IP Library Granted Patent US 8,852,301
Granted Patent B1
US 8,852,301 · App. 12/828,028 · Granted Oct 7, 2014

Composition of lignin pellets and system for producing

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Quick Facts
Patent No.
US 8,852,301
App. No.
12/828,028
Granted
Oct 7, 2014
Kind
B1
Abstract

A system for treating biomass for the production of a composition of lignin pellets .is disclosed. Pellets comprising at least 50 percent lignin by dry weight is disclosed. Also disclosed are pellets produced from a lignin composition by a process comprising: pre-treating lignocellulosic biomass into pre-treated biomass; separating the pre-treated biomass into a first liquid component comprising sugars and a first solids component comprising cellulose and the lignin composition; hydrolysing the first solids component of the pre-treated biomass into a hydrolysed biomass comprising sugars and the lignin composition; separating the hydrolysed biomass into a second liquid component comprising sugars and a second solids component comprising the lignin composition; supplying the second solids component comprising the lignin composition to a pelleting apparatus to produce the pellets; wherein the lignocellulosic biomass comprises cellulose, hemi-cellulose and lignin. According to an aspect, at least a portion of the lignin is not sulfonated.

Claims (38)

1. Pellets comprising lignin, wherein the pellets comprise at least 50 percent lignin by dry weight and from 40 to 75 weight percent moisture.

2. The pellets of claim 1 , wherein the pellets comprise at least 65 percent lignin by dry weight.

3. The pellets of claim 1 , wherein the pellets comprise at least 80 percent lignin by dry weight.

4. The pellets of claim 1 , wherein the pellets comprise at least 90 percent lignin by dry weight.

5. The pellets of claim 1 , wherein the pellets comprise at least 95 percent lignin by dry weight.

6. The pellets of claim 1 , wherein the lignin is recovered from lignocellulosic biomass comprising at least one of corn cobs, corn plant husks, corn plant leaves, corn plant stalks, or combinations thereof.

7. The method of claim 6 wherein the lignocellulosic biomass consists essentially of corn cobs, corn plant husks, corn plant leaves, corn stalks, or combinations thereof.

8. The pellets of claim 1 , wherein the pellets comprise an agent selected from the group consisting of ash, fiber, saw dust, distillers dried grains, or combinations thereof.

9. The pellets of claim 8 , wherein the agent comprises no more than 50 percent of the pellets by dry weight.

10. The pellets of claim 1 , wherein at least a majority of the lignin is not sulfonated.

11. Pellets produced from a lignin composition by a process comprising:

pre-treating lignocellulosic biomass into pre-treated biomass;

separating the pre-treated biomass into a first liquid component comprising sugars and a first solids component comprising cellulose and the lignin composition;

hydrolysing the first solids component of the pre-treated biomass into a hydrolysed biomass comprising sugars and the lignin composition;

separating the hydrolysed biomass into a second liquid component comprising sugars and a second solids component comprising the lignin composition;

supplying the second solids component comprising the lignin composition to a pelleting apparatus to produce the pellets;

wherein the lignocellulosic biomass comprises cellulose, hemi-cellulose and lignin, and

wherein the pellets comprise at least 50 percent lignin by dry weight and from 40 to 75 weight percent moisture.

12. The pellets of claim 11 , wherein the supplying comprises supplying the second solids component to a pelleting apparatus comprising a disk pelletizer.

13. The pellets of claim 11 , wherein the process further comprises:

supplying the second solids component to a fermentation system to produce fermentation product;

separating the fermentation product to a third liquid component and a third solids component comprising the lignin composition; and

supplying the third solids component to the pelleting apparatus to produce the pellets.

14. The pellets of claim 11 , wherein the pellets comprise at least 65 percent lignin by dry weight.

15. The pellets of claim 11 , wherein the process further comprises supplying the second solids component to a treatment system to increase the concentration of lignin in the lignin composition.

16. The pellets of claim 15 , wherein the pellets comprise at least 80 percent lignin by dry weight.

17. The pellets of claim 15 , wherein the pellets comprise at least 90 percent lignin by dry weight.

18. The pellets of claim 15 , wherein the pellets comprise at least 95 percent lignin by dry weight.

19. The pellets of claim 11 , wherein the process further comprises drying the pellets.

20. The pellets of claim 11 , wherein the lignocellulosic biomass comprises at least one of corn cobs, corn plant husks, corn plant leaves, corn plant stalks, or combinations thereof.

