Rapid drying lacquers
View Patent ↗Disclosed is a solventborne coating composition that provides a high quality basecoat especially for automotive substrates, methods for forming a layer of the solventborne coating composition and substrates coated with the coating composition. The coating composition contains an acrylic polymer that has both acid functional groups and polyether functional groups.
1. A solventborne basecoating composition comprising;
i. at least one solventborne acrylic copolymer which is a random copolymer comprising;
1. 2 percent to 10 percent by weight of a carboxylic acid monomer;
2. 1 percent to 5 percent of a polyether functional monomer, wherein the percents by weight are based on the total weight of the acrylic copolymer;
ii. pigment; and
iii. organic solvent,
and wherein the solventborne basecoat composition is substantially free from water.
2. The solventborne basecoating composition of claim 1 wherein the carboxylic acid functional monomer is selected from the group consisting of acrylic acid, methacrylic acid and a combination thereof.
3. The solventborne basecoating composition of claim 1 wherein the polyether functional monomer is H2C═C(R)C(O)O—(XO) n —R1; wherein R is H or CH3; X is an alkyl group having in the range of from 2 to 4 carbon atoms; n is from 2 to 10; and R1 is H or an alkyl group having in the range of from 1 to 6 carbon atoms.
4. The solventborne basecoating composition of claim 1 wherein the polyether functional monomer is ethoxytriethyleneglycol methacrylate or ethoxytriethyleneglycol acrylate.
5. The solventborne basecoat composition of claim 1 wherein the weight average molecular weight of the acrylic copolymer is in the range of from 25,000 to 55,000.
6. The solventborne basecoat of claim 1 wherein the acrylic copolymer further comprises monomers selected from the group consisting of styrene, alkyl acrylates, alkyl methacrylates, hydroxy alkyl acrylates, hydroxy alkyl methacrylates and a combination thereof.
7. A method for coating a substrate comprising the step of applying a solventborne coating composition to a substrate wherein the coating composition comprises;
i. at least one solventborne acrylic copolymer which is a random copolymer comprising;
1. 2 percent to 10 percent by weight of a carboxylic acid monomer;
2. 1 percent to 5 percent of a polyether functional monomer, wherein the percents by weight are based on the total weight of the acrylic copolymer;
ii. pigment; and
iii. organic solvent,
and wherein the solventborne basecoat composition is substantially free from water.
8. The method of claim 7 wherein the carboxylic acid functional monomer is selected from the group consisting of acrylic acid, methacrylic acid and a combination thereof.
9. The method of claim 7 wherein the polyether functional monomer is H2C═C(R)C(O)O—(XO) n —R1; wherein R is H or CH3; X is an alkyl group having in the range of from 2 to 4 carbon atoms; n is from 2 to 10; and R1 is H or an alkyl group having in the range of from 1 to 6 carbon atoms.
10. The method of claim 7 wherein the polyether functional monomer is ethoxytriethyleneglycol methacrylate or ethoxytriethyleneglycol acrylate.
11. The method of claim 7 wherein the weight average molecular weight of the acrylic copolymer is in the range of from 25,000 to 55,000.
12. The method of claim 7 wherein the acrylic copolymer further comprises monomers selected from the group consisting of styrene, alkyl acrylates, alkyl methacrylates, hydroxy alkyl acrylates, hydroxy alkyl methacrylates and a combination thereof.
13. The method of claim 7 further comprising applying a layer of a clearcoat composition over the applied layer of solventborne coating composition.
14. The method of claim 12 wherein the layer of solventborne basecoat composition is flash dried prior to applying the layer of clearcoat composition.
15. A substrate coated by a layer of a basecoat composition said basecoating composition comprising;
i. at least one solventborne acrylic copolymer which is a random copolymer comprising;
1. 2 percent to 10 percent by weight of a carboxylic acid monomer;
2. 1 percent to 5 percent of a polyether functional monomer, wherein the percents by weight are based on the total weight of the acrylic copolymer;
ii. pigment; and
iii. organic solvent,
and wherein the solventborne basecoat composition is substantially free from water.
16. The substrate of claim 15 wherein the layer of the basecoat composition is further coated by a layer of a clearcoat composition.
17. The substrate of claim 15 wherein the basecoat composition is uncrosslinked or crosslinked.
18. The substrate of claim 15 wherein the carboxylic acid functional monomer is selected from the group consisting of acrylic acid, methacrylic acid and a combination thereof.
19. The substrate of claim 15 wherein the polyether functional monomer is H2C═C(R)C(O)O—(XO) n —R1; wherein R is H or CH3; X is an alkyl group having in the range of from 2 to 4 carbon atoms; n is from 2 to 10; and R1 is H or an alkyl group having in the range of from 1 to 6 carbon atoms.
20. The substrate of claim 15 wherein the polyether functional monomer is ethoxytriethyleneglycol methacrylate or ethoxytriethyleneglycol acrylate.
21. The substrate of claim 15 wherein the weight average molecular weight of the acrylic copolymer is in the range of from 25,000 to 55,000.
22. The substrate of claim 15 wherein the acrylic copolymer further comprises monomers selected from the group consisting of styrene, alkyl acrylates, alkyl methacrylates, hydroxy alkyl acrylates, hydroxy alkyl methacrylates and a combination thereof.