Magnesium-titanium solid solution alloys
Films of magnesium mixed with titanium are produced by non-equilibrium alloying processes such as electron beam evaporation of magnesium and titanium ingots in a very low pressure chamber. Such magnesium-titanium films form as single phase solid solutions. Titanium is inherently resistant to corrosion and its admixture with magnesium in solid solution provides a new composition that is less subject to intra-film galvanic corrosion. The magnesium-titanium films also provide relatively hard and strong coatings.
1. A method of making a solid solution of titanium in magnesium as a film deposited on a magnesium or magnesium alloy substrate, the method comprising:
separately producing and mixing vapors of magnesium and of titanium in a low pressure chamber and co-depositing magnesium and titanium from the vapor on the substrate, at a substrate temperature of about 25° C., to form a film consisting essentially of a solid solution of titanium in magnesium, the solid solution having a hexagonal close packed crystal structure.
2. A method as recited in claim 1 in which the magnesium vapor and titanium vapor are each produced by electron beam evaporation and the solid solution film has a hexagonal close packed crystal structure.
3. A method as recited in claim 1 in which the solid solution film has a thickness of twenty nanometers or greater.
4. A method as recited in claim 1 in which the film consists essentially of up to about twenty atomic percent titanium.
5. A method as recited in claim 1 in which the thickness of the film is in the range of about twenty nanometers to about one millimeter.