IP Library Granted Patent US 8,298,098
Granted Patent B2
US 8,298,098 · App. 12/635,201 · Granted Oct 30, 2012

Multilayer core golf ball having hardness gradient within and between each core layer

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Quick Facts
Patent No.
US 8,298,098
App. No.
12/635,201
Filed
Dec 10, 2009
Granted
Oct 30, 2012
Kind
B2
Art Unit
3711
USPC
473/374
Abstract

The present invention is directed to an improved multi-layered core golf ball wherein each core layer comprises its own specific hardness gradient (positive, negative or a combination) in addition to an overall specific hardness gradient from one core layer to the next.

Claims (70)

1. A golf ball comprising:

a two layer core and a cover disposed about the two layer core,

the two layer core comprising an inner core layer and an outer core layer disposed about the inner core layer,

said inner core layer comprising a geometric center and a first outer surface and being formed from a substantially homogenous formulation and having a diameter of about 30 mm or less and having a plurality of hardnesses of from about 50 Shore C to about 80 Shore C,

the geometric center comprising a first hardness and the first outer surface comprising a second hardness wherein the first hardness is greater than the second hardness to define a negative hardness gradient of about 20 Shore C or less,

said outer core layer comprising an inner surface and a second outer surface and being formed from a substantially homogenous formulation and comprising a thickness of

about 10 mm or less and having a plurality of hardnesses of from about 50 Shore C to about 90 Shore C,

the inner surface comprising a third hardness and the second outer surface comprising a fourth hardness, wherein the fourth hardness is greater than the third hardness,

the outer core layer further comprising a fifth hardness disposed between the inner surface and the second outer surface in a region extending between about 10% and about 90% of the distance from the inner surface to the second outer surface, wherein the fifth hardness is greater than the first hardness, the third hardness and the fourth hardness, and

wherein the fourth hardness is greater than the first hardness to define a two layer core having a positive hardness gradient of less than about 20 Shore C.

2. The golf ball of claim 1 , wherein the third hardness is similar to the second hardness.

3. The golf ball of claim 1 , wherein the diameter of the inner core layer is about 26 mm or less.

4. The golf ball of claim 1 , wherein the first hardness is greater than the second hardness to define a negative hardness gradient of about 15 Shore C or less.

5. The golf ball of claim 1 , wherein the fourth hardness is greater than the first hardness to define a two layer core having a positive hardness gradient of less than about 15 Shore C.

6. The golf ball of claim 1 , wherein the inner core layer comprises antioxidant in an amount of from about 0.2 phr to about 2.5 phr and the outer core layer comprises antioxidant in an amount of about 1.2 phr or less.

7. The golf ball of claim 1 , wherein the inner core layer comprises peroxide in an amount of from about 0.5 phr to about 2.0 phr and the outer core comprises peroxide in an amount of from about 0.6 phr to about 2.5 phr.

8. The golf ball of claim 1 , wherein the ratio of antioxidant to peroxide for the inner core layer is about 2.5 or less.

9. The golf ball of claim 1 , wherein the ratio of antioxidant to peroxide for the outer core layer is about 2.0 or less.

10. A golf ball comprising:

a two layer core and a cover disposed about the two layer core,

the two layer core comprising an inner core layer and an outer core layer disposed about the inner core layer,

said inner core layer comprising a geometric center and a first outer surface and being formed from a substantially homogenous formulation and having a diameter of about 30 mm or less and having a plurality of hardnesses of from about 50 Shore C to about 80 Shore C,

the geometric center comprising a first hardness and the first outer surface comprising a second hardness wherein the first hardness is greater than the second hardness to define a negative hardness gradient of about 20 Shore C or less,

said outer core layer comprising an inner surface and a second outer surface and being formed from a substantially homogenous formulation and comprising a thickness of about 10 mm or less and having a plurality of hardnesses of from about 50 Shore C to about 80 Shore C,

the inner surface comprising a third hardness and the second outer surface comprising a fourth hardness, wherein the fourth hardness similar to the third hardness,

the outer core layer further comprising a fifth hardness disposed between the inner surface and the second outer surface in a region extending between about 10% and about 90% of the distance from the inner surface to the second outer surface, wherein the fifth hardness is greater than the third hardness and the fourth hardness and similar to the first hardness, and

wherein the fourth hardness is less than the first hardness to define a two layer core having a negative hardness gradient of less than about 10 Shore C.

