CARBON NANOTUBE MEMORY CELLS HAVING FLAT BOTTOM ELECTRODE CONTACT SURFACE
The present invention is directed to structures and methods of fabricating nanotube electromechanical memory cells having a bottom electrode with a substantially planar contact surface. The bottom electrode is configured so that during the operation of the memory cell the nanotube crossbar of the cell can make contact with a substantially planar surface of the bottom electrode.
1 . A nanotube electromechanical memory apparatus comprising:
a semiconductor substrate having a nanotube electromechanical memory cell formed thereon, the memory cell including a transistor with a bottom electrode comprising a substantially planar contact surface enabling a nanotube crossbar of the memory cell to contact the substantially planar contact surface of the bottom electrode during operation of the memory cells,
wherein the bottom electrode comprises a copper filled via enabling electrical contact with the transistor and having a substantially planar top surface comprising the substantially planar contact surface of the bottom electrode.
2 . The apparatus of claim 1 comprising a copper barrier layer between the copper filled via and the bottom electrode.
3 . The apparatus of claim 2 , wherein the barrier layer is about 100 angstroms to about 1500 angstroms thick.
4 . The apparatus of claim 2 , wherein the barrier layer is selected from the group consisting of tantalum, titanium, titanium nitride, tantalum nitride, titanium silicon nitride, and tungsten nitride.
5 . The apparatus of claim 2 , wherein the barrier layer comprises a bilayer. 6 . The apparatus 5 , wherein the bilayer comprises at least one or Ti/TiN or Ti/TaN.
7 . The apparatus of claim 2 comprising a copper seed layer between the barrier layer and the copper filled via.
8 . The apparatus of claim 7 , wherein the copper seed layer is between about 100 angstroms and about 2500 angstroms thick.
9 . A method of a forming a bottom electrode contact surface in a nanotube electromechanical memory cell, the method comprising:
providing a semiconductor substrate having an opening formed therein, the opening configured to enable electrical contact with an underlying transistor of an electromechanical memory cell; and
forming a bottom electrode that extends into the opening enabling electrical connection with the transistor such that the bottom electrode has a substantially planar top contact surface enabling a nanotube crossbar of the memory cell to contact the top contact surface of the bottom electrode during operation of the memory cell,
wherein forming the bottom electrode comprises:
filling the opening with copper; and
planarizing the surface to form a substantially planar top contact surface.
10 . The method of forming a bottom electrode contact surface in a nanotube electromechanical memory cell as in claim 9 , wherein filling the opening with copper comprises:
forming a barrier layer on the substrate;
forming a conductive seed layer on the barrier;
plating the seed layer with copper to form a bulk copper that fills the opening; and
wherein planarizing the surface comprises chemical mechanical polishing of the surface to planarize the bulk copper layer in the opening to form a conductive via having a substantially planarized top surface enabling the nanotube crossbar of the memory cell to contact the substantially planarized top surface of the bottom electrode during operation of the memory cell.
11 . The method of claim 10 , wherein forming a conductive seed layer comprises physical vapor deposition.
12 . The method of claim 10 , wherein plating the seed layer with copper comprises electrochemical plating.
13 . The method of claim 10 , wherein the barrier layer is about 100 angstroms to about 1500 angstroms thick.
14 . The method of claim 10 , wherein the barrier layer is selected from the group consisting of tantalum, titanium, titanium nitride, tantalum nitride, titanium silicon nitride, and tungsten nitride.
15 . The method of claim 10 , wherein the barrier layer comprises a bilayer.
16 . The method 10 , wherein the bilaver comprises at least one or Ti/TiN or Ti/TaN.
17 . The method of claim 10 , wherein the copper seed layer is between about 100 angstroms and about 2500 angstroms thick.
18 - 21 . (canceled)