Method for manufacturing membrane-membrane reinforcing member assembly, membrane-catalyst layer assembly, membrane-electrode assembly, and polymer electrolyte fuel cell
A membrane-membrane reinforcing member assembly ( 1 ) of the present invention includes: a polymer electrolyte membrane ( 10 ) having a pair of first main surface (F 1 ) and second main surface (F 2 ) which face each other and each has a substantially rectangular shape; a pair of first membrane reinforcing members 22 and 24 which are disposed on portions, respectively, extending along a pair of opposed sides of four sides of the first main surface (F 1 ), each has a main surface smaller than the first main surface (F 1 ) and each has a film shape; and a pair of second membrane reinforcing members ( 26 ) and ( 28 ) which are disposed on portions, respectively, extending along a pair of opposed sides of four sides of the second main surface (F 2 ), each has a main surface smaller than the second main surface (F 2 ) and each has a film shape, wherein the pair of first membrane reinforcing members ( 22 ) and ( 24 ) and the pair of second membrane reinforcing members ( 26 ) and ( 28 ) are disposed so as to extend along four sides as a whole, respectively, of the polymer electrolyte membrane ( 10 ) and so as to sandwich four corners of the polymer electrolyte membrane ( 10 ).
1. A method for manufacturing a membrane-membrane reinforcing member assembly, comprising steps of:
(A) disposing a pair of first membrane reinforcing members, on portions, respectively, extending along a pair of opposed sides of four sides of a first main surface and a second main surface of a polymer electrolyte membrane, the first main surface and the second main surface facing face each other and respectively having a substantially rectangular shape, each of the pair of first membrane reinforcing members having a main surface smaller than the first main surface and having a film shape; and
(B) disposing a pair of second membrane reinforcing members, each having a main surface smaller than the second main surface and having a film shape, on portions, respectively, extending along a pair of opposed sides of four sides of the second main surface, wherein:
in said steps A and B, said pair of first membrane reinforcing members and said pair of second membrane reinforcing members are disposed so as to extend along four sides as a whole, respectively, of the polymer electrolyte membrane and so as to sandwich four corners of the polymer electrolyte membrane,
said step A includes: a step of preparing a roll of the polymer electrolyte membrane having a tape shape and rolls of said two first membrane reinforcing members each having a tape-shape; a step of pulling out the tape-shaped polymer electrolyte membrane and the two tape-shaped first membrane reinforcing members from the respective rolls and joining the two first membrane reinforcing members to side end portions, respectively, of the first main surface of the tape-shaped polymer electrolyte membrane; and a step of cutting the tape-shaped polymer electrolyte membrane, to the side end portions of which the two tape-shaped first membrane reinforcing members are joined, into pieces each having a predetermined length,
the pair of first membrane reinforcing members and the pair of second membrane reinforcing members are made of at least one type of synthetic resin selected from a group consisting of polyethylene naphthalate, polyethylene terephthalate, fluoroethylene-propylene copolymer, tetrafluoroethylene-perfluoro alkoxy ethylene copolymer, polyethylene, polypropylene, polyether amide, polyether imide, polyether ether ketone, polyether sulfone, polyphenylene sulfide, polyarylate, polysulfide, polyimide, and polyimide amide, and
the pair of first membrane reinforcing members or the pair of second membrane reinforcing members are disposed only at the pair of opposed sides of four sides of the first main surface, or the second main surface respectively.
2. The method according to claim 1 , wherein an inner reinforcing film having a through hole that is an ion conduction path is disposed within the polymer electrolyte membrane.
3. A method for manufacturing a membrane-catalyst layer assembly, comprising steps of:
manufacturing a membrane-membrane reinforcing member assembly by the method according to claim 1 ;
(C) after the step of manufacturing a membrane-membrane reinforcing member assembly, disposing a first catalyst layer on at least part of a region of the first main surface of the polymer electrolyte membrane of the membrane-membrane reinforcing member assembly on which region the first membrane reinforcing member is not disposed; and
(D) after the step of manufacturing a membrane-membrane reinforcing member assembly, disposing a second catalyst layer on at least part of a region of the second main surface of the polymer electrolyte membrane of the membrane-membrane reinforcing member assembly on which region the second membrane reinforcing member is not disposed.
4. A method for manufacturing a membrane-electrode assembly, comprising steps of:
manufacturing a membrane-catalyst layer assembly by the method according to claim 3 ;
(E) after the step of manufacturing a membrane-catalyst layer assembly, disposing a first gas diffusion layer to cover the first catalyst layer of the membrane-catalyst layer assembly; and
(F) after the step of manufacturing a membrane-catalyst layer assembly, disposing a second gas diffusion layer to cover the second catalyst layer of the membrane-catalyst layer assembly.
5. The method according to claim 4 , wherein:
in said step E, the first gas diffusion layer is disposed so as to cover the first catalyst layer and at least part of the first membrane reinforcing member; and
in said step F, the second gas diffusion layer is disposed so as to cover the second catalyst layer and at least part of the second membrane reinforcing member.
6. A method for manufacturing a polymer electrolyte fuel cell, comprising the step of manufacturing a membrane-electrode assembly by the method according to claim 4 .