11. The golf ball of claim 10 , wherein the third hardness is similar to the second hardness.

12. The golf ball of claim 10 , wherein the diameter of the inner core layer is about 26 mm or less.

13. The golf ball of claim 10 , wherein the first hardness is greater than the second hardness to define a negative hardness gradient of about 15 Shore C or less.

14. The golf ball of claim 10 , wherein the fourth hardness is less than the first hardness to define a two layer core having a negative hardness gradient of less than about 7 Shore C.

15. The golf ball of claim 10 , wherein the inner core layer comprises antioxidant in an amount of from about 0.2 phr to about 2.5 phr and the outer core layer comprises antioxidant in an amount of about 1.2 phr or less.

16. The golf ball of claim 10 , wherein the inner core layer comprises peroxide in an amount of from about 0.5 phr to about 2.0 phr and the outer core comprises peroxide in an amount of from about 0.6 phr to about 2.5 phr.

17. The golf ball of claim 10 , wherein the ratio of antioxidant to peroxide for the inner core layer is about 2.5 or less.

18. The golf ball of claim 10 , wherein the ratio of antioxidant to peroxide for the outer core layer is about 2.0 or less.

19. A golf ball comprising:

a two layer core and a cover disposed about the two layer core,

the two layer core comprising an inner core layer and an outer core layer disposed about the inner core layer,

said inner core layer comprising a geometric center and a first outer surface and being formed from a substantially homogenous formulation and having a diameter of about 30 mm or less and having a plurality of hardnesses of from about 25 Shore D to about 55 Shore D,

the geometric center comprising a first hardness and the first outer surface comprising a second hardness wherein the first hardness is greater than the second hardness to define a negative hardness gradient of about 20 Shore D or less;

said outer core layer comprising an inner surface and a second outer surface and being formed from a substantially homogenous formulation and comprising a thickness of about 10 mm or less and having a plurality of hardnesses of from about 30 Shore D to about 69 Shore D,

the inner surface comprising a third hardness and the second outer surface comprising a fourth hardness, wherein the fourth hardness is greater than the third hardness,

the outer core layer further comprising a fifth hardness disposed between the inner surface and the second outer surface in a region extending between about 10% and about 90% of the distance from the inner surface to the second outer surface, wherein the fifth hardness is greater than the third hardness and the fourth hardness, and

wherein the fourth hardness is greater than the first hardness to define a two layer core having a positive hardness gradient of less than about 45 Shore D.

20. The golf ball of claim 19 , wherein the third hardness is similar to the second hardness.

21. The golf ball of claim 19 , wherein the diameter of the inner core layer is about 26 mm or less.

22. The golf ball of claim 19 , wherein the first hardness is greater than the second hardness to define a negative hardness gradient of about 15 Shore D or less.

23. The golf ball of claim 19 , wherein the fourth hardness is greater than the first hardness to define a two layer core having a positive hardness gradient of less than about 35 Shore D.

24. The golf ball of claim 19 , wherein the inner core layer comprises antioxidant in an amount of from about 0.2 phr to about 2.5 phr and the outer core layer comprises antioxidant in an amount of about 1.2 phr or less.

25. The golf ball of claim 19 , wherein the inner core layer comprises peroxide in an amount of from about 0.5 phr to about 2.0 phr and the outer core comprises peroxide in an amount of from about 0.6 phr to about 2.5 phr.

