Transfer resistant cosmetic composition with improved feel
A transfer resistant cosmetic composition with improved feel is provided which comprises: a) a film-forming effective amount of at least one silicone-aliphatic hydrocarbon wax in which the aliphatic hydrocarbon substituent possesses from 24 to 60 carbon atoms; b) a transfer resistant effective amount of at least one silicone resin selected from the group consisting of MQ resin and MT resin; and, c) at least one volatile carrier, the cosmetic composition being substantially free of dimethicone gum.
1 . A transfer resistant cosmetic composition with improved feel is provided which comprises:
a) a film-forming effective amount of at least one silicone-aliphatic hydrocarbon wax in which the aliphatic hydrocarbon substituent possesses from 24 to 60 carbon atoms;
b) a transfer resistant effective amount of at least one silicone resin selected from the group consisting of MQ resin and MT resin; and,
c) at least one volatile carrier,
the cosmetic composition being substantially free of dimethicone gum.
2 . The cosmetic composition of claim 1 wherein the silicone wax is a silicone-aliphatic hydrocarbon wax in which the aliphatic hydrocarbon substitutuent possesses from 30 to 45 carbon atoms.
3 . The cosmetic composition of claim 1 wherein the MQ resin is selected from the group consisting of non-fluorinated MQ resin, fluorinated MQ resin and mixtures thereof.
4 . The cosmetic composition of claim 3 wherein in the non-fluorinated MQ resin, M is a unit of the general formula R′ 3 SiO 1/2 and Q is a unit of the general formula SiO 4/2 , the MQ resin optionally containing small amounts of D and/or T units, R′ being a hydrocarbon radical of from 1 to 6 carbon atoms.
5 . The cosmetic composition of claim 4 wherein R′ is methyl.
6 . The cosmetic composition of claim 3 wherein in the fluorinated MQ resin, M is a unit of the general formula R 1 3 SiO 1/2 , Q is a unit of the general formula SiO 4/2 , the fluorine-containing group(s) are bonded to silicon atom(s) of M group(s) and the resin optionally contains up to 5 mole percent of D and/or T units, R 1 being a hydrocarbyl radical of from 1 to 6 carbon atoms.
7 . The cosmetic composition of claim 6 wherein R 1 is methyl.
8 . The cosmetic composition of claim 6 wherein the fluorine-containing group(s) are selected from the group consisting of those of the general formula:
and those of the general formula:
—O—R 4 —(CF 2 ) x CF 3
wherein R 4 and R 6 each independently is an alkylene group possessing from 2 to 6 carbon atoms, 0≦x≦12 and each R 5 independently is an alkyl group possessing from 1 to 6 carbon atoms.
9 . The cosmetic composition of claim 1 wherein in the MT resin, M possesses the formula R 3 SiO 0.5 , R 6 RRSiO 0.5 , R 6 R 7 RSiO 0.5 or R 6 R 7 R 8 SiO 0.5 wherein R is methyl and R 6 , R 7 and R 8 each independently is alkyl of from 1 to 6 carbon atoms, phenyl, diisostearoyl trimethylolpropane or dilauryltrimethylolpropane and T is a trifunctional siloxy unit of the formula R 9 SiO 1.5 wherein R 9 is alkyl of up to 20 carbon atoms optionally substituted with one or more hydroxyl groups and/or halogen atoms.
10 . The cosmetic composition of claim 9 wherein M possesses the formula R 3 SiO 0.5 in which R is methyl and T possesses the formula RSiO 1.5 in which R is methyl.
11 . The cosmetic composition of claim 7 wherein the MT resin is a polymethylsilesquioxane.
12 . The cosmetic composition of claim 1 wherein the volatile carrier is at least one member of the group consisting of volatile hydrocarbon oil and volatile silicone fluid.
13 . The cosmetic composition of claim 12 wherein the volatile hydrocarbon oil is an isoparaffin of from 8 to 20 carbon atoms.
14 . The cosmetic composition of claim 13 wherein the isoparaffin is at least one member selected from the group consisting of isododecane, isohexadecane, isoeicosane, 2,2,4-trimethylpentane and 2,3-dimethylhexane.
15 . The cosmetic composition of claim 12 wherein the volatile silicone fluid is a cyclomethecone.
16 . The cosmetic composition of claim 1 wherein silicone-aliphatic hydrocarbon wax (a) is present therein at a level of from about 3 to about 30 percent by weight, silicone resin (b) is present therein at a level of from about 1 to about 50 percent by weight and volatile carrier (c) is present therein at a level of from about 10 to about 90 percent by weight.
17 . The cosmetic composition of claim 1 wherein silicone wax (a) is present therein at a level of from about 5 to about 20 percent by weight, silicone resin (b) is present therein at a level of from about 2 to about 30 percent by weight and volatile carrier (b) is present therein at a level of from about 15 to about 80 percent by weight.
18 . The cosmetic composition of claim 1 wherein silicone wax (a) is present therein at a level of from about 8 to about 15 percent by weight, silicone resin (b) is present therein at a level of from about 5 to about 20 percent by weight and volatile carrier (b) is present therein at a level of from about 20 to about 70 percent by weight.
19 . The cosmetic composition of claim 1 , further comprising at least one additional component selected from the group consisting of pigments, colors, other waxes, emulsifiers, skin care ingredients, emollients and moisturizers.
20 . The cosmetic composition of claim 1 which is a lipstick, lip gloss, makeup, mascara, eye liner, blusher, eye shadow or foundation.
21 . The cosmetic composition of claim 19 which is a lipstick, lip gloss, makeup, mascara, eye liner, blusher, eye shadow or foundation.