Coating systems for cement composite articles
View Patent ↗A coating system, a method of coating a substrate, and a coated substrate (e.g., a coated cement fiberboard article) include one or more latex polymers, an aliphatic epoxy resin system, optionally a silicate additive, and optionally one or more olefinic compounds and an initiator. The coating system may be applied in one or more layers and may be applied to all the surfaces of the substrate (e.g., the front side, back side and edges of a board). The coated substrate may then be coated with other optional coatings, e.g., decorative or protective topcoats.
1. An aqueous coating system comprising:
one or more multistage latex polymers containing between 50 and 90 wt. % hard segments having a Tg between 30 and 130° C. and between 10 and 50 wt. % soft segments having a Tg between 0 and 25° C.;
an aliphatic epoxy resin system having an oxirane functional component that is distinct from the one or more multistage latex polymers, wherein the oxirane functional component in the aliphatic epoxy resin system has an epoxy equivalent weight less than 1000; and
wherein the aqueous coating system includes one or more coating compositions that may be applied in one or more layers and contains about 2-50 wt. % aliphatic epoxy resin based on total solids, and the aqueous coating system when dried is block-resistant.
2. The aqueous coating system of claim 1 , wherein the the one or more multistage latex polymers comprise one or more epoxy functional groups.
3. The aqueous coating system of claim 2 , wherein at least one of the latex polymers is made from glycidyl methacrylate, glycidyl acrylate, 4-hydroxybutyl acrylate glycidylether, and combinations thereof.
4. The aqueous coating system of claim 1 , wherein the minimum film forming temperature of a blend of the one or more multistage latex polymers with the oxirane functional component of the aliphatic epoxy resin system is less than about 20° C.
5. The aqueous coating system of claim 1 , wherein the the one or more multistage latex polymers comprise acetoacetoxy-functionality.
6. The aqueous coating system of claim 1 , wherein the one or more multistage latex polymers comprise one or more amine groups.
7. The aqueous coating system of claim 1 , wherein the aqueous coating system further comprises about 2 to 50 wt. % of a silicate salt;
wherein the silicate salt is potassium silicate, ammonium silicate, sodium silicate, lithium silicate, or mixtures thereof.
8. The aqueous coating system of claim 1 , wherein the oxirane functional component is the reaction product of an oxirane precursor molecule with an alcohol containing material or a carboxylic acid containing material.
9. The aqueous coating system of claim 8 , wherein the oxirane functional component is the reaction product of an oxirane precursor molecule with an alcohol containing material, and at least a portion of the alcohol containing material is ethylene glycol, propylene glycol, 1,3-propanediol, 1,4-butanediol, 1,3-butanediol, 2-methyl-1,3-propanediol, neopentyl glycol, 2,2-butylethyl propanediol, hexanediol, diethylene glycol, dipropylene glycol, polyethylene glycols, polypropylene glycols, cyclohexane dimethylol, 2,2,3-trimethylpentanediol, trimethylol propane, ethoxylated trimethylol propane, propoxylated trimethylol propane, glycerine, propoxylated glycerine, pentaerythritol, ethoxylated pentaerythritol, propoxylated pentaerythritol, dipentaerythritol, tripentaerythritol, ethoxylated and propoxylated dipentaerythritol, ethoxylated and propoxylated tri-pentaerythritol, ditrimethylolpropane, hydroxypivalyl hydroxypivalate, hydrogenated bisphenol A, ethoxylated and propoxylated hydrogenated bisphenol A, isosorbide, or mixtures thereof.
10. The aqueous coating system of claim 8 , wherein the oxirane functional component is the reaction product of an oxirane precursor molecule with a carboxylic acid containing material, and at least a portion of the carboxylic acid containing material is malonic acid, succinic acid, glutaric acid, sebacic acid, fumaric acid, adipic acid, pimelic acid, hexahydrophthalic acid, 1,3- and 1,4 cyclohexanedicarboxylic acid, orthophthalic acid, isophthalic acid, maleic acid, chlorendic acid, glycolic acid, citric acid, trimellitic acid, lactic acid, caprolactone, or mixtures thereof.
11. The aqueous coating system of claim 8 , wherein the oxirane functional component has an epoxy equivalent weight of about 90 to 350.
12. A coated article comprising a substrate, at least a portion of which is coated with one or more layers of the aqueous coating system of claim 1 , and one or more layers of a second coating system comprising a latex polymer.
13. A coated article comprising a substrate, at least a portion of which is coated with one or more layers of the aqueous coating system of claim 1 , and one or more layers of a second coating system comprising a functionalized latex polymer, a multistage latex polymer, or a functionalized, multistage latex polymer.
14. The aqueous coating system of claim 1 , wherein the aqueous coating system further comprises one or more olefinic compounds and is radiation curable.
15. A coated article comprising a substrate, at least a portion of which is coated with one or more layers of the aqueous coating system of claim 1 , and one or more layers of a second coating system comprising (i) a latex containing primer, (ii) a latex containing topcoat, or (iii) both (i) and (ii).
16. The coated article of claim 15 , wherein the second coating system comprises a functionalized latex polymer, a multistage latex polymer or a functionalized, multistage latex polymer.
17. The coated article of claim 16 , wherein the second coating system comprises (i) an acetoacetoxy-functional latex containing primer, or (ii) an acetoacetoxy-functional latex containing topcoat, or (iii) both (i) and (ii).
18. The aqueous coating system of claim 1 wherein the multistage latex polymer has a hard segment having a Tg between 30 and 70° C.
19. The aqueous coating system of claim 1 , wherein the aqueous coating system contains about 20-80 wt. % latex polymer based on total solids.
20. The aqueous coating system of claim 1 , wherein the aqueous coating system contains about 2-15 wt. % amine crosslinker based on total solids with a reactive hydrogen equivalent weight between 20 and 500.
21. The aqueous coating system of claim 1 , further comprising one or more pigments.
22. The aqueous coating system of claim 1 , wherein the aliphatic epoxy resin system acts as a coalescent.
23. The aqueous coating system of claim 22 , wherein the minimum film forming temperature of the aqueous coating system is less than about 20° C.
24. The aqueous coating system of claim 1 , wherein the aliphatic epoxy resin system lowers the minimum film forming temperature of the aqueous coating system.
25. The aqueous coating system of claim 24 , wherein the minimum film forming temperature of the aqueous coating system is less than about 30° C.
26. A coated article comprising a substrate, at least a portion of which is coated with one or more layers of the aqueous coating system of claim 1 .
27. The coated article according to claim 26 , wherein the substrate is cement fiberboard.