26. The golf ball of claim 19 , wherein the ratio of antioxidant to peroxide for the inner core layer is about 2.5 or less.

27. The golf ball of claim 19 , wherein the ratio of antioxidant to peroxide for the outer core layer is about 2.0 or less.

28. A golf ball comprising:

a two layer core and a cover disposed about the two layer core,

the two layer core comprising an inner core layer and an outer core layer disposed about the inner core layer,

said inner core layer comprising a geometric center and a first outer surface and being formed from a substantially homogenous formulation and having a diameter of about 30 mm or less and having a plurality of hardnesses of from about 25 Shore D to about 55 Shore D,

the geometric center comprising a first hardness and the first outer surface comprising a second hardness wherein the first hardness is greater than the second hardness to define a negative hardness gradient of about 20 Shore D or less;

said outer core layer comprising an inner surface and a second outer surface and being formed from a substantially homogenous formulation and comprising a thickness of about 10 mm or less and having a plurality of hardnesses of from about 30 Shore D to about 52 Shore D,

the inner surface comprising a third hardness and the second outer surface comprising a fourth hardness, wherein the fourth hardness is greater than the third hardness,

the outer core layer further comprising a fifth hardness disposed between the inner surface and the second outer surface in a region extending between about 10% and about 90% of the distance from the inner surface to the second outer surface, wherein the fifth hardness is greater than the third hardness and the fourth hardness, and

wherein the fourth hardness is less than the first hardness to define a two layer core having a negative hardness gradient of no greater than about 10 Shore D.

29. The golf ball of claim 28 , wherein the fifth hardness is similar to the first hardness.

30. The golf ball of claim 28 , wherein the third hardness is similar to the second hardness.

31. The golf ball of claim 28 , wherein the diameter of the inner core layer is about 26 mm or less.

32. The golf ball of claim 28 , wherein the first hardness is greater than the second hardness to define a negative hardness gradient of about 15 Shore D or less.

33. The golf ball of claim 28 , wherein the fourth hardness is less than the first hardness to define a two layer core having a negative hardness gradient of no greater than about 8 Shore D.

34. The golf ball of claim 28 , wherein the inner core layer comprises antioxidant in an amount of from about 0.2 phr to about 2.5 phr and the outer core layer comprises antioxidant in an amount of about 1.2 phr or less.

35. The golf ball of claim 28 , wherein the inner core layer comprises peroxide in an amount of from about 0.5 phr to about 2.0 phr and the outer core comprises peroxide in an amount of from about 0.6 phr to about 2.5 phr.

36. The golf ball of claim 28 , wherein the ratio of antioxidant to peroxide for the inner core layer is about 2.5 or less.

37. The golf ball of claim 28 , wherein the ratio of antioxidant to peroxide for the outer core layer is about 2.0 or less.

Assignments (5)
ASSIGNMENT OF SECURITY INTEREST IN PATENTS (ASSIGNS 039506-0030) Recorded Aug 3, 2022
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS RESIGNING ADMINISTRATIVE AGENT
To: JPMORGAN CHASE BANK, N.A., AS SUCCESSOR ADMINISTRATIVE AGENT
Reel/Frame 061521/0414 →
RELEASE OF SECURITY INTEREST IN PATENTS PREVIOUSLY RECORDED AT REEL/FRAME (027347/0053) Recorded Sep 7, 2016
From: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
To: ACUSHNET COMPANY
Reel/Frame 039939/0259 →
SECURITY INTEREST Recorded Jul 28, 2016
From: ACUSHNET COMPANY
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 039506/0030 →
SECURITY AGREEMENT Recorded Dec 8, 2011
From: ACUSHNET COMPANY
To: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
Reel/Frame 027347/0053 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 10, 2009
From: SULLIVAN, MICHAEL J.; COMEAU, BRIAN; GOGUEN, DOUGLAS S.; BULPETT, DAVID A.
To: ACUSHNET COMPANY
Reel/Frame 023636/0115 →