Dispersant for reducing viscosity of particulate solids
View Patent ↗The invention provides a dispersant for an aqueous dispersion of positively charged or chargeable solid particulates which comprises a compound having an anchoring moiety linked to a polymeric hydrophilic moiety, the anchoring moiety containing at least one acid and/or hydroxy group and having an overall acidity or neutrality and the polymeric moiety having a lower affinity for the particulate surface than the anchoring moiety. The anchoring moiety preferably contains at least two acid groups, preferably carboxylic acid groups, attached either in a [1,1], [1,2] or [1,3] relationship and is linked to the polymeric moiety, which is preferably derived from acrylamide or methacrylamide monomer units, preferably by a sulfur atom. The dispersant can reduce the viscosity of an aqueous dispersion of positively charged or chargeable solid particulates and can reduce the tendency of the resulting dispersion to form a gel or a yield stress material. The dispersant facilitates the processing of the resulting compositions in manufacturing operations and it may be used, for example, as a component of a coating material, a ceramic, paint, refractory material, filler or in an inkjet recording paper or film. Additionally, the dispersant can allow the use of higher concentrations of solid particulates and enable control of the yield stress, as some yield is often beneficial in helping prevent or reduce sedimentation.
1. A coating composition containing positively charged or chargeable solid particulates, the composition comprising one or more dispersants in association with an aqueous dispersing medium, wherein said dispersant comprises a compound having an anchoring moiety linked to a polymeric hydrophilic moiety, said anchoring moiety containing at least one acid and/or hydroxy group and having an overall acidity or neutrality and said polymeric moiety having a lower affinity for surfaces of the solid particulates than said anchoring moiety and wherein said solid particulates are selected from the group consisting of metal oxides, metal hydroxides, metal carbonates, nitrides, ceramics, metals and latexes, all at a pH below their isoelectric point; further wherein said compound has the formula (I):
wherein
A is carbon or nitrogen,
R′ is hydrogen or an alkyl, aryl or heterocyclic group and m is 1 when A is carbon and m is 0 when A is nitrogen;
B is an acid group or an ester or amide thereof, or a hydroxy group;
each E is independently hydrogen, an amino group or an acid group or an ester or amide of an acid group, and n is 0 or an integer from 1 to 10;
D is a hydrogen atom, an amino group, an acid group or an ester or amide of an acid group, an alkyl group, or an alkyl group substituted with one or more acid groups or an ester or amide of an acid group;
G is a carbonyl group or an alkylene, aminoalkylene or oxyalkylene group and p is 0 or 1;
L is a linking group selected from the group consisting of sulfur and alkylene, ester, thioester, amide, thioamide, ketone, thioketone, ether, thioether and polyalkylenethio groups, and z is 1;
D and L or D, G and L may combine with A to form a 5-, 6- or 7-membered ring which may include one or more further heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur;
each M is a monomer unit, which may be the same or different, comprising an acrylamide or methacrylamide, and x is 5-200; and
F is hydrogen or a halogen atom, an alkyl group, a thiol, a neutral thioether, an ether, an ester, or an alkyl- or aryl- sulfonate group;
with the proviso that (a) the number of acid groups is equal to or greater than the number of amino groups therein and (b) there is at least one hydroxy or acid group.
2. A composition as claimed in claim 1 wherein said solid particulates have an isoelectric point above pH 5.8.
3. A composition as claimed in claim 1 wherein said solid particulates are metal oxides selected from the group consisting of Al 2 O 3 , CeO 2 , Co 3 O 4 , Cr 2 O 3 , CuO, Eu 2 O 3 , Fe 2 O 3 , HgO, MgO, NiO, PuO 2 , TiO 2 , UO 2 , ZnO and ZrO 2 .
4. A composition as claimed in claim 1 wherein said positively charged or chargeable solid particulates have a particle size from 50 nm to 1 micrometer.
5. A composition as claimed in claim 1 wherein said positively charged or chargeable solid particulate content in said composition is a volume fraction of solids of about 0.2 to about 0.5.
6. A composition as claimed in claim 1 wherein the weight ratio of said dispersant to the positively charged or chargeable solid particulates is 7:1000 to 16:1000.
7. A method of coating a substrate comprising the steps of
(a) providing a coating composition of claim 1 ;
(b) applying said coating composition to said substrate to form a coating thereon; and
(c) drying the resultant coating.
8. A coating composition as claimed in claim 1 wherein each acid group of the anchoring moiety of the compound is independently selected from the group consisting of a carboxylic acid, sulfonic acid or phosphoric acid.
9. A coating composition as claimed in claim 1 wherein said polymeric hydrophilic moiety of the compound is selected from the group consisting of polyacrylamide, poly-N,N-di-methylacrylamide, poly-2-acryl -amido-2-hydroxy-methyl-1,3-propandiol, poly-methacrylamide, poly-N-methyl -acrylamide and poly-N-methyl-methacrylamide and mixtures thereof.
10. A coating composition as claimed in claim 1 wherein A is carbon and R′ is hydrogen or a methyl group.
11. A coating composition as claimed in claim 1 wherein any acid group as or forming part of B, E, D or G is independently selected from the group consisting of a carboxylic acid, sulfonic acid and phosphoric acid.
12. A coating composition as claimed in claim 1 wherein z is 1 and L is sulfur.
13. A coating composition as claimed in claim 1 wherein x is 10-50.
14. A coating composition as claimed in claim 1 wherein said monomer unit M is acrylamide or N,N-dimethyl-acrylamide or a mixture thereof.
15. A coating composition as claimed in claim 1 , wherein the dispersant has the structure
wherein x is from 10-50.
16. A coating composition as claimed in claim 1 wherein said solid particulates are inorganic solid particulates having an isoelectric point above pH 5.8.