IP Library Granted Patent US 8,444,508
Granted Patent B2
US 8,444,508 · App. 12/945,069 · Granted May 21, 2013

Golf balls comprising highly- and partially-neutralized alternate copolymers

Inventors: Murali Rajagopalan (South Dartmouth, MA); Michael J. Sullivan (Barrington, RI)
Assignee: Acushnet Company
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Quick Facts
Patent No.
US 8,444,508
App. No.
12/945,069
Granted
May 21, 2013
Kind
B2
Abstract

A golf ball includes a core having a diameter, a first Shore D hardness and a compression; and a cover having a second Shore D hardness that is at least 5 points less than the first Shore D hardness. The cover includes an ionomer of an alternate copolymer, the alternate copolymer being formed from the reaction product of a copolymer of ethylene and maleic anhydride monomer in the presence of a suitable base, the maleic anhydride monomer being present in an amount of about 78 wt %.

Claims (18)

1. A golf ball, comprising:

a core having a diameter, a first Shore D hardness and a compression; and

a cover having a second Shore D hardness that is at least 5 points greater than the first Shore D hardness;

wherein the cover comprises an ionomer of an alternate copolymer, the alternate copolymer comprising the reaction product of a copolymer of ethylene and maleic anhydride monomer in the presence of a suitable base, the maleic anhydride monomer being present in an amount of about 78 wt %.

2. The golf ball of claim 1 , wherein the ionomer of an alternate copolymer further comprises a flow modifier.

3. The golf ball of claim 2 , wherein flow modifier comprises a fatty-acid salt or non-fatty-acid salt.

4. The golf ball of claim 3 , wherein the fatty acid salt, or non-fatty acid salt, is present in an amount of about 10 wt % to about 50 wt %.

5. The golf ball of claim 1 , wherein the golf ball further comprises an intermediate layer having a melt flow of about 0 g/10 min at 190° C. to about 5.0 g/10 min at 190° C.

6. The golf ball of claim 5 , wherein the intermediate layer melt flow is about 0 g/10 min at 190° C.

7. The golf ball of claim 5 , wherein the intermediate layer comprises a highly-neutralized polymer, an ionomer of an alternate copolymer, or a mixture thereof.

8. The golf ball of claim 1 , wherein the core comprises the ionomer of an alternate copolymer.

9. The golf ball of claim 1 , wherein the ionomer of an alternate copolymer is blended with a conventional acid copolymer or the ionomeric derivatives thereof.

10. The golf ball of claim 1 , wherein the cover comprises ionomeric copolymers and terpolymers, ionomer precursors, thermoplastics, thermoplastic elastomers, polybutadiene rubber, balata, grafted metallocene-catalyzed polymers, non-grafted metallocene-catalyzed polymers, single-site polymers, high-crystalline acid polymers and their ionomers, anionic ionomers, cationic ionomers, or mixtures thereof.

11. A golf ball, comprising:

a core having a diameter, a first Shore D hardness and a compression;

a cover having a second Shore D hardness that is at least 5 points less than the first Shore D hardness; and

an intermediate layer disposed between the core and the cover;

wherein the intermediate layer and/or the cover comprises an ionomer of an alternate copolymer, the alternate copolymer comprising the reaction product of a copolymer of ethylene and maleic anhydride monomer in the presence of a suitable base, the maleic anhydride monomer being present in an amount of about 78 wt %.

Assignments (5)
ASSIGNMENT OF SECURITY INTEREST IN PATENTS (ASSIGNS 039506-0030) Recorded Aug 3, 2022
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS RESIGNING ADMINISTRATIVE AGENT
To: JPMORGAN CHASE BANK, N.A., AS SUCCESSOR ADMINISTRATIVE AGENT
Reel/Frame 061521/0414 →
RELEASE OF SECURITY INTEREST IN PATENTS PREVIOUSLY RECORDED AT REEL/FRAME (027345/0877) Recorded Sep 7, 2016
From: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
To: ACUSHNET COMPANY
Reel/Frame 039939/0087 →
SECURITY INTEREST Recorded Jul 28, 2016
From: ACUSHNET COMPANY
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 039506/0030 →
SECURITY AGREEMENT Recorded Dec 8, 2011
From: ACUSHNET COMPANY
To: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
Reel/Frame 027345/0877 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 12, 2010
From: RAJAGOPALAN, MURALI; SULLIVAN, MICHAEL J.
To: ACUSHNET COMPANY
Reel/Frame 025351/0737 →
Continuity (1)
Related Publication 20120122612A1 · May 17, 2012