Plasticized PVC compositions with long term high temperature stability
View Patent ↗A stable, plasticized composition of PVC polymer including a C 4 -C 30 alkyl pyrrolidone to plasticize said PVC into a flexible state and an organic phosphite ester stabilizer to impart long term high temperature stability.
1. A metal free, stable plasticized composition of polyvinyl chloride (PVC) polymer comprising:
(a) an alkylpyrrolidone plasticizer, wherein the alkyl pyrrolidone comprises linear N-dodecyl (C12) pyrrolidone (NDP) in an amount of 5-400 phr sufficient to plasticize said PVC into a flexible state; and
(b) alkyl bisphenol-A phosphite in an amount sufficient to prolong heat stability by delaying discoloration for at least 30 minutes at temperatures from about 140° C. to about 200° C.
2. The stable plasticized composition according to claim 1 , wherein the alkyl bisphenol-A phosphite is present in an amount from about 0.5 phr to about 5 phr.
3. The stable plasticized composition according to claim 1 , wherein the alkyl bisphenol-A phosphite is present in an amount from about 2 phr to about 3 phr.
4. The stable plasticized composition according to claim 1 , wherein the stabilized composition has about 30 to 50 minutes longer heat stability at temperature higher than about 180° C.
5. The stable plasticized composition according to claim 1 , free of heavy metal and solvent.
6. The stable plasticized composition according to claim 1 , further comprising one or more primary stabilizers and other PVC compounding ingredients.
7. The stable plasticized composition of PVC polymer according to claim 1 in the form of calendared sheet, plastisol, foam, dispersions, film, siding, pipe or tubing.