Stable aqueous suspension concentrate for delivery of UV-labile water-insoluble biocides
View Patent ↗A stable, aqueous suspension concentrate which includes a solid polymeric dispersant comprising one or more anionic polymeric dispersing agents, optionally a co-dispersant which preferably is a homopolymer and/or a copolymer of a heterocyclic vinyl lactam, preferably in a wt. ratio of 0.1:1 to 1:0.1, a UV-labile, water-insoluble biocide active, and a UV-blocker or UV-absorber to stabilize said active upon storage and/or exposure to sunlight or UV radiation.
1. A stable, aqueous suspension concentrate which includes a solid polymeric dispersant comprising one or more anionic polymeric dispersing agents and a polyvinyl pyrrolidone co-dispersant, wherein said anionic polymeric dispersing agent and said co-dispersant are present in a wt. ratio of 0.1:1 to 1:0.1, and further comprising iodopropargyl butyl carbamate (IPBC) and titanium dioxide wherein said IPBC is stable upon storage and/or exposure to sunlight or UV radiation and wherein the IPBC does not degrade upon storage for 30 days at 50° C.
2. A stable, aqueous suspension concentrate according to claim 1 wherein said anionic polymeric dispersing agent is selected from the group consisting of a sodium salt of alkyl vinyl ether/maleic acid half ester copolymer, a lignosulfonate or metal salt thereof, a sulfonated naphthalene/formaldehyde condensate, an alpha-olefin/maleic acid copolymer, a polyacrylate and mixtures thereof.
3. A stable, aqueous suspension concentrate according to claim 1 wherein said anionic polymeric dispersing agent is an ionic derivative of methyl vinyl ether-maleic acid half-ester.
4. A stable, aqueous suspension concentrate according to claim 1 wherein said concentrate is free of organic solvents.
5. A composition including the concentrate of claim 1 .
6. A paint composition including the concentrate of claim 1 .
7. A personal care composition including the concentrate of claim 1 .
8. An article comprising a substrate coated with the suspension concentrate of claim 1 .
9. An article according to claim 8 wherein said substrate is wood.