Propylene and isoprene production
View Patent ↗A process for producing propylene and isoprene from a feed stream comprising 1-butene and isobutene is disclosed. The feed stream is reacted in a catalytic distillation reactor containing an olefin isomerization catalyst to produce an overhead stream comprising 2-butene and isobutene and a bottoms stream comprising 2-butene. The overhead stream is reacted in the presence of a metathesis catalyst to produce propylene and isoamylenes. Isoprene is produced by dehydrogenation of isoamylenes.
1. A process comprising: (a) reacting a feed stream comprising 1-butene and isobutene in the presence of an isomerization catalyst to generate a first reaction mixture, and concurrently distilling the first reaction mixture to produce an overhead stream comprising 2-butene and isobutene and a bottoms stream comprising 2-butene; (b) reacting the overhead stream in the presence of a first metathesis catalyst to generate a second reaction mixture comprising isoamylenes, butenes, and propylene; (c) distilling the second reaction mixture to isolate isoamylenes; and (d) dehydrogenating isoamylenes from step (c) to produce isoprene.
2. The process of claim 1 further comprising reacting the bottoms stream from step (a) with ethylene in the presence of a second metathesis catalyst to produce a third reaction mixture comprising ethylene, propylene, 1-butene, 2-butene, and C 5 and higher olefins; distilling the third reaction mixture into ethylene, propylene, a butenes stream, and a heavy stream comprising the C 5 and higher olefins.
3. The process of claim 2 further comprising recycling the separated ethylene to the metathesis reaction of the bottoms stream from step (a) and ethylene.
4. The process of claim 3 further comprising recycling the butenes stream to step (a).
5. The process of claim 1 wherein the feed stream comprises 2-butene.
6. The process of claim 1 wherein the feed stream is raffinate-1.
7. The process of claim 1 wherein the isomerization catalyst is a basic catalyst.
8. The process of claim 1 wherein the isomerization catalyst comprises magnesium oxide.
9. The process of claim 1 wherein the isomerization catalyst is a hydroisomerization catalyst.
10. The process of claim 1 wherein the hydroisomerization catalyst comprises Pd and alumina.
11. The process of claim 10 wherein the feed stream comprises hydrogen.
12. The process of claim 10 wherein the isomerization reaction is performed at a temperature in the range of from 100 to 250° F.
13. The process of claim 10 wherein the isomerization reaction is performed at a pressure in the range of from 50 to 250 psig.
14. The process of claim 1 wherein the dehydrogenation reaction is performed at a temperature in the range of from 700 to 1300° F.
15. The process of claim 1 wherein the first metathesis catalyst comprises a transition metal oxide comprising an element selected from the group consisting of cobalt, molybdenum, rhenium, tungsten, and mixtures thereof.
16. The process of claim 1 wherein the first metathesis catalyst comprises tungsten oxide and silica.
17. The process of claim 16 wherein the first metathesis catalyst further comprises magnesium oxide.
18. The process of claim 2 wherein the second metathesis comprises a transition metal oxide comprising an element selected from the group consisting of cobalt, molybdenum, rhenium, tungsten, and mixtures thereof.
19. The process of claim 2 wherein the second metathesis catalyst comprises tungsten oxide and silica.
20. The process of claim 19 wherein the second metathesis catalyst further comprises magnesium oxide.