Light Diffusing Thermoplastic Resin Composition and Light Diffusion Sheet Thereof
The present invention provides a light diffusing thermoplastic resin composition comprising polycaprolactone, specific silicone rubber particles, and, when desired, a fluorescent brightening agent, an antioxidant and/or an ultraviolet light absorber. A light diffusion sheet can be obtained by molding the light diffusing thermoplastic resin composition, which has superior light diffusion properties, luminance, mechanical strength, thermal stability and light resistance.
1 . A light diffusing thermoplastic resin composition comprising 100 parts by weight of a resin component and 0.1 to 1.5 parts by weight of (C) silicone rubber particles having 0.5 μm to 10 μm of the average particle size, wherein the resin component consists of 0.1% to 7% by weight of (A) polycaprolactone and 93% to 99.9% by weight of (B) other transparent thermoplastic resins, and the (C) silicone rubber particles have a framework structure containing difunctional siloxane units and trifunctional siloxane units and have alkyl groups on the surface.
2 . The light diffusing thermoplastic resin composition of claim 1 wherein the viscosity average molecular weight of (A) polycaprolactone is 40,000 to 90,000.
3 . The light diffusing thermoplastic resin composition of claim 1 wherein the content of (A) polycaprolactone is 0.3% to 5% by weight.
4 . The light diffusing thermoplastic resin composition of claim 1 wherein the (B) transparent thermoplastic resin is at least one resin selected from the group consisting of polycarbonate resins, poly(methyl methacrylate), methyl methacrylate-styrene copolymers, polyarylate, polystyrene, styrene type copolymer resins and cycloolefin polymers.
5 . The light diffusing thermoplastic resin composition of claim 1 wherein the alkyl groups on the surface of the (C) silicone rubber particles are methyl groups.
6 . The light diffusing thermoplastic resin composition of claim 1 wherein the average particle size of the (C) silicone rubber particles is from 2 μm to 4 μm.
7 . The light diffusing thermoplastic resin composition of claim 1 wherein the amount of the (C) silicone rubber particles is 0.5 parts to 1.2 parts by weight per 100 parts by weight of the resin component.
8 . The light diffusing thermoplastic resin composition of claim 1 further comprising 0.1 parts or less by weight of (D) a fluorescent brightening agent per 100 parts by weight of the resin component.
9 . The light diffusing thermoplastic resin composition of claim 1 further comprising 1 part or less by weight of (E) an antioxidant per 100 parts by weight of the resin component.
10 . The light diffusing thermoplastic resin composition of claim 9 wherein the (E) antioxidant is a cyclic phosphite ester type compound.
11 . The light diffusing thermoplastic resin composition of claim 9 wherein the (E) antioxidant is 2,4,8,10-tetra-t-butyl-6-[3-(3-methyl-4-hydroxy-5-t-butylphenyl) propoxy] dibenzo[d,f][1,3,2]dioxaphosphepin.
12 . The light diffusing thermoplastic resin composition of claim 1 , further comprising 0.01 parts to 0.8 parts by weight of (F) an ultraviolet light absorber per 100 parts by weight of the resin component.
13 . The light diffusing thermoplastic resin composition of claim 12 wherein the (F) ultraviolet light absorber is a compound represented by a chemical formula below:
wherein R 4 is an alkyl group with 1 to 12 carbon atoms and R 5 is an alkoxy group with 1 to 12 carbon atoms.
14 . A light diffusion sheet obtained by molding the light diffusing thermoplastic resin composition of claim 1 .