminophenyl sulphone; 1,4-bis-(sec-utylamino)-benzene; 1,2-bis-(sec-butylamino)-benzene; N,N ′-dialkylamino-diphenylmethane; trimethyleneglycol-di-p-aminobenzoate; polytetramethyleneoxide-di-p-aminobenzoate; 4,4′-methylenebis-(3-chloro-2,6-diethyleneaniline); 4,4′-methylenebis-(2,6-diethylaniline); meta-phenylenediamine; paraphenylenediamine; N,N′-diisopropyl-isophoronediamine; polyoxypropylene diamine; propylene oxide-based triamine; 3,3′-dimethyl-4,4′-diaminocyclohexylmethane; piperidine; tertiary amines, such as triethylamine, benzyldimethylamine, dimethylaminomethyl phenol, tri(dimethylamino-methyl) phenol, and tri-2-ethylhexoate salt of tri(dimethylaminomethyl) phenol; and mixtures thereof.

10. A golf ball comprising a core and a cover, wherein at least a portion of the cover is formed from a composition comprising:

an intermediate having the following structure:

wherein R and R 1 independently comprise straight or branched hydrocarbon moieties, acyclic groups, cyclic groups, heterocyclic groups, aromatic groups, phenyl groups, hydrocarbylene group, or a mixture thereof; and

a curing agent selected from the group consisting of saturated or unsaturated primary, secondary, and tertiary amines and adducts thereof; polyamides; carbamates; phenols; thiols; anhydrides; low molecular weight acids; and mixtures thereof.

11. The golf ball of claim 10 , wherein the cover comprises an inner cover layer and an outer cover layer, and wherein the outer cover layer comprises the composition.

12. The golf ball of claim 11 , wherein the inner cover layer comprises thermoplastic or thermoset material.

13. The golf ball of claim 11 , wherein the inner cover layer comprises a highly neutralized polymer.

14. The golf ball of claim 10 , wherein the curing agent is selected from the group consisting of ethylene diamine; hexamethylene diamine; 1-methyl-2,6-cyclohexyl diamine; 2,2,4- and 2,4,4-trimethyl- 1,6-hexanediamine; 4,4 40 -bis-(sec-butylamino)-dicyclohexylmethane and derivatives thereof; 1,4-bis-(sec-butylamino)-cyclohexane; 1,2-bis-(sec-butylamino) -cyclohexane; 4,4′-dicyclohexylmethane diamine; 1 ,4-cyclohexane-bis-(methylaminc); 1,3 -cyclohexane-bis-(methylamine), isomers, and mixtures thereof diethylene glycol bis -(aminopropyl) ether; 2-methylpentamethylene-diamine; diaminocyclohexane, isomers, and mixtures thereof diethylene triamine; triethylene tetramine; tetraethylene pentamine; propylene diamine; 1 ,3-diaminopropane; dimethylamino propylamine; diethylamino propylamine; imido -bis-(propylamine); monoethanolamine, diethanolamine; triethanolamine; monoisopropanolamine, diisopropanolamine; isophoronediamine; 4,4′-methylenebis-(2-chloroaniline); 3,5-dimethylthio-2,4-toluenediamine; 3,5-dimethylthio-2,6-toluenediamine; 3,5-diethylthio-2,4-toluenediamine; 3,5-diethylthio-2,6-toluenediamine; m-phenylene diamine; 4,4 40 -bis-(sec-butylamino)-diphenylmethane and derivatives thereof diaminophenyl sulphone; 1 ,4-bis -(sec-butylamino)-benzene; 1,2-bis-(sec-butylamino)-benzene; N,N′-dialkylamino -diphenylmethane; trimethyleneglycol-di-p-aminobenzoate; polytetramethyleneoxide-di-p -aminobenzoate; 4,4′-methylenebis-(3-chloro-2,6-diethyleneaniline); 4,4′-methylenebis-(2,6-diethylaniline); meta-phenylenediamine; paraphenylenediamine; N,N′-diisopropyl -isophoronediamine; polyoxypropylene diamine; propylene oxide-based triamine; 3,3′-dimethyl -4,4′-diaminocyclohexylmethane; piperidine; tertiary amines, such as triethylamine, benzyldimethylamine, dimethylaminomethyl phenol, tri(dimethylamino-methyl) phenol, and tri -2-ethyihexoate salt of tri(dimethylaminomethyl) phenol; and mixtures thereof.

15. The golf ball of claim 12 , wherein the inner cover layer comprises an ionomeric resin.

16. A golf ball comprising:

a core; and

a cover, wherein the cover is formed from a composition comprising an intermediate having at least one of the following structures:

wherein R and R 1 independently comprise straight or branched hydrocarbon moieties, acyclic groups, cyclic groups, heterocyclic groups, aromatic groups, phenyl groups, hydrocarbylene group, or a mixture thereof; and

a curing agent.

17. The golf ball of claim 16 , further comprising an intermediate layer formed from a thermoplastic or thermoset material.

18. The golf ball of claim 16 , wherein the curing agent comprises reactive functional groups selected from the group consisting of hydroxy groups, amino groups, thiol groups, epoxy groups, anhydride groups, and combinations thereof.

19. The golf ball of claim 18 , wherein the curing agent further comprises non-reactive functional groups selected from the group consisting of chlorine, bromine, and substituted sulfur moieties.

20. The golf ball of claim 16 , wherein the curing agent comprises a curative and a catalyst.

21. The golf ball of claim 20 , wherein the catalyst comprises phosphine salt, phosphonium salt, or a mixture thereof.

22. The golf ball of claim 17 , wherein the inner cover layer comprises an ionomeric resin.