Method for making nitrogen aromatic oligomers and polymers

1. A method for polymerizing pyridine, comprising:

contacting a composition comprising pyridine with a catalyst composition, wherein the catalyst comprises:

a first metal selected from the group consisting of Mg, V, Cr, Zn, AL, Li, Na, K, Be, Ca, Sr, Ba, Ti, Si, and alloys thereof, and

a second reduced metal coated over the first metal, wherein the second metal is selected from the group consisting of Ni, Co, Cu, Ti, V, Re, Ru, Rh, Ir, Pd, Pt, Ag, Au, and alloys thereof.

2. The method according to claim 1 , wherein the catalyst is in the form of particles having an average diameter of less than about 500 μm.

3. The method according to claim 1 , wherein the catalyst is in particulate form and has sufficient surface area to catalyze a polymerization, the first metal forms a core of the catalyst particles, and the second metal is disposed on the core.

4. The method according to claim 3 , wherein the first metal comprises Mg or alloys thereof.

5. The method according to claim 3 , wherein the first metal comprises Mg or Mg alloy and the second metal comprises Ni, Cu, Co, or alloys thereof.

6. The method according to claim 1 further comprising adding the catalyst composition to the pyridine composition.

7. The method according to claim 1 , comprising forming the catalyst in the presence of the pyridine composition.

8. The method according to claim 7 , comprising adding particles comprising the first metal to the pyridine composition and adding a salt comprising the second metal to the pyridine composition.

9. The method according to claim 8 , comprising Soxhlet extraction of the salt into the pyridine.

10. A method for producing oligomeric nitrogen aromatic products comprising:

a) contacting a composition comprising a nitrogen aromatic with a catalyst composition; and

b) reacting for a time sufficient to favor formation of an oligomeric product over a dimeric product,

wherein the nitrogen aromatic comprises a compound or compounds represented by the structure

wherein

X is —N— or —CR 2 —; and

R 2 and R 3 are independently selected from the group consisting of hydrogen and alkyl, aryl, heterocyclyl, heteroaryl, or cycloalkyl groups containing 1 to 20 carbons; and the catalyst composition comprises a first metal substrate having a second reduced metal coated on the substrate, wherein the first metal is selected from the group consisting of Mg, V, Cr, Zn, Al, Li, Na, K, Be, Ca, Sr, Ba, Ti, Si, and alloys thereof, and the second metal is selected from the group consisting of Ni, Co, Cu, Ti, V, Re, Ru, Rh, Ir, Pd, Pt, Ag, Au, and alloys thereof.

11. The method according to claim 10 , wherein the catalyst is in a form selected from a mesh having a mesh size of from 40 to 80 mesh or particles having an average diameter less than about 500 μm.

12. The method according to claim 10 , wherein the catalyst is in particulate form and has sufficient surface area to catalyze a polymerization, the first metal forms a core of the catalyst particles, and the second metal is disposed on the core.

13. The method according to claim 12 , wherein the first metal comprises Mg or Mg alloy and the second metal comprises Ni, Cu, Co, or alloys thereof.

14. The method according to claim 10 , further comprising adding the catalyst composition to the pyridine composition.

15. The method according to claim 10 , further comprising forming the catalyst in the presence of the pyridine composition.

16. A method for synthesizing higher polymeric reaction products of nitrogen aromatics, comprising: contacting a composition comprising the nitrogen aromatic with a catalyst composition, wherein the nitrogen aromatic composition comprises a compound or a mixture of compounds represented by the structure

wherein

X is —N— or —CR 2 —;

R 1 , R 2 , and R 3 are independently selected from the group consisting of hydrogen or alkyl, aryl, heterocyclyl, heteroaryl, or cycloalkyl groups containing 1 to 20 carbons; and

wherein the catalyst composition is in particulate form having an average diameter less than about 500 μm and comprises a first metal substrate having a second reduced metal coated on the substrate, wherein the first metal comprises Mg or Mg alloy and the second metal comprises Ni, Cu, Co, or alloys thereof.

17. The method according to claim 16 , wherein the contacting is performed in a solvent selected from the group consisting of: acetonitrile, toluene, xylene, pyridine, pyridimine, and combinations thereof.

18. The method according to claim 16 , wherein the reaction product comprises a copolymer of pyridine and a different aromatic nitrogen compound.

19. The method according to claim 16 , further wherein the reaction product comprises at least 50 mole % pyridine.

20. The method according to claim 16 , wherein the catalyst comprises from about 0.1 to about 5% of the second reduced metal by weight.