Polyolefin resin blends for crack-resistant pipe
View Patent ↗Resin blends useful for pipe and blow-molded articles are disclosed. The blends comprise a low-molecular-weight, high-density polyethylene and a high-molecular-weight, low-density ethylene copolymer. The high-molecular-weight component is made with a bridged indenoindolyl Group 4 metal complex having open architecture. Blends of the invention uniquely have high molecular weight (M w >200,000) and low levels of long-chain branching. A quick, convenient approach for estimating levels of long-chain branching in polyethylenes from gel permeation chromatography and dynamic oscillatory rheometry (“viscosity enhancement factor”) is disclosed.
1. A blow molded pipe produced from a resin blend comprising from about 30 to about 70 wt. % of a low-molecular-weight, high-density polyethylene, and from about 30 to about 70 wt. % of a high-molecular-weight, low-density ethylene copolymer produced using a bridged indenoindolyl Group 4 metal complex having open architecture, wherein the ethylene copolymer has a weight-average molecular weight within the range of 150,000 to 500,000,
wherein the blend has a density from 0.94 to 0.96 g/cm 3 , a weight-average molecular weight (Mw) by gel permeation chromatography greater than 200,000, rheological polydispersity (E R ) of less than 1.5, and a viscosity enhancement factor (VEF), calculated from its melt viscosity (η*) at 190° C. and 0.025 radians per second, of less than 2, wherein the pipe exhibits a notched constant tensile (NCTL) value of greater than 500 hours to failure, and wherein the low molecular-weight, high-density polyethylene is produced using a polysiloxane-supplied Ziegler-Natta catalyst.
2. The pipe of claim 1 , wherein the resin blend has a high-load melt index (MI 20 ) of less than 25.
3. The pipe of claim 1 , wherein the low molecular-weight, high-density polyethylene is produced in the presence of a silane modifier.
4. The pipe of claim 3 , wherein the silane modifier is a cyclohexyl dialkoxy(alkyl)silane.
5. The pipe of claim 1 , wherein the ethylene copolymer has a density of from 0.900 to 0.925 g/cm 3 .
6. The pipe of claim 1 , wherein the ethylene copolymer has little to no long-chain branching content.
7. The pipe of claim 1 , wherein the polyethylene has a molecular weight distribution (M w /M a ) of less than 5.