IP Library Granted Patent US 7,833,112
Granted Patent B2
US 7,833,112 · App. 12/125,239 · Granted Nov 16, 2010

Golf balls having a low modulus HNP layer and a high modulus HNP layer

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Quick Facts
Patent No.
US 7,833,112
App. No.
12/125,239
Granted
Nov 16, 2010
Kind
B2
Abstract

The present invention is directed to golf balls consisting of a multi-layer core and a cover. The multi-layer core consists of a center and an outer core layer that are both soft relative to a hard intermediate core layer. The outer core layer is preferably thin relative to the center and the outer core layer. The multi-layer core includes at least one layer formed from a low modulus HNP composition and at least one layer formed from a high modulus HNP composition.

Claims (40)

1. A golf ball comprising a core and a cover, wherein the core has an overall diameter of from 1.40 inches to 1.60 inches and consists of:

(a) a center having a diameter of from 0.50 inches to 1.50 inches and a center hardness (H) of from 20 Shore C to 70 Shore C;

(b) an intermediate core layer having a surface hardness (I) of 40 Shore C or greater and formed from a high modulus HNP composition, the high modulus HNP composition comprising a highly neutralized ethylene/(meth)acrylic acid copolymer having a modulus of from 25,000 psi to 150,000 psi; and

(c) an outer core layer having a surface hardness (S) of from 20 Shore C to 70 Shore C and formed from a low modulus HNP composition, the low modulus HNP composition comprising a highly neutralized ethylene/(meth)acrylic acid/alkyl(meth)acrylate copolymer having a modulus of from 1,000 psi to 50,000 psi;

wherein H<I and S<I, and

wherein the modulus of the highly neutralized copolymer of the low modulus HNP composition is at least 10% less than the modulus of the highly neutralized copolymer of the high modulus HNP composition.

2. The golf ball of claim 1 , wherein H<S, and wherein S—H=D, where D is an integer from 1 to 22.

3. The golf ball of claim 1 , wherein S<H, and wherein H—S=D, where D is an integer from 1 to 22.

4. The golf ball of claim 1 , wherein the center has a diameter of from 0.750 inches to 1.500 inches and the center hardness (H) is from 50 Shore C to 60 Shore C; the intermediate core layer surface hardness (I) is from 80 Shore C to 90 Shore C; and the outer core layer has a thickness of from 0.010 inches to 0.150 inches and the outer core layer surface hardness (S) is from 50 Shore C to 60 Shore C.

5. The golf ball of claim 4 , wherein the outer core layer has a thickness of from 0.030 inches to 0.070 inches.

6. A golf ball comprising a core and a cover, wherein the core has an overall diameter of from 1.40 inches to 1.60 inches and consists of:

(a) a center having a diameter of from 0.50 inches to 1.50 inches, a center hardness (H) of from 20 Shore C to 70 Shore C, and formed from a low modulus HNP composition, the low modulus HNP composition comprising a highly neutralized ethylene/(meth)acrylic acid/alkyl(meth)acrylate copolymer having a modulus of from 1,000 psi to 50,000 psi;

(b) an intermediate core layer having a surface hardness (I) of 40 Shore C or greater and formed from a high modulus HNP composition, the high modulus HNP composition comprising a highly neutralized ethylene/(meth)acrylic acid copolymer having a modulus of from 25,000 psi to 150,000 psi; and

(c) an outer core layer having a surface hardness (S) of from 20 Shore C to 70 Shore C;

wherein H<I and S<I, and

wherein the modulus of the highly neutralized copolymer of the low modulus HNP composition is at least 10% less than the modulus of the highly neutralized copolymer of the high modulus HNP composition.

7. The golf ball of claim 6 , wherein H<S, and wherein S—H=D, where D is an integer from 1 to 22.

8. The golf ball of claim 6 , wherein S<H, and wherein H—S=D, where D is an integer from 1 to 22.

9. The golf ball of claim 6 , wherein the center has a diameter of from 0.750 inches to 1.500 inches and the center hardness (H) is from 50 Shore C to 60 Shore C; the intermediate core layer surface hardness (I) is from 80 Shore C to 90 Shore C; and the outer core layer has a thickness of from 0.010 inches to 0.150 inches and the outer core layer surface hardness (S) is from 50 Shore C to 60 Shore C.

