IP Library Granted Patent US 9,284,625
Granted Patent B2
US 9,284,625 · App. 11/942,769 · Granted Mar 15, 2016

Use of polyols as scale control reagents in the mining processes

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Quick Facts
Patent No.
US 9,284,625
App. No.
11/942,769
Granted
Mar 15, 2016
Kind
B2
Abstract

A hyperbranched polyglycerol is employed as a process stabilization aid of pregnant liquor of a Bayer process of producing alumina from bauxite. The hyperbranched polyglycerol has a molecular weight of from about 1,000 to about 1,000,000.

Claims (14)

1. A method of increasing stability of a pregnant liquor of a Bayer process comprising:

adding to the pregnant liquor of a Bayer process a hyperbranched polyglycerol having a molecular weight of from 1,000 to 1,000,000 in an amount of no less than 0.1 ppm.

2. The method of claim 1 , wherein the hyperbranched polyglycerol contains 5 to 30 milliequivalents of hydroxyl units per gram of active polymer.

3. The method of claim 1 , wherein the hyperbranched polyglycerol contains 8 to 18 milliequivalents of hydroxyl units per gram of active polymer.

4. The method of claim 1 , wherein the hyperbranched polyglycerol is synthesized via an addition polymerization.

5. The method of claim 1 , wherein the hyperbranched polyglycerol has from 25 to 12,000 monomeric units.

6. The method of claim 1 , wherein the hyperbranched polyglycerol has from 42 to 7,200 monomeric units.

7. The method of claim 1 , wherein the hyperbranched polyglycerol is a homopolymer.

8. The method of claim 6 , wherein the hyperbranched polyglycerol consists of a combination of multiple monomers.

9. The method of claim 1 , wherein the hyperbranched polyglycerol is present in the pregnant liquor of a Bayer process at a concentration of from 5 to 50 ppm.

10. The method of claim 1 , wherein the hyperbranched polyglycerol has a molecular weight of from 1,000 to 50,000.

11. Pregnant Bayer liquor comprising a hyperbranched polyglycerol having a molecular weight of from 1,000 to 1,000,000 at a concentration of from 0.1 to 100 ppm.

12. The pregnant Bayer liquor of claim 11 , wherein the hyperbranched polyglycerol has a molecular weight of from 1,000 to 50,000.

13. The method of claim 1 , wherein the hyperbranched polyglycerol is synthesized via addition polymerization of glycidol.

Assignments (7)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 4, 2017
From: NALCO COMPANY
To: ECOLAB USA INC.
Reel/Frame 042147/0420 →
CHANGE OF NAME Recorded Feb 28, 2017
From: NALCO COMPANY
To: NALCO COMPANY LLC
Reel/Frame 041835/0903 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 28, 2017
From: NALCO COMPANY LLC; CALGON CORPORATION; CALGON LLC; ONDEO NALCO ENERGY SERVICES, L.P.
To: ECOLAB USA INC.
Reel/Frame 041836/0437 →
RELEASE OF SECURITY INTEREST Recorded Feb 24, 2017
From: BANK OF AMERICA, N.A.
To: NALCO COMPANY
Reel/Frame 041808/0713 →
RELEASE OF SECURITY INTEREST Recorded May 26, 2015
From: BANK OF AMERICA, N.A.
To: NALCO COMPANY
Reel/Frame 035771/0668 →
SECURITY AGREEMENT Recorded May 18, 2009
From: NALCO COMPANY; CALGON LLC; NALCO ONE SOURCE LLC; NALCO CROSSBOW WATER LLC
To: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
Reel/Frame 022703/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 20, 2007
From: WANG, JING; LI, XIAOJIN; BODE, HEINRICH ENOCH
To: NALCO COMPANY
Reel/Frame 020136/0930 →