Two-component coating compositions
The present invention relates to isocyanate-curing two-component coating compositions containing urethane compounds having at least two —O—CO—NH-groups. The invention relates to coating compositions comprising A) at least one binder having functional groups containing active hydrogen, B) at least one polyisocyanate crosslinking agent having free isocyanate groups and C) at least one urethane compound having at least two —O—CO—NH-groups, wherein the urethane compound has a number-average molecular mass Mn of from 400 to 5,000 and is substantially free from functional groups which are capable of entering into a crosslinking reaction with components A) and/or B). Preferred urethane compounds C) are obtained by reacting polyisocyanate compounds with monohydroxy compounds.
1. Coating compositions comprising:
A) at least one binder having functional groups containing active hydrogen,
B) at least one polyisocyanate crosslinking agent having free isocyanate groups and
C) 5-20% by weight of at least one urethane compound C) (solid) based on the amount of the at least one binder A) (solid) having at least two —O—CO—NH— groups, wherein the urethane compound is substantially free from functional groups which are capable of entering into a crosslinking reaction with components A) and/or B), said urethane compound being prepared by reacting a mixture consisting of i) the isocyanurate of hexamethylene diisocyanate and/or the isocyanurate of isophorone diisocyanate; ii) with monohydroxy compounds; and optionally iii) organic solvents.
2. Coating compositions according to claim 1 , wherein the urethane compound C) has a number-average molecular mass Mn of from 400 to 5,000.
3. Coating compositions according to claim 1 , wherein the at least one urethane compound C) is prepared by reacting the isocyanurate of hexamethylene diisocyanate and/or the isocyanurate of isophorone diisocyanate with cyclo(aliphatic) monoalcohols containing 1-22 carbon atoms in the alkyl part.
4. Coating compositions according to claim 1 , wherein the at least one urethane compound C) is prepared by reacting the isocyanurate of hexamethylene diisocyanate and/or the isocyanurate of isophorone diisocyanate with cyclohexanol.
5. Coating compositions according to claim 1 , wherein the component A) contains hydroxyfunctional (meth)acrylic copolymers.
6. Coating compositions according to claim 5 , wherein the (meth)acrylic copolymers have a number-average molecular mass of from 1,500 to 6,000, an acid number of from 5 to 35 mg KOH/g of solid resin and a hydroxyl number of from 60 to 150 mg KOH/g of solid resin.
7. Coating compositions according to claim 1 , wherein the coating compositions are water-based.
8. Coating compositions according to claim 1 wherein said coating compositions are clear coats in multi-coat paintings of vehicle refinishing paintings.
9. Coating compositions according to claim 1 wherein said coating compositions are pigmented top coats in multi-coat paintings of vehicle refinishing paintings.
10. The coating composition of claim 1 wherein the monohydroxy compound is cyclohexanol.