1-phenoxy-2-propanol as a formulating aid for dyes
View Patent ↗The invention relates to an aqueous dye solution comprising a) 5 to 30% by weight of an anionic or cationic direct dye, b) 0.1 to 10% by weight of 1-phenoxy-2-propanol, c) 0 to 20% by weight of an inorganic or an organic acid, d) 0 to 20% by weight of further additives and e) water to complete to 100%, a process for the preparation of the solution and the use thereof for dyeing paper.
1. An aqueous dye solution comprising:
a) 10 to 25% by weight of an anionic or cationic direct dye,
b) 0.1 to 5% by weight of 1-phenoxy-2-propanol,
c) 0 to 20% by weight of an inorganic or an organic acid,
d) 0 to 20% by weight of further additives and
e) water to complete to 100%.
2. The aqueous dye solution according to claim 1 , wherein the anionic direct dye contains at least one sulfonic acid and/or carboxylic acid group and is derived from a metal-free or metallic monoazo, disazo, or polyazo dye, a pyrazolone dye, a thioxanthone dye, an oxazine dye, a stilbene dye, a formazan dye, an anthraquinone dye, a nitro dye, a methane dye, a triphenylmethane dye, a xanthone dye, a naphthazarine dye, a styryl dye, an azastyryl dye, a naphthoperinone dye, a quinophthalone dye, or a phthalocyanine dye.
3. The aqueous dye solution according to claim 1 , wherein the cationic direct dye is a basic dye selected from the group consisting of acridine basic dyes, anthraquinone basic dyes, azine basic dyes, azomethine basic dyes, azostyryl basic dyes, mono-, bis- and polyazo basic dyes, benzimidazole basic dyes, benzothiazole basic dyes, cyanine basic dyes, di- and triarylmethane basic dyes, ketone imine basic dyes, methane and polymethine basic dyes, naphthostyryl basic dyes, nitro basic dyes, oxazine and dioxazine basic dyes, phthalocyanine basic dyes, quinoline basic dyes, quinophthalone basic dyes, thiazine basic dyes, thiazole basic dyes, and xanthene derived basic dyes.
4. A process for preparing an aqueous dye solution according to claim 1 , said process comprising stirring an anionic or cationic direct dye with a mixture of water, 1-phenoxy-2-propanol, 0 to 20% by weight of an inorganic or an organic acid, and 0 to 20% by weight of further additives.
5. A method of dyeing paper, paperboard, or pulp, said method comprising applying the aqueous dye solution according to claim 1 to said paper, paperboard, or pulp.
6. A paper dyed with an aqueous dye solution according to claim 1 .
7. The aqueous dye solution according to claim 1 , wherein said aqueous dye solution is essentially free of alcohol solvents other than 1-phenoxy-2-propanol.
8. The aqueous dye solution according to claim 1 , wherein the further additives are selected from the group consisting of water-soluble organic solubilizers, hydrotropic agents, viscosity regulators, dispersing agents, microbiocides, and pH adjusting agents.
9. The aqueous dye solution according to claim 8 , wherein the water-soluble organic solubilizers are selected from the group consisting of urea, formamide, ε-caprolactam, sugars, carboxycelluloses, dimethylformamide, 1,2-diaminopropane, 2-(4-aminophenyl)-6-methylbenzothiazole 7-sulphonic acid and salts thereof, and polyhydric alcohols.
10. The aqueous dye solution according to claim 2 , wherein the anionic direct dye is derived from a monoazo, disazo, polyazo, or phthalocyanine dye.
11. The aqueous dye solution according to claim 3 , wherein the cationic direct dye is selected from the group consisting of mono-, bis, and polyazo basic dyes, and phthalocyanine basic dyes.