Golf balls having layers made from rubber compositions containing nucleating agents
View Patent ↗Golf balls containing at least one layer made from a rubber composition comprising a benzenetrisamide nucleating agent are provided. The rubber composition preferably contains a free-radical initiator agent, cross-linking agent, and fillers along with the base rubber and nucleating agent. Golf balls of various constructions may be made including two-piece, three-piece, and four-piece balls. The composition is used preferably to form a golf ball core having improved resiliency, durability, toughness, and impact strength.
1. A solid golf ball, comprising a core and a cover, wherein the core is formed from a rubber composition comprising a base rubber and nucleating agent, the nucleating agent being present in the amount of 0.1 to 5 parts by weight per 100 parts of the base rubber and having the following structure:
wherein R 1 , R 2 and R 3 are identical and are cyclopropyl, cyclobutyl, cycloheptyl, 1-adamantyl, 3-methylcyclohexyl, 2,3-dimethylcyclohexyl, 3,3,5-trimethylcyclohexyl, S(+)-1-cyclohexylethyl, R(+)-1-cyclohexylethyl, isopropyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2-butyl, 3-methylbutyl or 1,1,3,3-tetramethylbutyl, the core having a COR value in the range of about 0.60 to about 0.85 and a compression in the range of about 60 to about 90.
2. The golf ball of claim 1 , wherein the rubber composition comprises a base rubber selected from the group consisting of polybutadiene, polyisoprene, natural rubber, a copolymer of ethylene/propylene rubber, a copolymer of ethylene/propylene diene rubber, a copolymer of styrene/butadiene rubber, and mixtures thereof.
3. The golf ball of claim 1 , wherein the base rubber is polybutadiene.
4. The golf ball of claim 1 , wherein the composition further comprises a cross-linking agent selected from the group consisting of zinc acrylate, zinc diacrylate, zinc methacrylate, and zinc dimethacrylate, trimethylolpropane trimethacrylate, and mixtures thereof.
5. The golf ball of claim 1 , wherein the composition further comprises a peroxide free-radical initiator.
6. The golf ball of claim 1 , wherein the composition further comprises a sulfur-based curing agent.
7. The golf ball of claim 1 , wherein the composition further comprises a halogenated organosulfur compound.
8. The golf ball of claim 7 , wherein the halogenated organosulfur compound is zinc pentachlorothiophenol.
9. The golf ball of claim 1 , wherein the core has a diameter in the range of about 1.26 to about 1.60 inches.
10. The golf ball of claim 1 , wherein the cover has a thickness in the range of about 0.015 to about 0.090 inches.
11. The golf ball of claim 1 , wherein an intermediate layer is disposed between the core and cover, the intermediate layer having a thickness in the range of about 0.015 to about 0.120 inches.
12. The golf ball of claim 1 , wherein the core has a surface hardness in the range of about 30 to about 65 Shore D, and the cover has a material hardness in the range of about 30 to about 65 Shore D.
13. The golf ball of claim 11 , wherein the intermediate layer has a material hardness in the range of about 30 to about 75 Shore D.
14. A solid golf ball, comprising an inner core and an outer core layer, the outer core layer encapsulating the inner core; an intermediate layer; and a cover, wherein the intermediate layer is disposed between the outer core layer and cover, the inner core and outer core layer each being formed from a rubber composition comprising a base rubber and nucleating agent, the nucleating agent being present in the amount of 0.1 to 5 parts by weight per 100 parts of the base rubber and having the following structure:
wherein R 1 , R 2 and R 3 are identical and are cyclopropyl, cyclobutyl, cycloheptyl, 1-adamantyl, 3-methylcyclohexyl, 2,3-dimethylcyclohexyl, 3,3,5-trimethylcyclohexyl, S(+)-1-cyclohexylethyl, R(+)-1-cyclohexylethyl, isopropyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2-butyl, 3-methylbutyl or 1,1,3,3-tetramethylbutyl, the inner core and outer core layer, combined together, having a COR value in the range of about 0.60 to about 0.85 and a compression in the range of about 60 to about 90.