Multi-layer core golf ball
View Patent ↗Golf balls comprising a multi-layer core and a cover are disclosed. The multi-layer core comprises a thermoset rubber inner core, a thermoplastic first intermediate core layer, a thermoplastic second intermediate core layer, and a thermoset rubber outer core layer.
1. A golf ball comprising:
an inner core layer formed from a first thermoset rubber composition and having a diameter of from 1.000 inches to 1.580 inches, a center hardness of from 40 Shore C to 65 Shore C, a surface hardness of from 50 Shore C to 85 Shore C, and a positive hardness gradient wherein the difference between the center hardness and the surface hardness of the inner core layer is from 10 to 45;
a first intermediate core layer formed from a first thermoplastic composition and having a thickness of from 0.005 inches to 0.100 inches and a surface hardness of greater than 60 Shore D;
a second intermediate core layer formed from a second thermoplastic composition and having a thickness of from 0.005 inches to 0.100 inches;
an outer core layer formed from a second thermoset rubber composition and having a thickness of from 0.010 inches to 0.100 inches and a surface hardness of 50 Shore C or greater; and
a cover layer having a thickness of from 0.010 inches to 0.050 inches and a surface hardness of 65 Shore D or less.
2. The golf ball of claim 1 , wherein the diameter of the inner core layer is from 1.400 inches to 1.500 inches.
3. The golf ball of claim 1 , wherein the surface hardness of the outer core layer is greater than the surface hardness of the inner core layer.
4. The golf ball of claim 1 , wherein the surface hardness of the inner core layer is from 70 Shore C to 85 Shore C.
5. The golf ball of claim 4 , wherein the surface hardness of the outer core layer is greater than 85 Shore C.
6. The golf ball of claim 1 , wherein the inner core layer has a compression of from 40 to 60.
7. The golf ball of claim 1 , wherein the first and second thermoplastic compositions are independently selected from the group consisting of partially- and fully-neutralized ionomers optionally blended with a maleic anhydride-grafted non-ionomeric polymer, polyesters, polyamides, polyethers, and blends of two or more thereof.
8. The golf ball of claim 1 , wherein the first intermediate core layer is formed from an ionomer composition comprising a blend of two or more ionomers, and wherein the second intermediate core layer is formed from a composition selected from the group consisting of polyesters, polyamides, polyethers, and blends of two or more thereof.
9. The golf ball of claim 1 , wherein the inner core layer is formed from a first polybutadiene composition; the first intermediate core layer is formed from an ionomer composition; the second intermediate core layer is formed from a composition selected from the group consisting of polyesters, polyamides, polyethers, and blends of two or more thereof; the outer core layer is formed from a second polybutadiene composition; and the cover layer is formed from a composition selected from the group consisting of polyurethanes, polyureas, and copolymers and blends thereof.
10. The golf ball of claim 9 , wherein the second polybutadiene composition comprises from 1 phr to 100 phr of a stiffening agent.
11. The golf ball of claim 1 , wherein each of the inner core layer, first intermediate core layer, second intermediate core layer, and outer core layer has a specific gravity of 1.25 g/cc or less.
12. The golf ball of claim 1 , wherein one or more of the inner core layer, first intermediate core layer, second intermediate core layer, and outer core layer has a specific gravity of less than 1.05 g/cc.
13. The golf ball of claim 1 , wherein one or more of the inner core layer, first intermediate core layer, second intermediate core layer, and outer core layer has a specific gravity of less than 0.95 g/cc.