Thermoformed article made from polybutylene succinate (PBS) and modified polybutylene succinate (MPBS)
View Patent ↗The present invention relates to articles made of a thermoformable resin comprising a biodegradable polymer having polybutylene succinate (PBS) via extrusion using an extruder which comprise: a biodegradable polymer having: (a) a T s value of up to about 160° C. (e.g., in the range of from about 50° to about 150° C.); (b) a heat distortion index of up to about 150° C. (for example, up to about 120° C.); and (c) optionally, a T m in the range of from about 70° to about 160° C. (e.g., in the range of from about 80° to about 150° C.). Thermoformed article such as a food or beverage cup, lid, cutlery item, foodservice item, molded tray, food storage container, etc provide the ability to resist deformation during higher temperature conditions that may occur during storage and distribution.
1. A hot beverage cup lid made of a thermoformable resin composition comprising a biodegradable polymer comprising polybutylene succinate (PBS), and optionally comprising a filler, wherein, when present, the filler is a natural filler selected from the group consisting of cellulose fibers and powders, wherein the biodegradable polymer composition has a) a heat distortion index of from 50° C. to 140° C., b) a Tm in the range of 40° C. to 250° C., and c) a Ts value in the range of 60° C. to 150° C. wherein the heat distortion index is the temperature at which a polymer deforms under a specified load as determined by test procedure ASTM D648, Tm is the melting temperature of the polymer, and the Ts refers to the Vicat softening point wherein the Vicat softening point is measured as the temperature at which a polymer specimen is penetrated to a depth of 1 mm by a flat-ended needle with a 1 sq. mm circular or square cross-section.
2. The lid of claim 1 wherein the biodegradable polymer composition further comprises a polyhydroxyalkanoate polymer, a polycaprolactone polymer, a starch-based polymer, a cellulose-based polymer, or combination thereof.
3. The lid of claim 2 wherein the biodegradable polymer composition further comprises a polyhydroxyalkanoate polymer.
4. The lid of claim 3 wherein the polyhydroxyalkanoate polymer comprises one or more of poly-beta-hydroxybutyrate, poly-alpha-hydroxybutyrate, poly-3-hydroxypropionate, poly-3-hydroxyvalerate, poly-4-hydroxybutyrate, poly-4-hydroxyvalerate, poly-5-hydroxyvalerate, poly-3-hydroxyhexanoate, poly-4-hydroxyhexanoate, poly-6-hydroxyhexanoate, polyhydroxybutyrate-valerate, polyglycolic acid, or polylactic acid.
5. The lid of claim 3 wherein the polyhydroxyalkanoate polymer comprises polylactic acid.
6. The lid of claim 5 wherein the polylactic acid has a number average molecular weight in the range of from about 15,000 and about 300,000.
7. The lid of claim 6 wherein the biodegradable polymer composition further comprises a starch-based polymer, or a combination of a starch-based polymer and a polyhydroxyalkanoate polymer.
8. The lid of claim 1 wherein the lid is extruded with a co-rotating, twin-screw extruder.
9. The lid of claim 1 wherein the lid is extruded with a counter-rotating, twinscrew extruder.
10. The article of claim 1 wherein the biodegradable polymer composition has a Tm in the range of 80° C. to 150° C.