21. The pellets of claim 11 , wherein the lignocellulosic biomass consists essentially of corn cobs, corn plant husks, corn plant leaves, corn stalks, or combinations thereof.

22. The pellets of claim 11 , wherein at least a portion of the lignin is not sulfonated.

23. The pellets of claim 1 , comprising from about 57-67 percent lignin and from about 2 to 22 weight percent ash based on total solids.

24. The pellets of claim 1 , comprising from about 57-67 percent lignin, from about 5.5 to 7.5 percent cellulose, and from about 1.8 to 3.9 percent hemicellulose based on total solids.

25. The pellets of claim 1 , comprising from 40 to 65 percent moisture.

26. The pellets of claim 1 , comprising from 45 to 55 percent moisture.

27. Pellets comprising lignin, wherein the pellets comprise from about 57-67 percent lignin, and from about 2 to 22 weight percent ash based on total solids.

28. Pellets comprising lignin, wherein the pellets comprise from about 57-67 percent lignin, from about 5.5 to 7.5 percent cellulose, and from about 1.8 to 3.9 percent hemicellulose based on total solids.

Assignments (8)
SECURITY INTEREST Recorded Apr 3, 2020
From: POET RESEARCH, INC.
To: COBANK, ACB, AS ADMINISTRATIVE AGENT
Reel/Frame 052312/0801 →
RELEASE OF SECURITY INTEREST RECORDED AT REEL/FRAME 035603/0778 Recorded Apr 2, 2020
From: JPMORGAN CHASE BANK N.A., AS ADMINISTRATIVE AGENT
To: POET, LLC; POET RESEARCH, INC.; POET PLANT MANAGEMENT, LLC; POET INVESTMENTS, INC.; POET BIOMASS, LLC; POET DESIGN AND CONSTRUCTION, INC.; RISK MANAGEMENT ASSOCIATES, INC.; POET NUTRITION, INC.; POET RESEARCH CENTER, LLC (FORMERLY KNOWN AS POET RESEARCH CENTER, INC.); POET LEASING, LLC; POET NUTRITION INTERNATIONAL, INC.
Reel/Frame 052299/0676 →
SECURITY INTEREST Recorded Apr 2, 2020
From: POET RESEARCH, INC.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 052295/0712 →
RELEASE OF PATENT, TRADEMARK AND COPYRIGHT SECURITY INTEREST Recorded May 6, 2015
From: BOKF, N.A., DBA BANK OF OKLAHOMA
To: POET RESEARCH, INC. F/K/A BROIN AND ASSOCIATES, INC.; POET, LLC F/K/A BROIN COMPANIES, LLC; POET INVESTMENTS, INC. F/K/A BROIN ENTERPRISES, INC.; POET PLANT MANAGEMENT, LLC
Reel/Frame 035603/0610 →
ACKNOWLEDGEMENT OF SECURITY INTEREST IN PATENTS Recorded May 6, 2015
From: POET, LLC; POET RESEARCH, INC.; POET PLANT MANAGEMENT, LLC; POET INVESTMENTS, INC.; POET BIOMASS, LLC; POET DESIGN AND CONSTRUCTION, INC.; RISK MANAGEMENT ASSOCIATES, INC.; POET NUTRITION, INC.; POET RESEARCH CENTER, INC.; POET LEASING, LLC; POET NUTRITION INTERNATIONAL, INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 035603/0778 →
SECURITY INTEREST Recorded Aug 7, 2014
From: POET RESEARCH, INC. F/K/A BROIN AND ASSOCIATES, INC.
To: BOKF, NA DBA BANK OF OKLAHOMA
Reel/Frame 033494/0016 →
SECURITY AGREEMENT Recorded Feb 11, 2011
From: POET RESEARCH, INC.
To: BOKF, NA, D/B/A BANK OF OKLAHOMA
Reel/Frame 025783/0430 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 28, 2010
From: BOOTSMA, JASON
To: POET RESEARCH, INC.
Reel/Frame 024751/0467 →