IP Library Granted Patent US 8,784,941
Granted Patent B2
US 8,784,941 · App. 13/063,207 · Granted Jul 22, 2014

Process for the production of a dark-color multi-layer coating

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Quick Facts
Patent No.
US 8,784,941
App. No.
13/063,207
Granted
Jul 22, 2014
Kind
B2
Abstract

A process for the production of a dark-color multi-layer coating, comprising the successive steps: (1) applying an NIR-opaque coating layer A′ from a waterborne pigmented coating composition A to a substrate, (2) applying a coating layer B′ from a waterborne pigmented coating composition B onto the substrate provided with coating layer A′, (3) subjecting the coated substrate obtained in step (2) to a drying step, (4) applying a clear coat layer, and (5) curing the coating layers simultaneously; wherein both coating compositions A and B comprise aqueous microgel and sheet silicate, wherein the pigment content of coating composition A comprises <90 wt. % of aluminum flake pigments and has such a composition that coating layer A′ exhibits low NIR absorption, wherein the pigment content of coating composition B consists 50 to 100 wt. % of black pigment with low NIR absorption and 0 to 50 wt. % of further pigment.

Claims (24)

1. A process for the production of a dark-color multi-layer coating, comprising the successive steps:

(1) applying an NIR-opaque coating layer A′ from a waterborne pigmented coating composition A to a substrate,

(2) applying a coating layer B′ from a waterborne pigmented coating composition B onto the substrate provided with coating layer A′,

(3) subjecting the coated substrate obtained in step (2) to a drying step,

(4) applying a clear coat layer from a clear coat composition onto the coated substrate obtained in step (3), and

(5) curing the coating layers applied in steps (1), (2), and (4) simultaneously;

wherein both waterborne coating compositions A and B comprise aqueous microgel and sheet silicate,

wherein the pigment content of coating composition A comprises <90 wt. % of aluminum flake pigments and is composed in such a way that NIR-opaque coating layer A′ exhibits low NIR absorption,

wherein the pigment content of coating composition B consists 50 to 100 wt. % of at least one black pigment with low NIR absorption and 0 to 50 wt. % of at least one further pigment, which is selected in such a way that coating layer B′ exhibits low NIR absorption and that the dark-color multi-layer coating exhibits a brightness L* (according to CIEL*a*b*, DIN 6174), measured at an illumination angle of 45 degrees to the perpendicular and an observation angle of 45 degrees to the specular, of at most 10 units, and

wherein the sum of the respective wt. % equals 100 wt. %.

2. The process of claim 1 , wherein the pigment content of coating composition A comprises less than 25 wt. % of aluminum flake pigments.

3. The process of claim 1 , wherein coating composition A is a solid color coating composition free of special effect pigments.

4. The process of claim 1 , 2 or 3 , wherein the pigment content of coating composition A comprises 80 to 100 wt. % of titanium dioxide.

5. The process of claim 4 , wherein coating composition A does not contain any carbon black.

6. The process of claim 4 , wherein coating composition A comprises a binder solids comprising 30 to 100 wt. % of aqueous microgel.

7. The process of claim 4 , wherein coating composition A comprises 0.1 to 1.6 wt. % sheet silicate.

8. The process of claim 4 , wherein the at least one black pigment with low NIR absorption is selected from the group consisting of iron oxide black pigments, mixed metal/iron oxide black pigments and perylene black pigments.

9. The process of claim 4 , wherein coating composition B does not contain any carbon black.

10. The process of any claim 4 , wherein coating composition B comprises a binder solids comprising 30 to 100 wt. % of aqueous microgel.

11. The process of claim 4 , wherein coating composition B comprises 0.1 to 1.6 wt. % sheet silicate.

12. The process of claim 4 , wherein coating layer B′ is a transparent or a visually opaque coating layer.

13. The process of claim 4 , wherein coating composition B is applied to coating layer A′ when at least 50 wt. % of the volatiles of coating composition A are still present in coating layer A′.

14. The process of claim 4 , wherein coating composition B is applied within 10 to 300 seconds of the application of coating composition A.

15. The process of claim 4 being carried out in the context of an industrial mass production coating process.

Assignments (5)
RELEASE OF SECURITY INTEREST Recorded Sep 29, 2016
From: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
To: AXALTA COATING SYSTEMS IP CO. LLC (FORMERLY KNOWN AS U.S. COATINGS IP CO. LLC)
Reel/Frame 040184/0192 →
SECURITY AGREEMENT Recorded Nov 19, 2013
From: U.S. COATINGS IP CO. LLC (N/K/A AXALTA COATING SYSTEMS IP CO. LLC)
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 031668/0001 →
CHANGE OF NAME Recorded Jun 18, 2013
From: U.S. COATINGS IP CO., LLC
To: AXALTA COATING SYSTEMS IP CO., LLC
Reel/Frame 030639/0164 →
SECURITY AGREEMENT Recorded Mar 28, 2013
From: U.S. COATINGS IP CO. LLC
To: BARCLAYS BANK PLC, AS COLLATERAL AGENT
Reel/Frame 030119/0163 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 13, 2013
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: U.S. COATINGS IP CO. LLC
Reel/Frame 029803/0826 →