INKJET PRINTING PAPER
The invention provides an ink jet recording sheet which is highly resistant to printings smearing, running, feathering, color bleeding, or fading when wet, humid, or exposed to intense or continual light. The recording sheet has a solid substrate and a composition coating the solid substrate. The composition comprises a cationic polymer as well as starch, inorganic salt, pigment, and water. The composition can further comprise a non-ionic polymer. The coating tightly binds both pigment based inkjet inks and dye based inkjet inks. The composition is easy to apply and the ink jet recording sheet can be easily formed with a standard size press device.
1 . An inkjet recording sheet having a substrate with at least one surface and a composition engaged to at least a portion of the at least one surface, the composition comprising at least one cationic polymer and one item selected from the list consisting of starch, inorganic salt, pigment, water, and any combination thereof.
2 . The ink jet recording sheet of claim 1 in which the composition completely coats every surface of the substrate.
3 . The ink jet recording sheet of claim 1 in which the composition further comprises at least one non-ionic polymer.
4 . The ink jet recording sheet of claim 1 in which the substrate is selected from the list consisting of: cellulose, furnish, wet web, web paper, paper, sheet of paper, wood free sheet of paper precursor, wood bearing sheet of paper precursor, treated sheet of paper precursor, untreated sheet of paper precursor, wood free sheet of paper, wood bearing sheet of paper, treated sheet of paper, and untreated sheet of paper.
5 . The ink jet recording sheet of claim 1 in which substrate has been smoothed out by a papermaking machine to reduce the presence of roughness or pores in at least a portion of the surface of the substrate and the composition has been applied to the roughness and pore reduced substrate surface by the papermaking machine.
6 . The ink jet recording sheet of claim 1 in which at least one of the polymers has a reduced specific viscosity which is no greater than 30 dL/g.
7 . The ink jet recording sheet of claim 3 in which the non-ionic polymer is a polyvinyl alcohol with a hydrolysis level above 85%.
8 . The ink jet recording sheet of claim 1 in which the composition contains starch and the starch is one item selected from the list consisting of: an ethylated starch and a cationic starch.
9 . The ink jet recording sheet of claim 1 in which the in which the composition contains an inorganic salt and the inorganic salt is water-soluble and has a charge that is at least a divalent charge.
10 . The ink jet recording sheet of claim 1 in which the pigment is one item selected from the list consisting of: titanium oxide, aluminum oxide, clay, silica, and calcium carbonate.
11 . The ink jet recording sheet of claim 3 in which the cationic polymer and the non-ionic polymer together comprise between 2% and 35% by mass of the composition coating.
12 . The ink jet recording sheet of claim 3 in which molar ratio of cationic polymer to non-ionic polymer is 1:1.
13 . The ink jet recording sheet of claim 3 in which at least one of the at least two polymers is a copolymer.
14 . The ink jet recording sheet of claim 3 in which the cationic polymer is an acrylamide-dimethylaminoethylacrylate benzyl chloride quaternary salt dispersion polymer-acrylamide copolymer.
15 . The ink jet recording sheet of claim 3 in which the non-ionic polymer is a pigment dispersion polymer.
16 . The ink jet recording sheet of claim 3 in which the mass of the coating composition is 1-3% non-ionic polymer, 1-2% cationic polymer, 3-5% starch, 0.5-2% pigment, 0.5-2% salt, and 80% to 94% water.
17 . The ink jet recording sheet of claim 3 in which the mass of the coating composition is 1.8% cationic polymer, 1.5% polyvinyl alcohol polymer, 3.9% cationic starch, 0.8% calcium chloride, and 92% water.
18 . A method of increasing the inkjet ink adhesive properties of paper including the steps of:
providing a solid substrate for making paper,
providing a coating composition, the coating composition comprising at least one cationic polymer, at least one non-ionic polymer, and one item selected from the list consisting of starch, inorganic salt, pigment, water, and any combination thereof, and
coating the solid substrate with the coating composition with a size press device.
19 . The method of claim 19 further comprising the step of synthesizing the coating composition, the synthesizing including the steps of:
providing at least one cationic polymer,
providing at least one non-ionic polymer,
providing at least one item selected from the list consisting of starch, inorganic salt, pigment, water, and any combination thereof,
combining the at least one cationic polymer, the at least one non-ionic polymer, and the one item selected from the list consisting of starch, inorganic salt, pigment, water, and any combination thereof, and
charging the non-ionic polymer after charging the cationic polymer.