10. The golf ball of claim 9 , wherein the outer core layer has a thickness of from 0.030 inches to 0.070 inches.

11. A golf ball comprising a core and a cover, wherein the core has an overall diameter of from 1.40 inches to 1.60 inches and consists of:

(a) a center having a diameter of from 0.50 inches to 1.50 inches, a center hardness (H) of from 20 Shore C to 70 Shore C, and formed from a low modulus HNP composition, the low modulus HNP composition comprising a highly neutralized ethylene/(meth)acrylic acid/alkyl(meth)acrylate copolymer having a modulus of from 1,000 psi to 50,000 psi;

(b) an intermediate core layer having a surface hardness (I) of 40 Shore C or greater; and

(c) an outer core layer having a surface hardness (S) of from 20 Shore C to 70 Shore C and formed from a high modulus HNP composition, the high modulus HNP composition comprising a highly neutralized ethylene/(meth)acrylic acid copolymer having a modulus of from 25,000 psi to 150,000 psi;

wherein H<I and S<I, and

wherein the modulus of the highly neutralized copolymer of the low modulus HNP composition is at least 10% less than the modulus of the highly neutralized copolymer of the high modulus HNP composition.

12. The golf ball of claim 11 , wherein H<S, and wherein S—H=D, where D is an integer from 1 to 22.

13. The golf ball of claim 11 , wherein S<H, and wherein H—S=D, where D is an integer from 1 to 22.

14. The golf ball of claim 11 , wherein the center has a diameter of from 0.750 inches to 1.500 inches and the center hardness (H) is from 50 Shore C to 60 Shore C; the intermediate core layer surface hardness (I) is from 80 Shore C to 90 Shore C; and the outer core layer has a thickness of from 0.010 inches to 0.150 inches and the outer core layer surface hardness (S) is from 50 Shore C to 60 Shore C.

15. The golf ball of claim 14 , wherein the outer core layer has a thickness of from 0.030 inches to 0.070 inches.

16. A golf ball comprising a core and a cover, wherein the core has an overall diameter of from 1.40 inches to 1.60 inches and consists of:

(a) a center having a diameter of from 0.50 inches to 1.50 inches, a center hardness (H) of from 20 Shore C to 70 Shore C, and formed from a high modulus HNP composition, the high modulus HNP composition comprising a highly neutralized ethylene/(meth)acrylic acid copolymer having a modulus of from 25,000 psi to 150,000 psi;

(b) an intermediate core layer having a surface hardness (I) of 40 Shore C or greater; and

(c) an outer core layer having a surface hardness (S) of from 20 Shore C to 70 Shore C and formed from a low modulus HNP composition, the low modulus HNP composition comprising a highly neutralized ethylene/(meth)acrylic acid/alkyl(meth)acrylate copolymer having a modulus of from 1,000 psi to 50,000 psi;

wherein H<I and S<I, and

wherein the modulus of the highly neutralized copolymer of the low modulus HNP composition is at least 10% less than the modulus of the highly neutralized copolymer of the high modulus HNP composition.

17. The golf ball of claim 16 , wherein H<S, and wherein S—H=D, where D is an integer from 1 to 22.

18. The golf ball of claim 16 , wherein S<H, and wherein H—S=D, where D is an integer from 1 to 22.

19. The golf ball of claim 16 , wherein the center has a diameter of from 0.750 inches to 1.500 inches and the center hardness (H) is from 50 Shore C to 60 Shore C; the intermediate core layer surface hardness (I) is from 80 Shore C to 90 Shore C; and the outer core layer has a thickness of from 0.010 inches to 0.150 inches and the outer core layer surface hardness (S) is from 50 Shore C to 60 Shore C.

20. The golf ball of claim 19 , wherein the outer core layer has a thickness of from 0.030 inches to 0.070 inches.

Assignments (6)
SECURITY INTEREST Recorded Aug 3, 2022
From: ACUSHNET COMPANY
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 061099/0236 →
ASSIGNMENT OF SECURITY INTEREST IN PATENTS (ASSIGNS 039506-0030) Recorded Aug 3, 2022
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS RESIGNING ADMINISTRATIVE AGENT
To: JPMORGAN CHASE BANK, N.A., AS SUCCESSOR ADMINISTRATIVE AGENT
Reel/Frame 061521/0414 →
RELEASE OF SECURITY INTEREST IN PATENTS PREVIOUSLY RECORDED AT REEL/FRAME (027332/0829) Recorded Sep 7, 2016
From: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
To: ACUSHNET COMPANY
Reel/Frame 039939/0012 →
SECURITY INTEREST Recorded Jul 28, 2016
From: ACUSHNET COMPANY
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 039506/0030 →
SECURITY AGREEMENT Recorded Dec 6, 2011
From: ACUSHNET COMPANY
To: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
Reel/Frame 027332/0829 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 23, 2008
From: SULLIVAN, MICHAEL J.; LADD, DEREK A.; HEBERT, EDMUND A.; JONES, DOUGLAS E.
To: ACUSHNET COMPANY
Reel/Frame 020990/0460 →