METHODS OF CURING POLYURETHANE PREPOLYMERS FOR GOLF BALLS
Multi-piece, solid golf balls having a cover material made from a polyurethane/urea hybrid composition are provided. The balls include an inner core preferably made of polybutadiene and may include at least one intermediate layer disposed between the core and outer cover. The cover materials are prepared by first forming a polyurethane prepolymer which undergoes two curing steps. In the first step, the prepolymer is chemically-cured by reacting it with hydroxyl curing agents, amine curing agents, or mixtures thereof. In the second step, the composition is moisture-cured. The cured material may be used to make a golf ball cover having improved durability, cut/tear resistance, and impact strength.
1 . A method of making a golf ball, comprising the steps of:
forming a core;
forming a cover layer over the core by:
i) mixing an isocyanate compound and polyol compound to produce a polyurethane prepolymer;
ii) chemically-curing the prepolymer by reacting it with a hydroxyl-terminated curing agent at a stoichiometric ratio of isocyanate groups to hydroxyl groups of at least 1.20:1.00 to form a composition;
iii) applying the composition over the core and allowing it to partially-cure; and
iv) moisture-curing the composition to form a cover layer comprising a polyurethane/urea hybrid composition.
2 . The method of claim 1 , wherein the core comprises polybutadiene.
3 . The method of claim 1 , wherein the isocyanate compound is selected from the group consisting of MDI, H 12 MDI, PPDI, TDI, IPDI, HDI, NDI, XDI, TMXDI, THDI, and TMDI, and homopolymers and copolymers and mixtures thereof.
4 . The method of claim 1 , wherein the hydroxyl-terminated curing agent is selected from the group consisting of ethylene glycol, diethylene glycol, polyethylene glycol, propylene glycol, PTMEG, polyethylene propylene glycol, polyoxypropylene glycol, 2-methyl-1,3-propanediol, 2-methyl-1,4-butanediol, and mixtures thereof.
5 . The method of claim 1 , wherein the core has a diameter of about 1.26 to about 1.60 inches.
6 . The method of claim 1 , wherein the cover has a thickness of about 0.015 to about 0.090 inches.
7 . The method of claim 8 , wherein the cover has a thickness of about 0.020 to about 0.040 inches.
8 . The method of claim 1 , wherein the core has a surface hardness in the range of about 30 to about 65 Shore D.
9 . The method of claim 1 , wherein the cover has a material hardness of about 40 to about 65 Shore D.
10 . A method of making a golf ball, comprising the steps of:
forming a core;
forming a cover layer over the core by:
i) mixing an isocyanate compound and polyol compound to produce a polyurethane prepolymer;
ii) chemically-curing the prepolymer by reacting it with an amine-terminated curing agent at a stoichiometric ratio of isocyanate groups to amine groups of at least 1.20:1.00 to form a composition;
iii) applying the composition over the core and allowing it to partially-cure; and
iv) moisture-curing the composition to form a fully-cured cover layer comprising a polyurethane/urea hybrid composition.
11 . The method of claim 10 , wherein the core comprises polybutadiene.
12 . The method of claim 10 , wherein the isocyanate compound is selected from the group consisting of MDI, H 12 MDI, PPDI, TDI, IPDI, HDI, NDI, XDI, TMXDI, THDI, and TMDI, and homopolymers and copolymers and mixtures thereof.
13 . The method of claim 10 , wherein the amine-terminated curing agent is selected from the group consisting of group consisting of 4,4′-diamino-diphenylmethane; 3,5-diethyl-(2,4- or 2,6-) toluenediamine; 3,5-dimethylthio-(2,4- or 2,6-)toluenediamine; 3,5-diethylthio-(2,4- or 2,6-) toluenediamine: 2,2′-dichloro-3,3′,5,5′-tetraethyl-4,4′-diamino-diphenylmethane; polytetramethyleneglycol-di(p-aminobenzoate); 4,4′-bis(sec-butylamino)-dicyclohexylmethane; and mixtures thereof.
14 . The method of claim 10 , wherein the core has a diameter of about 1.26 to about 1.60 inches.
15 . The method of claim 10 , wherein the cover has a thickness of about 0.015 to about 0.090 inches.
16 . The method of claim 15 , wherein the cover has a thickness of about 0.020 to about 0.040 inches.
17 . The method of claim 10 , wherein the core has a surface hardness in the range of about 30 to about 65 Shore D.
18 . The method of claim 10 , wherein the cover has a material hardness of about 40 to about 65 Shore D.
19 . A method of making a golf ball, comprising the steps of:
forming a core;
forming an intermediate layer that encapsulates the core;
forming a cover layer over the intermediate layer by:
i) mixing an isocyanate compound and polyol compound to produce a polyurethane prepolymer;
ii) chemically-curing the prepolymer by reacting it with a hydroxyl-terminated curing agent at a stoichiometric ratio of isocyanate groups to hydroxyl groups of at least 1.20:1.00 to form a composition;
iii) applying the composition over the core and allowing it to partially-cure; and
iv) moisture-curing the composition to form a fully-cured cover layer comprising a polyurethane/urea hybrid composition.
20 . A method of making a golf ball, comprising the steps of:
forming a core;
forming an intermediate layer that encapsulates the core;
forming a cover layer over the intermediate layer by:
i) mixing an isocyanate compound and polyol compound to produce a polyurethane prepolymer;
ii) chemically-curing the prepolymer by reacting it with an amine-terminated curing agent at a stoichiometric ratio of isocyanate groups to amine groups of at least 1.20:1.00 to form a composition;
iii) applying the composition over the core and allowing it to partially-cure; and
iv) moisture-curing the composition to form a fully-cured cover layer comprising a polyurethane/urea hybrid composition.