IP Library Granted Patent US 9,145,487
Granted Patent B2
US 9,145,487 · App. 12/936,493 · Granted Sep 29, 2015

Plasticized PVC compositions with long term high temperature stability

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Quick Facts
Patent No.
US 9,145,487
App. No.
12/936,493
Granted
Sep 29, 2015
Kind
B2
Abstract

A stable, plasticized composition of PVC polymer including a C 4 -C 30 alkyl pyrrolidone to plasticize said PVC into a flexible state and an organic phosphite ester stabilizer to impart long term high temperature stability.

Claims (9)

1. A metal free, stable plasticized composition of polyvinyl chloride (PVC) polymer comprising:

(a) an alkylpyrrolidone plasticizer, wherein the alkyl pyrrolidone comprises linear N-dodecyl (C12) pyrrolidone (NDP) in an amount of 5-400 phr sufficient to plasticize said PVC into a flexible state; and

(b) alkyl bisphenol-A phosphite in an amount sufficient to prolong heat stability by delaying discoloration for at least 30 minutes at temperatures from about 140° C. to about 200° C.

2. The stable plasticized composition according to claim 1 , wherein the alkyl bisphenol-A phosphite is present in an amount from about 0.5 phr to about 5 phr.

3. The stable plasticized composition according to claim 1 , wherein the alkyl bisphenol-A phosphite is present in an amount from about 2 phr to about 3 phr.

4. The stable plasticized composition according to claim 1 , wherein the stabilized composition has about 30 to 50 minutes longer heat stability at temperature higher than about 180° C.

5. The stable plasticized composition according to claim 1 , free of heavy metal and solvent.

6. The stable plasticized composition according to claim 1 , further comprising one or more primary stabilizers and other PVC compounding ingredients.

7. The stable plasticized composition of PVC polymer according to claim 1 in the form of calendared sheet, plastisol, foam, dispersions, film, siding, pipe or tubing.

Assignments (4)
RELEASE OF SECURITY INTEREST Recorded Jan 10, 2020
From: THE BANK OF NOVA SCOTIA
To: AVOCA LLC; HERCULES LLC; ISP INVESTMENTS LLC; PHARMACHEM LABORATORIES LLC
Reel/Frame 051557/0504 →
SECURITY AGREEMENT Recorded Jul 3, 2017
From: AVOCA, INC.; HERCULES LLC; ISP INVESTMENTS LLC; PHARMACHEM LABORATORIES, INC.
To: THE BANK OF NOVA SCOTIA, AS ADMINISTRATIVE AGENT
Reel/Frame 043084/0753 →
RELEASE OF PATENT SECURITY AGREEMENT Recorded Mar 18, 2013
From: THE BANK OF NOVA SCOTIA
To: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; AQUALON COMPANY; ISP INVESTMENTS INC.; HERCULES INCORPORATED
Reel/Frame 030025/0320 →
SECURITY AGREEMENT Recorded Sep 16, 2011
From: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; HERCULES INCORPORATED; AQUALON COMPANY; ISP INVESTMENT INC.
To: THE BANK OF NOVA SCOTIA, AS ADMINISTRATIVE AGENT
Reel/Frame 026918/0052 →