IP Library Granted Patent US 7,825,208
Granted Patent B2
US 7,825,208 · App. 11/373,264 · Granted Nov 2, 2010

Golf equipment formed from amine-adduct modified polyurea compositions

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Quick Facts
Patent No.
US 7,825,208
App. No.
11/373,264
Granted
Nov 2, 2010
Kind
B2
Abstract

Golf equipment having at least one portion formed from amine-adduct modified polyurea compositions, including epoxy-silicone modified polyurea compositions, epoxy modified polyurea compositions, silicone modified polyurea compositions, and polyurea compositions including polyamine/carbonyl adducts and/or amine-modified adducts having backbones based on polyfunctional acrylates or methacrylates or caprolactone monomers or oligomers.

Claims (30)

1. A golf ball comprising a core and a cover, wherein at least a portion of the golf ball is formed from a composition comprising:

a prepolymer comprising an isocyanate and at least one of an amine-terminated component or a hydroxy-terminated component; and

a curing agent comprising an adduct formed from the reaction product of an amine and a silicone having at least one end group comprising oxirane functionality.

2. The golf ball of claim 1 , wherein the silicone has oxirane functional end groups.

3. The golf ball of claim 1 , wherein the composition has a gel time of about 45 seconds or greater.

4. The golf ball of claim 3 , wherein the composition has a gel time of about 60 seconds or greater.

5. The golf ball of claim 1 , wherein the portion is the cover of the golf ball.

6. The golf ball of claim 5 , wherein the cover comprises an inner cover layer and an outer cover layer, and wherein the outer cover layer comprises the composition.

7. The golf ball of claim 6 , wherein the inner cover layer comprises thermoplastic or thermoset material.

8. The golf ball of claim 6 , wherein the inner cover layer comprises a highly neutralized polymer.

9. A golf ball comprising a core and a cover, wherein the cover is formed from a composition comprising:

a prepolymer comprising urea or urethane linkages and having terminal ends comprising hydroxy groups or amine groups; and

a curing agent comprising an adduct comprising a reaction product formed from an amine and a compound comprising a silicone backbone with oxirane functionality.

10. The golf ball of claim 9 , wherein the silicone backbone comprises dimethyl siloxane, 1,3-bis(3-aminopropyl)tetramethyl-di-siloxane, 1,4-bis(3-aminopropyldimethylsilyl)benzene, or mixtures thereof and.

11. The golf ball of claim 9 , wherein the prepolymer consists of urea linkages.

12. A method of forming a golf ball comprising a core and a cover, comprising the following steps:

providing a core;

providing a precursor formed from a silicone with at least one oxirane functional endcap;

forming an amine adduct by reacting an amine-terminated compound with the precursor, wherein the amine adduct comprises the precursor as the backbone;

forming a prepolymer comprising:

an isocyanate-containing component; and

a hydroxy-terminated component, an amine-terminated component, or a combination thereof;

reacting the amine adduct with the prepolymer to form a material; and

forming the cover from the material.

13. The method of claim 12 , wherein the step of providing a precursor comprises reacting a silicone compound with an oxirane functional resin.

14. The method of claim 13 , wherein the silicone compound is selected from the group consisting of dimethyl siloxane, 1,3-bis(3-aminopropyl)tetramethyl-di-siloxane, 1,4-bis(3-aminopropyldimethylsilyl)benzene, and mixtures thereof.

15. The method of claim 14 , wherein the oxirane functional resin is selected from the group consisting of 1,4-butanediol diglycidyl ether, diglycidyl ether of bisphenol A, cresyl diglycidyl ether, ethylhexyl glycidyl ether, and mixtures thereof.

16. The method of claim 12 , further comprising the step of forming a layer disposed about the core, and wherein the step of forming the cover from the material further comprises forming the cover about the layer.

17. The method of claim 16 , wherein the step of forming the layer comprises providing a thermoplastic material and forming the layer from the thermoplastic material.

18. The method of claim 17 , wherein the thermoplastic material comprises a highly neutralized polymer.

Assignments (5)
ASSIGNMENT OF SECURITY INTEREST IN PATENTS (ASSIGNS 039506-0030) Recorded Aug 3, 2022
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS RESIGNING ADMINISTRATIVE AGENT
To: JPMORGAN CHASE BANK, N.A., AS SUCCESSOR ADMINISTRATIVE AGENT
Reel/Frame 061521/0414 →
RELEASE OF SECURITY INTEREST IN PATENTS PREVIOUSLY RECORDED AT REEL/FRAME (027332/0829) Recorded Sep 7, 2016
From: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
To: ACUSHNET COMPANY
Reel/Frame 039939/0012 →
SECURITY INTEREST Recorded Jul 28, 2016
From: ACUSHNET COMPANY
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 039506/0030 →
SECURITY AGREEMENT Recorded Dec 6, 2011
From: ACUSHNET COMPANY
To: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
Reel/Frame 027332/0829 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 17, 2006
From: RICCI, SHAWN
To: ACUSHNET COMPANY
Reel/Frame 017771/0423 →