Polymer and method for using the polymer for noncovalently functionalizing nanotubes
View Patent ↗A new, non-wrapping approach to functionalizing nanotubes, such as carbon nanotubes, in organic and inorganic solvents is provided. In accordance with certain embodiments, carbon nanotube surfaces are functionalized in a non-wrapping fashion by functional conjugated polymers that include functional groups. Various embodiments provide polymers that noncovalently bond with carbon nanotubes in a non-wrapping fashion. For example, various embodiments of polymers are provided that comprise a relatively rigid backbone that is suitable for noncovalently bonding with a carbon nanotube substantially along the nanotube's length, as opposed to about its diameter. In preferred polymers, the major interaction between the polymer backbone and the nanotube surface is parallel π-stacking. In certain implementations, the polymers further comprise at least one functional extension from the backbone that are any of various desired functional groups for functionalizing a carbon nanotube.
1. A method of controlling the location of at least one functional group on a functionalized nanotube, comprising:
selecting at least one functional group,
selecting at least one polymer having a backbone portion capable of bonding to a nanotube in a non-wrapping fashion for controlling the location of the at least one functional group on the backbone portion,
interacting the at least one polymer and the at least one functional group to form a polymer having a backbone portion for noncovalently bonding with a nanotube in a non-wrapping fashion and having at least one functional group, and
interacting the polymer having a backbone portion for noncovalently bonding with a nanotube in a non-wrapping fashion and having at least one functional group and at least one carbon nanotube.
2. The method of claim 1 wherein the backbone portion comprises a portion selected from the group consisting of:
selected from the group consisting of Ni, Pd, and Pt,
wherein at least one of R 1 -R 8 in the above-listed backbone portions a)-q) represents a functional group; and wherein n is greater than or equal to 2.
3. The method of claim 1 wherein the polymer comprises poly(aryleneethynylene).
4. The method of claim 3 further comprising at least 4 functional portions (R 1 , R 2 , R 3 , and R 4 ), wherein said functional portions comprise functional portions selected from the group consisting of:
a) R 1 =R 4 =H and R 2 =R 3 =OC 10 H 21 ,
b) R 1 =R 2 =R 3 =R 4 =F,
c) R 1 =R 4 =H and R 2 =R 3 =
and
d) R 1 =R 4 =H and R 2 =R 3 =
5. The method of claim 1 wherein the polymer comprises poly(phenyleneethynylene).
6. The method of claim 1 wherein the polymer comprises poly(3-decyithiophene).
7. The method of claim 1 wherein the at least one functional group comprises at least one member selected from the group consisting of:
H, OC 10 H 21 , F,
8. The method of claim 1 wherein the at least one functional group comprises a chemical handle.
9. The method of claim 1 wherein the at least one functional group comprises a sensor.
10. The method of claim 1 wherein the at least one functional group comprises an ionic functional group.
11. The method of claim 1 wherein the at least one functional group comprises a neutral functional group.
12. The method of claim 1 wherein the at least one functional group comprises an organic functional group.
13. The method of claim 1 wherein the nanotube is a carbon nanotube.
14. The method of claim 1 wherein the backbone portion is capable of interacting with the nanotube's surface via π-stacking.